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公开(公告)号：US20040171891A1
公开(公告)日：2004-09-02
申请号：US10739086
申请日：2003-12-19
发明人： Bernhard Scholz , Franz Nierlich , Dieter Reusch , Silvia Santiago Fernandez , Andreas Beckmann , Wilfried Buschken , Alfred Kaizik
IPC分类号： C07C029/06
摘要： The invention relates to a process for preparing tert-butanol by reaction of a homogeneous mixture comprising water, tert-butanol and an isobutene-containing hydrocarbon mixture over an acidic ion-exchange resin at from 30 to 120null C., wherein the homogeneous mixture contains, at a proportion by mass of isobutene of above 10%, from 30 to 80% of the maximum amount of water made possible by the solubility of water in the mixture of tert-butanol and the isobutene-containing hydrocarbon mixture.
摘要翻译： 本发明涉及一种通过酸性离子交换树脂在30〜120℃下由包含水，叔丁醇和含异丁烯的烃混合物的均匀混合物反应制备叔丁醇的方法，其中均匀混合物 以大于10％的异丁烯的比例含有由水在叔丁醇和含异丁烯的烃混合物的混合物中的溶解度而产生的最大量的水的30至80％。
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2.发明申请公开(公告)号：US20010023306A1
公开(公告)日：2001-09-20
申请号：US09789571
申请日：2001-02-22
IPC分类号： C07C045/49
CPC分类号： C07C45/50 , C07C29/141 , C07C47/21 , C07C31/125
摘要： The present invention is a process for preparing C4-25 aldehydes by hydroformylating the corresponding C3-24 olefins in the presence of a cobalt hydroformylation catalyst, and catalytically decomposing the formic acid formed in the hydroformylation reaction or in the subsequent catalyst work-up. The aldehydes so produced may be hydrogenated to form alcohols.
摘要翻译： 本发明是通过在钴加氢甲酰化催化剂存在下对相应的C3-24烯烃进行加氢甲酰化，催化分解在加氢甲酰化反应中形成的甲酸或随后的催化剂后处理来制备C4-25醛的方法。 如此生产的醛可以被氢化以形成醇。
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公开(公告)号：US20030114718A1
公开(公告)日：2003-06-19
申请号：US10014517
申请日：2001-12-14
发明人： Cord Knoop , Bernhard Scholz , Alfred Kaizik , Dietmar Gubisch , Joachim Schuler , Walter Totsch , Wilfried Buschken
IPC分类号： C07C029/44
CPC分类号： C07C29/141 , C07C31/125
摘要： The present invention provides a process, which includes: in a homogeneous liquid phase including water, and over a fixed-bed catalyst, continuously hydrogenating at least one hydroformylation product obtained from a hydroformylation of one or more C4-16 olefins to produce at least one output mixture; wherein the fixed-bed catalyst includes at least one element of transition group eight of the Periodic Table of the Elements; wherein the output mixture includes at least one corresponding alcohol and from 0.05 to 10% by weight of water; and wherein in a steady-state operation of the process, from 3 to 50% more hydrogen is fed to the hydrogenation than is consumed by the hydrogenation.
摘要翻译： 本发明提供了一种方法，其包括：在均匀的液相中包括水，并且在固定床催化剂上，连续氢化由一种或多种C 4-6-16烯烃的加氢甲酰化得到的至少一种加氢甲酰化产物，以产生至少一种 输出混合物 其中所述固定床催化剂包括所述元素周期表的过渡组8的至少一个元素; 其中所述输出混合物包括至少一种相应的醇和0.05至10重量％的水; 并且其中在该方法的稳态操作中，比氢化消耗更多的氢被加入到氢化中3至50％以上。
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4.发明申请Process for the hydroformylation of higher olefins using cobalt compounds as catalyst 有权使用钴化合物作为催化剂的高级烯烃的羰基化方法公开(公告)号：US20030032843A1
公开(公告)日：2003-02-13
申请号：US10200752
申请日：2002-07-24
发明人： Stefan Drees , Bernhard Scholz , Alfred Kaizik , Walter Toetsch , Wilfried Bueschken , Martin Trocha
IPC分类号： C07C045/00 , C09K003/00
CPC分类号： C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： Olefins having from 5 to 24, in particular from 5 to 12, carbon atoms are hydroformylated by reacting an olefin or a mixture of olefins in the presence of an unmodified cobalt catalyst in a single-stage process in a reactor at a temperature of from 100null C. to 220null C. and a pressure of from 100 bar to 400 bar, to obtain an aldehyde, an alcohol or a mixture thereof. An aqueous bottom phase and an organic phase are present in the reactor, the aqueous bottom phase is mixed with the organic phase, and a concentration of the cobalt catalyst, calculated as metallic cobalt, in the aqueous bottom phase is in the range from 0.4 to 1.7% by mass based on the total weight of the aqueous bottom phase. A level of the aqueous bottom phase in the reactor is kept constant during steady-state operation.
摘要翻译： 具有5至24个，特别是5至12个碳原子的烯烃通过使烯烃或烯烃混合物在未改性的钴催化剂存在下在反应器中的单级方法中在100℃的温度下进行加氢甲酰化 ℃至220℃，压力为100巴至400巴，得到醛，醇或其混合物。 含水底相和有机相存在于反应器中，底部水相与有机相混合，在底部水相中以钴金属计算的钴催化剂浓度在0.4至 相对于底部水相的总重量为1.7质量％。 在稳态运行期间，反应器中的底部水相的水平保持恒定。
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公开(公告)号：US20020028974A1
公开(公告)日：2002-03-07
申请号：US09904893
申请日：2001-07-16
发明人： Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
IPC分类号： C07C045/49 , C07C029/136
CPC分类号： C07C45/50 , C07C29/16 , C07C31/125 , C07C47/02
摘要： Olefins are hydroformylated to give alcohols and/or aldehydes in a plurality of hydroformylation stages, each of which comprises: a) hydroformylating olefins having a carbon atom content of 6 to 24 carbon atoms in the presence of a cobalt- or rhodium catalyst in a reactor to the point of conversion of olefin reactant to product of 20 to 98%; b) removing the catalyst from the resulting liquid discharged from the reactor; c) separating the resulting liquid hydroformylation mixture into a low-boiler fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols; and d) reacting the olefins present in the low-boiler fraction in subsequent process stages comprising steps a, b and c and combining the bottoms fractions of process steps c) of all process stages.
摘要翻译： 烯烃被加氢甲酰化以在多个加氢甲酰化阶段中产生醇和/或醛，其各自包括：a）在反应器中的钴或铑催化剂存在下，碳原子含量为6至24个碳原子的烯烃加氢甲酰化 到烯烃反应物的转化率为20〜98％的产物; b）从反应器排出的所得液体中除去催化剂; c）将所得液体加氢甲酰化混合物分离成包含烯烃和链烷烃的低沸点馏分，以及包含醛和/或醇的塔底馏分; 和d）使包含步骤a，b和c的后续工艺阶段中存在于低沸点馏分中的烯烃反应，并组合所有工艺阶段的工艺步骤c）的底部馏分。
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