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公开(公告)号：US20150185153A1
公开(公告)日：2015-07-02
申请号：US14575381
申请日：2014-12-18
发明人： Li Zhang , Li Jiang , Jianhong Zhang , Hongqiu Wang , Yumin Yi
IPC分类号： G01N21/65
CPC分类号： G01N21/65 , G01N21/658
摘要： Embodiments of the present invention disclose a pesticide residue detection method, comprising the steps: (a) irradiating a sample to be detected by an exciting light and collecting a Raman scattered light from the sample; (b) acquiring a Raman spectrum of the sample from the collected Raman scattered light; and (c) comparing the Raman spectrum with reference Raman spectra for known pesticides in a reference Raman library to determine composition and concentration of the pesticide residue in the sample. The method may achieve effective, convenient and accurate inspection of the pesticide residue in foods, in particular suitable for rapid detection.
摘要翻译： 本发明的实施方式公开了农药残留检测方法，其特征在于，包括以下步骤：（a）用激发光照射被检测体，从所述样品收集拉曼散射光; （b）从所收集的拉曼散射光中获取样品的拉曼光谱; 和（c）将参考拉曼文库中的已知农药的拉曼光谱与参考拉曼光谱进行比较，以确定样品中农药残留的组成和浓度。 该方法可以有效，方便，准确地检测食品中的农药残留，特别适合快速检测。
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公开(公告)号：US09250180B2
公开(公告)日：2016-02-02
申请号：US14495233
申请日：2014-09-24
发明人： Zhiqiang Chen , Li Zhang , Jianhong Zhang , Hongqiu Wang , Ziran Zhao , Yumin Yi , Jianping Gu , Qingping Huang
CPC分类号： G01N21/47 , G01J3/44 , G01N21/65 , G01N21/658 , G01N33/15
摘要： A raman spectrum measuring method for drug inspection is provided, comprising: measuring raman spectrum of a sample to be inspected to acquire an original raman spectrum curve of the sample; determining whether the original raman spectrum curve has a characterizing portion, and if not, measuring a mixture of the sample and an enhancing agent to acquire an enhanced raman spectrum curve of the sample; and if the original raman spectrum curve of the sample to be inspected has a characterizing portion, comparing the original raman spectrum curve of the sample with data in an original raman spectrum database of a drug to determine whether the sample contains the drug, otherwise, comparing the enhanced raman spectrum curve of the sample with data in an enhanced raman spectrum database of the drug to determine whether the sample to be inspected contains the drug.
摘要翻译： 提供了用于药物检查的拉曼光谱测量方法，包括：测量被检样品的拉曼光谱以获得样品的原始拉曼光谱曲线; 确定原始拉曼光谱曲线是否具有特征部分，如果不是，则测量样品和增强剂的混合物以获得样品的增强的拉曼光谱曲线; 如果要检查的样本的原始拉曼光谱曲线具有特征部分，则将样品的原始拉曼光谱曲线与药物的原始拉曼光谱数据库中的数据进行比较，以确定样品是否含有药物，否则比较 增强的拉曼光谱曲线的样品与增强的拉曼光谱数据库中的数据，以确定待检样品是否含有药物。
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3.发明授权Raman spectroscopy method of measuring melamine contents in dairy products having different matrixes 有权测量具有不同基质的乳制品中三聚氰胺含量的拉曼光谱法公开(公告)号：US08891081B1
公开(公告)日：2014-11-18
申请号：US14145454
申请日：2013-12-31
发明人： Zhiqiang Chen , Li Zhang , Jianhong Zhang , Hongqui Wang , Ziran Zhao , Jianping Gu , Zhiming Wang , Qingping Huang , Yumin Yi
CPC分类号： G01N21/65
摘要： A raman spectroscopy method of measuring melamine contents in dairy products having different matrixes. The method includes: (a) establishing a database of characteristic curves of dairy products having different matrixes; (b) taking several copies of the dairy products having one certain unknown matrix and adding melamine standard solutions having different concentrations therein, to obtain a series of dairy product samples in which the relative concentrations of the melamine are known; (c) performing raman spectrum testing analysis and obtaining corresponding characteristic peak intensities to obtain a slope of the characteristic curve showing variation of the characteristic peak intensities with the relative concentrations of the melamine; (d) searching the database of step (a) using the slope of the characteristic curve of the dairy product samples to find a matching characteristic curve, and (e) calculating concentration of melamine in the dairy products by using the matched characteristic curve and the characteristic peak intensity.
摘要翻译： 测量具有不同基质的乳制品中三聚氰胺含量的拉曼光谱法。 该方法包括：（a）建立具有不同矩阵的乳制品特征曲线数据库; （b）取几份具有一定未知基质的乳制品，并加入其中浓度不同的三聚氰胺标准溶液，以获得其中已知三聚氰胺的相对浓度的一系列乳制品样品; （c）进行拉曼光谱测试分析并获得相应的特征峰强度，以获得特征曲线的斜率，显示特征峰强度与三聚氰胺的相对浓度的变化; （d）使用乳制品样品的特征曲线的斜率来搜索步骤（a）的数据库，以找到匹配的特征曲线，以及（e）通过使用匹配的特征曲线计算乳制品中三聚氰胺的浓度， 特征峰强度。
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公开(公告)号：US10775310B2
公开(公告)日：2020-09-15
申请号：US16232339
申请日：2018-12-26
发明人： Haihui Liu , Hongqiu Wang , Jianhong Zhang
摘要： A detection apparatus, including: a laser configured to emit laser light towards an object to be detected; a Raman spectrometer configured to receive Raman light from the object; an imaging device configured to obtain an image of the object; a light sensor configured to receive light reflected and scattered by the object under irradiation of the laser light, and to determine the power of the received light; and a controller configured to control an operation of the detection apparatus based on the image obtained by the imaging device and the power determined by the light sensor. A detection method using the detection apparatus.
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公开(公告)号：US10267678B2
公开(公告)日：2019-04-23
申请号：US14577748
申请日：2014-12-19
发明人： Ziran Zhao , Jianhong Zhang , Hongqiu Wang , Weiwei Wang , Zhiming Wang , Yumin Yi
摘要： Embodiments of the present invention provide a Raman spectroscopic inspection method, comprising the steps of: measuring a Raman spectrum of an object to be inspected successively to collect a plurality of Raman spectroscopic signals; superposing the plurality of Raman spectroscopic signals to form a superposition signal; filtering out a florescence interfering signal from the superposition signal; and identifying the object to be inspected on basis of the superposition signal from which the florescence interfering signal has been filtered out. By means of the above method, a desired Raman spectroscopic signal may be acquired by removing the interference caused by a florescence signal from a Raman spectroscopic inspection signal of the object. It may inspect correctly the characteristics of the Raman spectrum of the object so as to identify the object effectively.
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公开(公告)号：US10663393B2
公开(公告)日：2020-05-26
申请号：US15858274
申请日：2017-12-29
发明人： Haihui Liu , Hongqiu Wang , Yumin Yi , Jianhong Zhang , Ankai Wang
摘要： An embodiment of the present disclosure provides a spectrum inspecting apparatus. The apparatus includes a laser source; a focusing cylindrical lens configured to converge a light beam onto a sample; a light beam collecting device configured to collect a light beam signal, which is excited by the light beam, from the sample, so as to form a strip-shaped light spot; a slit configured to receive the collected light beam and couple it to downstream of a light path; a collimating device; a dispersing device configured to disperse the collected light beam so as to form a plurality of sub-beams having different wavelengths; an imaging device configured to image the sub-beams on the photon detector array respectively, wherein the light beam emitted from the laser source has a rectangular cross-section, the strip-shaped light spot impinges on the slit and its length is smaller than a length of the slit.
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7.发明申请公开(公告)号：US20200088645A1
公开(公告)日：2020-03-19
申请号：US16473192
申请日：2018-02-13
发明人： Jianhong Zhang , Hongqiu Wang , Rui Fan , Haihui Liu
摘要： There are provided a Raman spectrum inspection apparatus (100a) and a method of monitoring detection security of the same. The Raman spectrum inspection apparatus (100a) includes: an optical device (20) configured to guide exciting light (11) to a sample (30) and collect a light signal from the sample (30); a spectrometer (40) configured to split the light signal collected by the optical device (20) so as to generate a Raman spectrum of the sample (30) which is detected; and a security monitor configured to monitor a security state of the sample (30) during irradiating of the exciting light (11) from the laser (10) onto the sample (30), and to provide a security indicating signal representing whether or not the sample (30) is damaged due to being irradiated by the exciting light (11).
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公开(公告)号：US20180188158A1
公开(公告)日：2018-07-05
申请号：US15858274
申请日：2017-12-29
发明人： Haihui Liu , Hongqiu Wang , Yumin Yi , Jianhong Zhang , Ankai Wang
CPC分类号： G01N21/255 , G01N21/39 , G01N21/4795 , G01N21/65 , G01N2021/3129 , G01N2021/3137 , G01N2021/393 , G01N2021/399
摘要： An embodiment of the present disclosure provides a spectrum inspecting apparatus. The apparatus includes a laser source; a focusing cylindrical lens configured to converge a light beam onto a sample; a light beam collecting device configured to collect a light beam signal, which is excited by the light beam, from the sample, so as to form a strip-shaped light spot; a slit configured to receive the collected light beam and couple it to downstream of a light path; a collimating device; a dispersing device configured to disperse the collected light beam so as to form a plurality of sub-beams having different wavelengths; an imaging device configured to image the sub-beams on the photon detector array respectively, wherein the light beam emitted from the laser source has a rectangular cross-section, the strip-shaped light spot impinges on the slit and its length is smaller than a length of the slit.
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9.发明申请公开(公告)号：US20180180551A1
公开(公告)日：2018-06-28
申请号：US15853074
申请日：2017-12-22
发明人： Jianhong Zhang , Ankai Wang , Hongqiu Wang , Rui Fan , Huacheng Feng
IPC分类号： G01N21/65 , G01J5/00 , G01N21/01 , G05B19/4065 , G01J3/44
CPC分类号： G01N21/65 , G01J3/44 , G01J3/4412 , G01J5/0003 , G01N21/01 , G01N2201/06113 , G01N2201/063 , G02B27/141 , G05B19/4065 , G05B2219/49353
摘要： A Raman spectrum inspection apparatus and a security monitoring method for a Raman spectrum inspection apparatus are provided. The Raman spectrum inspection apparatus includes: a laser device configured to emit an exciting light; an optical device configured to guide the exciting light to an object to be detected and collect a light signal from the object; a spectrometer configured to split the collected light signal to generate a Raman spectrum of the object; and a security detector configured to detect an infrared light emitted from the object.
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公开(公告)号：US09465189B2
公开(公告)日：2016-10-11
申请号：US14573387
申请日：2014-12-17
发明人： Ziran Zhao , Jianhong Zhang , Hongqiu Wang , Dong Lin , Shixin Zhang , Bin Hu , Yumin Yi
摘要： An embodiment of the present invention provides an optical probe, comprising: a first sleeve in which a lens is contained, the first sleeve having a light transmission aperture from which an exciting light enters the first sleeve; a second sleeve movably engaged with the first sleeve and having a detection window from which the exciting light having passed through the first sleeve and focused by the lens exits the optical probe, the second sleeve being capable of moving with respect to the first sleeve from a first detection position to a second detection position or from the second detection position to the first detection position; and a positioning member configured to position the second sleeve at the first detection position or the second detection position with respect to the first sleeve.
摘要翻译： 本发明的一个实施例提供了一种光学探针，包括：第一套筒，其中容纳透镜，第一套筒具有透光孔，激发光从该光透射孔进入第一套筒; 第二套筒可移动地与第一套筒接合并且具有检测窗口，已经穿过第一套筒并被透镜聚焦的激发光从该检测窗口离开光学探针，第二套筒能够相对于第一套筒从一个 第一检测位置到第二检测位置或从第二检测位置到第一检测位置; 以及定位构件，其构造成将所述第二套筒相对于所述第一套筒定位在所述第一检测位置或所述第二检测位置。
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