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    High molecular weight polyols, process for preparation and use thereof
    5.
    发明授权
    High molecular weight polyols, process for preparation and use thereof 失效
    高分子量多元醇，其制备方法和用途

    公开(公告)号：US06420320B1

    公开(公告)日：2002-07-16

    申请号：US09656855

    申请日：2000-09-07

    Applicant: Philip W. McGraw ,  Robert H. Whitmarsh

    Inventor： Philip W. McGraw ,  Robert H. Whitmarsh

    IPC: C10M11104

    CPC classification number: C10M173/02 ,  C08G18/10 ,  C08G18/4837 ,  C08G18/4866 ,  C08G18/718 ,  C08G65/2651 ,  C08G65/336 ,  C10M107/34 ,  C10M145/26 ,  C10M145/28 ,  C10M145/30 ,  C10M2201/02 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2209/107 ,  C10N2220/02 ,  C10N2240/08 ,  C10N2250/02 ,  C08G18/307

    Abstract: The invention is a high molecular weight polyether polyol prepared by the reaction of one or more compounds having one or more active hydrogen compounds with one or more alkylene oxides in the presence of a catalyst comprising calcium having counterions of carbonate and a C6-10 alkanoate in a solvent or dispersant which does not contain active hydrogen atoms. The polyether polyol prepared preferably has an equivalent weight of from about 10,000 to about 30,000, a polydispersity of 1.3 or less and a residual catalyst level of from more than 0 to about 2000 parts per million (ppm). In another embodiment the invention is a process for preparing such high molecular weight polyether polyols. The process comprises first, contacting one or more compounds having one or more active hydrogen atoms with one or more alkylene oxides in the presence of a catalyst. The catalyst comprises calcium having counterions of carbonate and a C6-10 alkanoate in a solvent, wherein the solvent does not contain active hydrogen atoms. The mixture is exposed to conditions at which the alkylene oxides react with the compound containing more than one active hydrogen atoms such that a polyether polyol is prepared which has an equivalent weight of from about 10,000 to about 30,000, a polydispersity of about 1.3 or less and a residual catalyst level of from more than 0 to about 2,000 (ppm).

    Abstract translation: 本发明是一种高分子量聚醚多元醇，其通过一种或多种具有一种或多种活性氢化合物与一种或多种烯化氧的化合物的反应制备，所述化合物在催化剂存在下，该催化剂包含具有与碳酸酯和C 6-10链烷酸酯的抗衡离子的钙 不含活性氢原子的溶剂或分散剂。 制备的聚醚多元醇的当量重量优选为约10,000至约30,000，多分散性为1.3或更低，残留催化剂含量为大于0至约2000ppm（ppm）。 在另一个实施方案中，本发明是制备这种高分子量聚醚多元醇的方法。 该方法首先在催化剂存在下使具有一个或多个活性氢原子的一种或多种化合物与一种或多种环氧烷接触。 该催化剂包括在溶剂中具有碳酸酯和C 6-10链烷酸酯的抗衡离子的钙，其中溶剂不含活性氢原子。 将混合物暴露于环氧烷与含有多于一个活性氢原子的化合物反应的条件，使得制备的聚醚多元醇的当量为约10,000至约30,000，多分散度为约1.3或更小，以及 残余催化剂含量大于0至约2,000（ppm）。

    High molecular weight polyols, process for preparation and use thereof
    6.
    发明授权
    High molecular weight polyols, process for preparation and use thereof 失效
    高分子量多元醇，其制备方法和用途

    公开(公告)号：US06362140B1

    公开(公告)日：2002-03-26

    申请号：US09656603

    申请日：2000-09-07

    Applicant: Philip W. McGraw ,  Robert H. Whitmarsh

    Inventor： Philip W. McGraw ,  Robert H. Whitmarsh

    IPC: C10M10734

    CPC classification number: C10M173/02 ,  C08G18/10 ,  C08G18/4837 ,  C08G18/4866 ,  C08G18/718 ,  C08G65/2651 ,  C08G65/336 ,  C10M107/34 ,  C10M145/26 ,  C10M145/28 ,  C10M145/30 ,  C10M2201/02 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2209/107 ,  C10N2220/02 ,  C10N2240/08 ,  C10N2250/02 ,  C08G18/307

    Abstract: The invention is a high molecular weight polyether polyol prepared by the reaction of one or more compounds having one or more active hydrogen compounds with one or more alkylene oxides in the presence of a catalyst comprising calcium having counterions of carbonate and a C6-10 alkanoate in a solvent or dispersant which does not contain active hydrogen atoms. The polyether polyol prepared preferably has an equivalent weight of from about 1000 to about 20,000, a polydispersity of 1.3 or less and a residual catalyst level of from about 0 to about 2000 parts per million (ppm). In another embodiment the invention is a process for preparing such high molecular weight polyether polyols. The process comprises first, contacting one or more compounds having one or more active hydrogen atoms with one or more alkylene oxides in the presence of a catalyst. The catalyst comprises calcium having counterions of carbonate and a C6-10 alkanoate in a solvent, wherein the solvent does not contain active hydrogen atoms. The mixture is exposed to conditions at which the alkylene oxides react with the compound containing more than one active hydrogen atoms such that a polyether polyol is prepared which has an equivalent weight of from about 1,000 to about 20,000, a polydispersity of about 1.3 or less and a residual catalyst level of from about 0 to about 1000 (ppm).

    Abstract translation: 本发明是一种高分子量聚醚多元醇，其通过一种或多种具有一种或多种活性氢化合物与一种或多种烯化氧的化合物的反应制备，所述化合物在催化剂存在下，该催化剂包含具有与碳酸酯和C 6-10链烷酸酯的抗衡离子的钙 不含活性氢原子的溶剂或分散剂。 制备的聚醚多元醇的当量重量优选为约1000至约20,000，多分散性为1.3或更低，残留催化剂含量为约0至约2000ppm（ppm）。 在另一个实施方案中，本发明是制备这种高分子量聚醚多元醇的方法。 该方法首先在催化剂存在下使具有一个或多个活性氢原子的一种或多种化合物与一种或多种环氧烷接触。 该催化剂包括在溶剂中具有碳酸酯和C 6-10链烷酸酯的抗衡离子的钙，其中溶剂不含活性氢原子。 将混合物暴露于环氧烷与含有多于一个活性氢原子的化合物反应的条件，使得制备的聚醚多元醇的当量为约1,000至约20,000，多分散度为约1.3或更小，以及 残余催化剂水平为约0至约1000（ppm）。

    Method for preparing flexible polyurethane foams
    8.
    发明授权
    Method for preparing flexible polyurethane foams 失效
    制备柔性聚氨酯泡沫的方法

    公开(公告)号：US5807903A

    公开(公告)日：1998-09-15

    申请号：US919023

    申请日：1997-08-27

    Applicant: Michael Allen Stanga ,  Robert Edward Stevens ,  Kevin Dale Wiese ,  Wanda Wells Rauscher ,  Robert H. Whitmarsh ,  Vicky Sue Cobb

    Inventor： Michael Allen Stanga ,  Robert Edward Stevens ,  Kevin Dale Wiese ,  Wanda Wells Rauscher ,  Robert H. Whitmarsh ,  Vicky Sue Cobb

    IPC: C08G18/00 ,  C08G18/48 ,  C08G77/46 ,  C08G101/00 ,  C08J9/00 ,  C08J9/08 ,  C08L75/04

    CPC classification number: C08J9/0061 ,  C08G18/4837 ,  C08G77/46 ,  C08G2101/0008 ,  C08J2375/04 ,  C08J2483/00

    Abstract: This invention relates to a method for preparing a flexible polyurethane slabstock foam by reacting a polyol, an organic diisocyanate, and water in the presence of at least one urethane catalyst, a siloxane-oxyalkylene copolymer surfactant and, optionally another blowing agent, where the surfactant has the average formula MD.sub.x D'.sub.y M where M is (CH.sub.3).sub.3 SiO.sub.1/2 or R(CH.sub.3).sub.2 SiO.sub.1/2, D is (CH.sub.3).sub.2 SiO.sub.2/2, D' is (CH.sub.3)RSiO.sub.2/2, and the value of x+y is 48 to 220, the ratio x/y is 5 to 15 inclusive, R is a polyether-containing substituent selected from the group consisting of (1) --C.sub.n H.sub.2n O(C.sub.2 H.sub.4 O).sub.a (C.sub.3 H.sub.6 O).sub.b R' group having weight average molecular weights in the range 2300-3400 and wherein n is 3-4, the ratio a/b is from 0.5 to 1.3 inclusive, R' represents hydrogen, an alkyl group of 1-4 carbon atoms or --C(O)CH.sub.3 and (2) --C.sub.n' H.sub.2n' O(C.sub.2 H.sub.4 O).sub.a' (C.sub.3 H.sub.6 O).sub.b' R' group having weight average molecular weights in the range 750-1400 and wherein n' is 3-4, a' is a number such that the ethylene oxide residues constitute 30-100% by weight of the alkylene oxide residues of the polyether, b' is a number such that the propylene oxide residues constitute 0-70% by weight of the alkylene oxide residues of the polyether, R' represents hydrogen, an alkyl group of 1-4 carbon atoms or --C(O)CH.sub.3, and the blend average molecular weight of the overall polyether-containing substituents R in the surfactant is in the range from 1500 to 2200 and the EO/PO molar ratio ranges from 0.65 to 1.2.

    Abstract translation: 本发明涉及一种在至少一种氨基甲酸酯催化剂，硅氧烷 - 氧化烯共聚物表面活性剂和任选地另外的发泡剂存在下使多元醇，有机二异氰酸酯和水反应制备柔性聚氨酯块状泡沫的方法，其中表面活性剂 具有平均式MDxD'yM，其中M为（CH3）3SiO1 / 2或R（CH3）2SiO1 / 2，D为（CH3）2SiO2 / 2，D'为（CH3）RSiO2 / 2，x + y为48〜220，x / y为5〜15，R为含有（1）-CnH 2 O（C 2 H 4 O）a（C 3 H 6 O）b R'的具有重均分子量的聚醚的取代基 在2300-3400范围内，其中n为3-4，a / b为0.5-3.3（含），R'表示氢，1-4个碳原子的烷基或-C（O）CH 3和（2 ）-C n'H 2 n O（C 2 H 4 O）a'（C 3 H 6 O）b'R'基团，其重均分子量在750-1400范围内，其中n'为3-4，a'是使环氧乙烷 残留量为30-100％b 聚醚的氧化烯残基的重量，b'是使得环氧丙烷残基构成聚醚的氧化烯残基的0-70重量％的数，R'表示氢，1-4的烷基 碳原子或-C（O）CH 3，并且表面活性剂中总的含聚醚取代基R的共混物平均分子量在1500至2200的范围内，EO / PO摩尔比为0.65至1.2。

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