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公开(公告)号：US4891070A
公开(公告)日：1990-01-02
申请号：US37526
申请日：1987-04-13
申请人： Peter Dilling , Mitchell S. Dimitri
发明人： Peter Dilling , Mitchell S. Dimitri
CPC分类号： C08H6/00 , C09D11/08 , D21C11/0007
摘要： A method of producing a lignin by-product of the black liquor residue of a kraft pulping process having improved water-solubility in amine salt form wherein the lignin precipitate of the black liquor residue is water-wash purified and maintained at moderately acid pH of no lower than about 5. The lignin may then be combined in aqueous slurry with an organic amine, such as monoethanolamine, to provide a highly stable aqueous solution of the amine salt of the lignin. The water-soluble lignin salt is particularly suited for use as an additive in water-based pigment printing compositions. The lignin amine salt functions as a grinding agent for the pigment in formulating and as a binder for the pigment in the printing process.
摘要翻译： 一种制备具有改善的胺盐形式的水溶性的硫酸盐法制浆工艺的黑液残留物的木质素副产物的方法，其中黑液残留物的木质素沉淀物被水洗净化并保持在中等酸度pH值为 然后可以将木质素与含水浆料与有机胺如单乙醇胺混合，以提供高度稳定的木质素胺盐水溶液。 水溶性木质素盐特别适合用作水性颜料印刷组合物中的添加剂。 木质素胺盐在配制中用作颜料的研磨剂，并且用作印刷方法中的颜料的粘合剂。
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公开(公告)号：US4740591A
公开(公告)日：1988-04-26
申请号：US37772
申请日：1987-04-13
申请人： Peter Dilling , Mitchell S. Dimitri
发明人： Peter Dilling , Mitchell S. Dimitri
摘要： A method of producing a lignin by-product of the black liquor residue of a kraft pulping process having improved water-solubility in amine salt form wherein the lignin precipitate of the black liquor residue is water-wash purified and maintained at moderately acid pH of no lower than about 5. The lignin may then be combined in aqueous slurry with an organic amine, such as monoethanolamine, to provide a highly stable aqueous solution of the amine salt of the lignin. The water-soluble lignin salt is particularly suited for use as an additive in water-based pigment printing compositions. The lignin amine salt functions as a grinding agent for the pigment in formulating and as a binder for the pigment in the printing process.
摘要翻译： 一种制备具有改善的胺盐形式的水溶性的硫酸盐法制浆工艺的黑液残留物的木质素副产物的方法，其中黑液残留物的木质素沉淀物被水洗净化并保持在中等酸度pH值为 然后可以将木质素与含水浆料与有机胺如单乙醇胺混合，以提供高度稳定的木质素胺盐水溶液。 水溶性木质素盐特别适合用作水性颜料印刷组合物中的添加剂。 木质素胺盐在配制中用作颜料的研磨剂，并且用作印刷方法中的颜料的粘合剂。
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3.发明授权Dispersant composition for azo dyestuffs contaminated with soluble copper impurities 失效用可溶性铜杂质污染的偶氮染料的分散剂组合物
公开(公告)号：US4743268A
公开(公告)日：1988-05-10
申请号：US875204
申请日：1986-06-17
申请人： Peter Dilling
发明人： Peter Dilling
CPC分类号： C09B67/0086
摘要： An improved composition for use as a dispersant in azo dye systems contaminated with soluble copper impurities comprising an amine lignosulfonate salt and ethylenediaminetetraacetic acid. Preferably, the ethylenediaminetetraacetic acid is employed in an amount of about 1 to about 4 moles per each molar amount of the copper present in the system, per 1,000 grams of the lignosulfonate. Also disclosed is an improved azo dye system containing an amine lignosulfonate salt and ethylenediaminetetraacetic acid, and an improved method of dyeing materials with copper-contaminated dye systems containing azo dyestuffs and lignosulfonate salts wherein the azo dye reduction effect is alleviated by utilizing as the lignosulfonate salt an amine salt thereof, together with ethylenediaminetetraacetic acid.
摘要翻译： 用作分散剂的改进的组合物，其用可溶性铜杂质污染的偶氮染料体系中，所述可溶性铜杂质包含胺木质素磺酸盐和乙二胺四乙酸胺。 优选地，乙二胺四乙酸的用量为每1000克木质素磺酸盐中每摩尔量的系统中存在的铜约1至约4摩尔。 还公开了一种改进的含有木质素磺酸胺和乙二胺四乙酸胺的偶氮染料体系，以及用含有偶氮染料和木质素磺酸盐的铜污染染料体系染色材料的改进方法，其中偶氮染料还原效果通过利用木素磺酸盐缓解 其胺盐与乙二胺四乙酸一起。
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公开(公告)号：US4740590A
公开(公告)日：1988-04-26
申请号：US819600
申请日：1986-01-17
申请人： Peter Dilling
发明人： Peter Dilling
CPC分类号： C08H6/00 , C09B67/0086 , C09D17/00
摘要： An improved method of producing sodium salts of low electrolyte-containing lignosulfonates suited for use as dye and print paste additives, comprising the steps of (1) methylolating a sodium salt of a lignin compound in an alkaline aqueous medium by the addition of a suitable methylolating component, such as formaldehyde, (2) adding sulfur dioxide to the methylolated lignin in aqueous medium to lower the pH of the lignin to a pH of between about 6.1 to 6.3, (3) heating the resultant aqueous composition containing the methylolated lignin to sulfonate the same by reaction with a sulfur-containing compounds present therein.Resultant sodium salt lignosulfonate products suitable as additives in dyestuffs and dyestuff compositions containing such additives are disclosed.
摘要翻译： 一种生产适合用作染料和印花糊添加剂的含低电解质木质素磺酸盐的钠盐的改进方法，包括以下步骤：（1）通过加入适当的羟甲基化（1）在碱性水介质中羟胺化木质素化合物的钠盐 组分如甲醛，（2）在水性介质中向羟甲基化木质素中加入二氧化硫以将木质素的pH降低至约6.1至6.3之间的pH，（3）将含有羟甲基化木质素的所得水性组合物加热至磺酸盐 通过与其中存在的含硫化合物的反应相同。 公开了适用于含有这些添加剂的染料和染料组合物中的添加剂的所得钠盐木质素磺酸盐产品。
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公开(公告)号：US4001202A
公开(公告)日：1977-01-04
申请号：US623441
申请日：1975-10-17
申请人： Peter Dilling , Gerald Prazak
发明人： Peter Dilling , Gerald Prazak
CPC分类号： C08H6/00 , C09B67/0071 , C09B67/0086
摘要： Disclosed herein is an improved process for producing sulfonated lignin surfactants for use as dispersants for disperse dyes and vat dyes. The improved process is to react a sulfonated lignin and epihalohydrin under certain conditions to block a portion of the free-phenolic hydroxyl group and at the same time cross-link the lignin molecules to increase the molecular weight. Another aspect of the process of this invention is to oxidize the thus treated lignin to stabilize its properties. Dispersants made according to this process have improved fiber staining and heat stability properties over other lignin-based dispersants.
摘要翻译： 本文公开了用于生产磺化木质素表面活性剂的改进方法，其用作分散染料和还原染料的分散剂。 改进的方法是在某些条件下使磺化的木质素和表卤醇反应以阻断部分游离酚羟基，同时交联木质素分子以增加分子量。 本发明方法的另一方面是氧化如此处理的木质素以稳定其性质。 根据该方法制备的分散剂相对于其它基于木质素的分散剂改善了纤维染色和热稳定性。
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公开(公告)号：US5749926A
公开(公告)日：1998-05-12
申请号：US712907
申请日：1996-09-12
申请人： Peter Dilling , Sallie B. Huguenin
发明人： Peter Dilling , Sallie B. Huguenin
CPC分类号： C08H6/00 , B01F17/0057 , C09B67/0086
摘要： Improved dyestuff compositions comprising a dye cake and a dye dispersant are disclosed wherein the dye dispersant comprises sulfonated or sulfomethylated lignin of increased activity and improved heat stability properties and which dispersants are disclosed to be prepared by substantial removal of the low molecular weight component of the sulfonated and sulfomethylated lignin. Exclusion of the low molecular weight portion of the dispersant may be accomplished by fractionation of the sulfonated or sulfomethylated lignin to remove a substantial portion of the molecules having a molecular weight below 3,000. Alternatively, in the case of lignin recovered from sulfate or soda wood pulping processes, the lignin may be fractionated to remove a substantial portion of the molecules having a molecular weight below 3,000 prior to sulfonation or sulfomethylation.
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7.发明授权Selective crosslinking of low molecular weight sulfonated lignins and lignosulfate products produced thereby 失效由此生产的低分子量磺化木质素和木质素硫酸盐产品的选择性交联
公开(公告)号：US4534771A
公开(公告)日：1985-08-13
申请号：US591809
申请日：1984-03-21
申请人： Peter Dilling
发明人： Peter Dilling
CPC分类号： D06P1/62 , C08L97/005 , C09B67/0086
摘要： A process for preparing sulfonated lignins suitable for use as dispersants and additives in dye compositions wherein sulfonated lignins are post-sulfonation crosslinked with a crosslinking agent of the aldehyde, epoxide, or polyhalide type at a pH range of between about 6.1 to 9 to selectively crosslink low molecular weight sizes of the sulfonated lignins to provide improved heat stability and dispersibility of the sulfonated lignins in dye compositions. The invention also concerns disperse and vat dye compositions, and printing gels, containing the sulfonated lignins as a dispersing agent or additive.
摘要翻译： 一种制备磺化木质素的方法，其适用于染料组合物中的分散剂和添加剂，其中磺化木质素是在约6.1至9的pH范围内用醛，环氧化物或多卤素类型的交联剂进行后磺化交联，以选择性交联 磺化木质素的低分子量尺寸，以提供磺化木质素在染料组合物中的改进的热稳定性和分散性。 本发明还涉及分散和还原染料组合物以及含有磺化木质素作为分散剂或添加剂的印刷凝胶。
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公开(公告)号：US4355996A
公开(公告)日：1982-10-26
申请号：US240279
申请日：1981-03-04
申请人： Peter Dilling , Gerald Prazak
发明人： Peter Dilling , Gerald Prazak
CPC分类号： C09B67/0086
摘要： Improved sulfonated lignin surfactants are provided for use as dispersants in dyestuffs. The process for providing the improved surfactants relates to using metals and borate salts to react with the azo dye reducing dihydroxy functions of the lignin molecule through chelation and ester formation mechanisms thereby inhibiting the lignin's azo dye reducing characteristics.
摘要翻译： 提供改进的磺化木质素表面活性剂用作染料中的分散剂。 提供改进的表面活性剂的方法涉及使用金属和硼酸盐通过螯合和酯形成机理与木质素分子的偶氮染料还原二羟基官能团反应，从而抑制木质素的偶氮染料还原特性。
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公开(公告)号：US4244729A
公开(公告)日：1981-01-13
申请号：US693876
申请日：1976-06-08
摘要： A sustained release composition is disclosed which provides an improved carrier for an organic pesticide. The improved carrier is a reversibly swellable lignin gel made by cross-linking an alkali lignin with epichlorohydrin using particular conditions.
摘要翻译： 公开了持续释放组合物，其提供了有机农药的改进的载体。 改进的载体是通过使用特定条件将碱性木质素与表氯醇交联而制得的可逆膨胀的木质素凝胶。
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公开(公告)号：US4244728A
公开(公告)日：1981-01-13
申请号：US654884
申请日：1976-02-03
摘要： Disclosed herein are cross-linked lignin gels which have been found useful as pesticide carriers in controlled release pesticide systems. The carrier is a highly reswellable cross-linked lignin gel prepared by reacting alkali lignin with from 1 mole to 10 moles of cross-linking agent, such as formaldehyde, per 1,000 grams of lignin. An aqueous solution of lignin and the cross-linking agent is reacted at elevated temperatures until cross-linking occurs to the point where a discernible increase in viscosity takes place and the gel is formed. The gels are allowed to dehydrate, and the pesticide in an amount from 0.1:1.0 to 2:1 (pesticide to carrier) is included by reswelling the dehydrated gel in an aqueous solution of the pesticide.
摘要翻译： 本文公开了交联的木质素凝胶，其被发现可用作控释农药体系中的农药载体。 载体是通过使碱木质素与每摩尔木质素1摩尔至10摩尔的交联剂如甲醛反应而制备的高度可重熔的交联木质素凝胶。 木质素和交联剂的水溶液在升高的温度下反应直到交联发生到发生可见的粘度增加并形成凝胶的程度。 将凝胶脱水，将农药的水溶液中的脱水凝胶再溶解，包括0.1：1.0至2：1（农药至载体）的农药。
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