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1.发明授权公开(公告)号：US10734660B2
公开(公告)日：2020-08-04
申请号：US15066574
申请日：2016-03-10
发明人： Dianne Atienza , Nilesh Dale
IPC分类号： H01M8/028 , H01M8/1004 , H01M8/1018 , H01M4/90 , H01M4/86
摘要： A membrane electrode assembly for a fuel cell comprises a proton exchange membrane having an anode side and a cathode side. An anode catalyst layer is on the anode side of the proton exchange membrane and a cathode catalyst layer is on the cathode side of the proton exchange membrane. Each of the anode catalyst layer and the cathode catalyst layer comprises a metal alloy. A gas diffusion layer is on each of the anode catalyst layer and the cathode catalyst layer opposite the proton exchange membrane. A sacrificial intercalating agent is between the proton exchange membrane and one of the anode catalyst layer and the cathode catalyst layer, the sacrificial intercalating agent having sulfonate sites that attract metal cations resulting from dissolution of the metal alloy prior to the metal cations reaching the proton exchange membrane.
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公开(公告)号：US10033046B2
公开(公告)日：2018-07-24
申请号：US15339495
申请日：2016-10-31
发明人： Cenk Gumeci , Dianne Atienza
摘要： Cathodes for lithium-sulfur batteries inhibit the parasitic polysulfide shuttle effect. The cathodes contain an active material support having a transition metal-containing nitrogen doped carbon developed to host the sulfur and suppress the diffusion of polysulfides into the electrolyte by retaining them in the high surface area nanostructured pores of the carbon while the transition metals serve as anchors for the soluble species due to the transition metals' affinity for sulfur. The cathodes 12 are gram scalable and have high surface area and high conductivity. The cathode active material support includes a nitrogen-containing polymer structure doped with a sulfide precursor of one or more transition metals selected from the group containing Fe, V, Mo, W, Co, Ni, Cu and Zn.
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公开(公告)号：US20190097249A1
公开(公告)日：2019-03-28
申请号：US15716222
申请日：2017-09-26
发明人： Dianne Atienza
IPC分类号： H01M8/1213 , H01M4/86 , H01M4/90 , H01M8/0252 , H01M8/1246
摘要： Implementations of a solid oxide fuel cell (SOFC) include a current collector, an electrolyte layer, and an anode. The electrolyte layer may be a solid electrolyte layer. The anode may include one or more micro-pathways that extend between the current collector and the electrolyte layer. The micro-pathways may be constructed of yttria stabilized zirconia (YSZ). Each micro-pathway is in contact with the electrolyte layer and provides a direct pathway between the electrolyte layer and the current collector. The direct pathway created by the micro-pathways may be the shortest distance between the electrolyte layer and the current collector. Each of the one or more micro-pathways may be coated with electrocatalyst nanoparticles. A barrier material may be disposed between each micro-pathway and the current collector to prevent contact between the current collector and the electrocatalyst nanoparticles.
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公开(公告)号：US20180123136A1
公开(公告)日：2018-05-03
申请号：US15339495
申请日：2016-10-31
发明人： Cenk Gumeci , Dianne Atienza
CPC分类号： H01M4/668 , H01M4/0471 , H01M4/13 , H01M4/139 , H01M4/366 , H01M4/38 , H01M10/0525 , H01M2004/028
摘要： Cathodes for lithium-sulfur batteries inhibit the parasitic polysulfide shuttle effect. The cathodes contain an active material support having a transition metal-containing nitrogen doped carbon developed to host the sulfur and suppress the diffusion of polysulfides into the electrolyte by retaining them in the high surface area nanostructured pores of the carbon while the transition metals serve as anchors for the soluble species due to the transition metals' affinity for sulfur. The cathodes 12 are gram scalable and have high surface area and high conductivity. The cathode active material support includes a nitrogen-containing polymer structure doped with a sulfide precursor of one or more transition metals selected from the group containing Fe, V, Mo, W, Co, Ni, Cu and Zn.
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5.发明申请公开(公告)号：US20170263948A1
公开(公告)日：2017-09-14
申请号：US15066574
申请日：2016-03-10
发明人： Dianne Atienza , Nilesh Dale
IPC分类号： H01M8/028 , H01M4/86 , H01M4/90 , H01M8/1004 , H01M8/1018
摘要： A membrane electrode assembly for a fuel cell comprises a proton exchange membrane having an anode side and a cathode side. An anode catalyst layer is on the anode side of the proton exchange membrane and a cathode catalyst layer is on the cathode side of the proton exchange membrane. Each of the anode catalyst layer and the cathode catalyst layer comprises a metal alloy. A gas diffusion layer is on each of the anode catalyst layer and the cathode catalyst layer opposite the proton exchange membrane. A sacrificial intercalating agent is between the proton exchange membrane and one of the anode catalyst layer and the cathode catalyst layer, the sacrificial intercalating agent having sulfonate sites that attract metal cations resulting from dissolution of the metal alloy prior to the metal cations reaching the proton exchange membrane.
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公开(公告)号：US20160204447A1
公开(公告)日：2016-07-14
申请号：US14592181
申请日：2015-01-08
发明人： Nilesh Dale , Kan Huang , Ellazar Niangar , Dianne Atienza
CPC分类号： H01M4/925 , H01M4/8605 , H01M4/923 , H01M8/0234 , H01M8/0239 , H01M8/0243 , H01M2008/1095
摘要： A membrane electrode assembly includes a membrane, a first layer contacting the membrane and consisting essentially of catalyst particles comprising non-carbon metal oxide support particles and precious metal particles deposited on the non-carbon metal oxide support particles, a second layer of carbon particles on the first layer and a gas diffusion layer in contact with the second layer.
摘要翻译： 膜电极组件包括膜，第一层与膜接触并且基本上由催化剂颗粒组成，催化剂颗粒包含非碳金属氧化物载体颗粒和沉积在非碳金属氧化物载体颗粒上的贵金属颗粒，第二层碳颗粒 第一层和与第二层接触的气体扩散层。
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公开(公告)号：US20160204442A1
公开(公告)日：2016-07-14
申请号：US14592166
申请日：2015-01-08
发明人： Nilesh Dale , Kan Huang , Ellazar Niangar , Dianne Atienza
CPC分类号： H01M4/8652 , H01M4/8673 , H01M4/9075 , H01M4/925
摘要： A composite electrocatalyst layer comprises catalyst particles having non-carbon metal oxide support particles and precious metal particles deposited on the non-carbon metal oxide support particles. Carbon particles are mixed with, but discreet from, the catalyst particles. The catalyst particles can be titanium dioxide and ruthenium dioxide support with platinum deposited on the support. Electrodes are produced using the composite electrocatalyst.
摘要翻译： 复合电催化剂层包括具有非碳金属氧化物载体颗粒和沉积在非碳金属氧化物载体颗粒上的贵金属颗粒的催化剂颗粒。 碳颗粒与催化剂颗粒混合，但离开催化剂颗粒。 催化剂颗粒可以是二氧化钛和二氧化钛载体，铂沉积在载体上。 使用复合电催化剂生产电极。
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公开(公告)号：US11108047B2
公开(公告)日：2021-08-31
申请号：US16263520
申请日：2019-01-31
发明人： Dianne Atienza
摘要： A conductive polymer material is provided that includes an electrically conducting monomer and a zwitterionic sulfate chemically attached to the monomer. The electrically conducting monomer is at least one of acetylene, pyrrole, thiophene, phenylenevinylene, paraphenylene and aniline. The zwitterionic sulfonate includes an imidazolium group or an ammonium group. A solid-state battery is also provided that includes the conductive polymer material in an electrode. The solid-state battery includes an anode, a cathode and a solid electrolyte disposed between the anode and the cathode. At least one of the anode and the cathode includes the conductive polymer material.
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公开(公告)号：US10910662B2
公开(公告)日：2021-02-02
申请号：US15716222
申请日：2017-09-26
发明人： Dianne Atienza
IPC分类号： H01M8/0252 , H01M8/1213 , H01M4/86 , H01M8/1246 , H01M4/90 , H01M8/021 , H01M8/124
摘要： Implementations of a solid oxide fuel cell (SOFC) include a current collector, an electrolyte layer, and an anode. The electrolyte layer may be a solid electrolyte layer. The anode may include one or more micro-pathways that extend between the current collector and the electrolyte layer. The micro-pathways may be constructed of yttria stabilized zirconia (YSZ). Each micro-pathway is in contact with the electrolyte layer and provides a direct pathway between the electrolyte layer and the current collector. The direct pathway created by the micro-pathways may be the shortest distance between the electrolyte layer and the current collector. Each of the one or more micro-pathways may be coated with electrocatalyst nanoparticles. A barrier material may be disposed between each micro-pathway and the current collector to prevent contact between the current collector and the electrocatalyst nanoparticles.
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公开(公告)号：US20200251737A1
公开(公告)日：2020-08-06
申请号：US16263520
申请日：2019-01-31
发明人： Dianne Atienza
摘要： A conductive polymer material is provided that includes an electrically conducting monomer and a zwitterionic sulfate chemically attached to the monomer. The electrically conducting monomer is at least one of acetylene, pyrrole, thiophene, phenylenevinylene, paraphenylene and aniline. The zwitterionic sulfonate includes an imidazolium group or an ammonium group. A solid-state battery is also provided that includes the conductive polymer material in an electrode. The solid-state battery includes an anode, a cathode and a solid electrolyte disposed between the anode and the cathode. At least one of the anode and the cathode includes the conductive polymer material.
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