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1.发明授权Algicidal and fungicidal 1-halo-2-substituted-thioethyl sulfones, 2-substituted-thiovinyl sulfones, and 1,2-dihalothioethyl sulfones 失效杀藻和杀真菌剂1-卤代-2-硫代乙基砜，2-取代 - 硫代乙烯基砜和1,2-二卤代硫代乙基砜
公开(公告)号：US4255451A
公开(公告)日：1981-03-10
申请号：US60114
申请日：1979-07-23
Applicant: Philip S. Magee
Inventor： Philip S. Magee
IPC: A01N41/10
CPC classification number: C07C323/00 , A01N41/10
Abstract: 1-Halo-2-alkylthioethyl and 1-halo-2-arylthioethyl sulfones, having algicidal and fungicidal activity, are prepared by the addition of arylsulfenyl or alkylsulfenyl halides to alkyl or aryl vinyl sulfones. The thioethyl sulfone products are treated with a base to produce 2-alkylthiovinyl or 2-arylthiovinyl sulfones, which also have algicidal and fungicidal activity. The vinyl sulfones are halogenated to produce 1,2-dihalothioethyl sulfones, which have superior fungicidal activity, especially for tomato and celery late blight.
Abstract translation: 具有杀藻和杀真菌活性的1-卤代-2-烷基硫代乙基和1-卤代-2-芳基硫代乙基砜通过在烷基或芳基乙烯基砜中加入芳基亚磺酰基或烷基硫基卤化物来制备。 硫代乙基砜产物用碱处理以产生2-烷硫基乙烯基或2-芳硫基乙烯基砜，其也具有杀藻和杀真菌活性。 乙烯基砜被卤化以产生具有优异的杀真菌活性的1,2-二卤代硫代乙基砜，特别是对于番茄和芹菜晚疫病。
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2.发明授权Algicidal and fungicidal 1-halo-2-substituted-thioethyl sulfones, 2-substituted-thiovinyl sulfones, and 1,2-dihalothioethyl sulfones 失效杀藻和杀真菌剂1-卤代-2-硫代乙基砜，2-取代 - 硫代乙烯基砜和1,2-二卤代硫代乙基砜
公开(公告)号：US4196152A
公开(公告)日：1980-04-01
申请号：US912778
申请日：1978-06-05
Applicant: Philip S. Magee
Inventor： Philip S. Magee
IPC: A01N41/10 , C07C149/32 , A01N9/14 , C07C149/00 , C07C149/34
CPC classification number: C07C323/00
Abstract: 1-Halo-2-alkylthioethyl and 1-halo-2-arylthioethyl sulfones, having algicidal and fungicidal activity, are prepared by the addition of arylsulfenyl or alkylsulfenyl halides to alkyl or aryl vinyl sulfones. The thioethyl sulfone products are treated with a base to produce 2-alkylthiovinyl or 2-arylthiovinyl sulfones, which also have algicidal and fungicidal activity. The vinyl sulfones are halogenated to produce 1,2-dihalothioethyl sulfones, which have superior fungicidal activity, especially for tomato and celery late blight.
Abstract translation: 具有杀藻和杀真菌活性的1-卤代-2-烷基硫代乙基和1-卤代-2-芳基硫代乙基砜通过在烷基或芳基乙烯基砜中加入芳基亚磺酰基或烷基硫基卤化物来制备。 硫代乙基砜产物用碱处理以产生2-烷硫基乙烯基或2-芳硫基乙烯基砜，其也具有杀藻和杀真菌活性。 乙烯基砜被卤化以产生具有优异杀真菌活性的1,2-二卤代硫代乙基砜，特别是对于番茄和芹菜晚疫病。
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3.发明授权Insecticidal O,S-dihydrocarbyl-N-haloacylphosphoroamidothioates and S,S-dihydrocarbyl-N-haloacylphosphoroamidodithioates 失效杀虫剂O，S-二烃基-N-卤代酰基磷酰氨基硫代磷酸酯和S，S-二烃基-N-卤代酰基磷酰胺二硫代磷酸酯
公开(公告)号：US4049679A
公开(公告)日：1977-09-20
申请号：US317316
申请日：1972-12-21
Applicant: Philip S. Magee
Inventor： Philip S. Magee
CPC classification number: C07F9/2487 , A01N57/28
Abstract: O,S-dihydrocarbylphosphoroamidothioates and S,S-dihydrocarbylphosphoroamidodithioates have a high degree of insecticidal activity with relatively low mammalian toxicity.
Abstract translation: O，S-二烃基磷酰胺硫代磷酸酯和S，S-二烃基磷酰胺二硫代磷酸酯具有较高的杀虫活性，相对较低的哺乳动物毒性。
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公开(公告)号：US4511735A
公开(公告)日：1985-04-16
申请号：US537753
申请日：1983-09-30
Applicant: Philip S. Magee
Inventor： Philip S. Magee
IPC: A01N41/10 , C07C67/00 , C07C313/00 , C07C313/18 , C07C317/04 , C07C317/14 , C07C143/74 , C07C143/76 , C07C143/78
CPC classification number: A01N41/10 , C07C317/00 , C07C323/00 , C07C327/00
Abstract: The present invention relates to novel fungicides of the formula: ##STR1## wherein R.sup.1 is lower alkyl, lower akenyl, lower alkynyl or aryl of 6 to 10 carbon atoms optionally substituted with up to 3 halogen atoms; R.sup.2 is lower alkyl, lower alkenyl, lower alkynyl or aryl of 6 to 10 carbon atoms optionally substituted with up to 3 halogen atoms or up to 3 lower alkoxy groups; and R.sup.3 is alkyl of 1 to 3 carbon atoms substituted with 3 to 6 halogen atoms or trihalovinyl.
Abstract translation: 本发明涉及下式的新型杀真菌剂：其中R 1为任选被至多3个卤素原子取代的6至10个碳原子的低级烷基，低级烯基，低级炔基或芳基; R2是任选被至多3个卤素原子或至多3个低级烷氧基取代的6至10个碳原子的低级烷基，低级烯基，低级炔基或芳基; R3为被3〜6个卤素原子取代的1〜3个碳原子的烷基或三卤代乙烯基。
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5.发明授权1-Alkylsulfonyl-3-substituted phosphinylthio- or phosphinothioylthio-propenes 失效1-烷基磺酰基-3-取代的氧膦基硫基或膦硫基硫代丙烯
公开(公告)号：US4299783A
公开(公告)日：1981-11-10
申请号：US143984
申请日：1980-04-28
Applicant: Philip S. Magee
Inventor： Philip S. Magee
CPC classification number: C07F9/173 , A01N57/12 , A01N57/22 , A01N57/28 , C07F9/2412 , C07F9/2487 , C07F9/4078
Abstract: 3-Phosphinylthio- and 3-phosphinothioylthio-1-sulfonyl propenes have fungicidal and insecticidal activity.
Abstract translation: 3-氧膦基硫代和3-膦硫基硫基-1-磺酰基丙烯具有杀真菌和杀虫活性。
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Patent Agency Ranking6.发明授权Insecticidal O,S-dihydrocarbyl-N-haloacylphosphoroamidothioates and S,S-dihydrocarbyl-N-haloacylphosphoroamidodithioates 失效杀虫剂O，S-二羟基-N-对羟基苯甲酰氨基甲酸酯和S，S-二氢氨基-N-羟基磷酰基二磷酸酯
公开(公告)号：US4110443A
公开(公告)日：1978-08-29
申请号：US805494
申请日：1977-06-10
Applicant: Philip S. Magee
Inventor： Philip S. Magee
CPC classification number: A01N57/28 , C07F9/2487
Abstract: O,S-dihydrocarbylphosphoroamidothioates and S,S-dihydrocarbylphosphoroamidodithioates have a high degree of insecticidal activity with relatively low mammalian toxicity.
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公开(公告)号：US4461764A
公开(公告)日：1984-07-24
申请号：US421178
申请日：1982-09-22
Applicant: Philip S. Magee
Inventor： Philip S. Magee
IPC: A01N57/08 , C07D333/48 , C07F9/24 , C07F9/40 , C07F9/42 , C07F9/6553 , A01N57/32
CPC classification number: C07D333/48 , A01N57/08 , C07F9/2408 , C07F9/4075 , C07F9/425 , C07F9/655345
Abstract: Compounds of the formula: ##STR1## wherein X is sulfur or oxygen; R.sub.1 is lower alkyl; R.sub.2 is lower alkyl, lower straight chain alkoxy, lower alkylthio, phenyl or the group --NR.sub.3 R.sub.4 where R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl, provided that when X is oxygen, R.sub.2 is not phenyl, are pesticidal, exhibiting activity against pests such as plant fungal diseases and, in many cases, insects.
Abstract translation: 下式的化合物：其中X是硫或氧; R1是低级烷基; R2是低级烷基，低级直链烷氧基，低级烷硫基，苯基或-NR3R4基团，其中R3和R4独立地是氢或低级烷基，条件是当X是氧时，R 2不是苯基，是杀虫剂，表现出对害虫的活性， 作为植物真菌病，在许多情况下是昆虫。
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8.发明授权Algicidal and fungicidal 1-halo-2-substituted-thioethyl sulfones, 2-substituted-thiovinyl sulfones, and 1,2-dihalothioethyl sulfones 失效杀藻和杀真菌剂1-卤代-2-硫代乙基砜，2-取代 - 硫代乙烯基砜和1,2-二卤代硫代乙基砜
公开(公告)号：US4321080A
公开(公告)日：1982-03-23
申请号：US176898
申请日：1980-08-11
Applicant: Philip S. Magee
Inventor： Philip S. Magee
IPC: A01N41/10
CPC classification number: A01N41/10
Abstract: 1-Halo-2-alkylthioethyl and 1-halo-2-arylthioethyl sulfones, having algicidal and fungicidal activity, are prepared by the addition of arylsulfenyl or alkylsulfenyl halides to alkyl or aryl vinyl sulfones. The thioethyl sulfone products are treated with a base to produce 2-alkylthiovinyl or 2-arylthiovinyl sulfones, which also have algicidal and fungicidal activity. The vinyl sulfones are halogenated to produce 1,2-dihalothioethyl sulfones, which have superior fungicidal activity, especially for tomato and celery late blight.
Abstract translation: 具有杀藻和杀真菌活性的1-卤代-2-烷基硫代乙基和1-卤代-2-芳基硫代乙基砜通过在烷基或芳基乙烯基砜中加入芳基亚磺酰基或烷基硫基卤化物来制备。 硫代乙基砜产物用碱处理以产生2-烷硫基乙烯基或2-芳硫基乙烯基砜，其也具有杀藻和杀真菌活性。 乙烯基砜被卤化以产生具有优异的杀真菌活性的1,2-二卤代硫代乙基砜，特别是对于番茄和芹菜晚疫病。
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公开(公告)号：US4031247A
公开(公告)日：1977-06-21
申请号：US715959
申请日：1976-08-19
Applicant: Philip S. Magee
Inventor： Philip S. Magee
IPC: A01N9/12
Abstract: Vinyl 2-arylthiovinyl and vinyl 2-alkylthiovinyl sulfones, having fungicidal and algicidal activity, are prepared by the addition of arylsulfenyl halides or alkylsulfenyl halides to divinyl sulfone and the dihydrohalogenation of the resulting 1,2-addition product.
Abstract translation: 具有杀真菌和杀藻活性的2-芳基硫代乙烯基乙烯基和乙烯基2-烷硫基乙烯基砜通过在二乙烯基砜中加入芳基硫基卤化物或烷基硫基卤化物和所得1,2-加成产物的二氢卤代化来制备。
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公开(公告)号：US3988376A
公开(公告)日：1976-10-26
申请号：US657679
申请日：1976-02-12
Applicant: Philip S. Magee
Inventor： Philip S. Magee
IPC: C07C149/10
CPC classification number: C07C323/00 , C07C321/00
Abstract: Vinyl 2-arylthiovinyl and vinyl 2-alkylthiovinyl sulfones, having fungicidal and algicidal activity, are prepared by the addition of arylsulfenyl halides or alkylsulfenyl halides to divinyl sulfone and the dihydrohalogenation of the resulting 1,2-addition product.
Abstract translation: 具有杀真菌和杀藻活性的2-芳基硫代乙烯基乙烯基和乙烯基2-烷硫基乙烯基砜通过在二乙烯基砜中加入芳基硫基卤化物或烷基硫基卤化物和所得1,2-加成产物的二氢卤代化来制备。
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