Abstract:
A lithium ion secondary battery having high energy density and being excellent in cycle characteristics is provided. The present invention relates to a lithium ion secondary battery comprising: a negative electrode active material comprising a material comprising silicon as a constituent element; and an electrolyte solution comprising: a non-aqueous solvent comprising a fluorinated ether compound, an open-chain sulfone compound, and a cyclic carbonate compound, and a supporting salt comprising LiPF6, lithium bis(fluorosulfonyl)imide, and lithium bis(oxalato)borate (LiBOB); wherein the content of LiBOB in the electrolyte solution is 0.2 mass % or more.
Abstract:
A charging apparatus comprises a charge control unit. The charge control unit charges a secondary battery at a first current value until the voltage of the secondary battery reaches a predetermined first voltage value. The charge control unit, on detecting that the voltage has reached the first voltage value, performs control to charge the secondary battery at a second current value that is lower than the first current value, until a predetermined second voltage value is reached.
Abstract:
A purpose of one embodiment of the present invention is to provide a lithium ion secondary battery that has improved life-span characteristics. The first lithium ion secondary battery of the present invention comprises an electrolyte solution comprising a sulfone compound, a fluorinated ether compound and LiN(FSO2)2, and a negative electrode comprising a silicon material, wherein a content of LiN(FSO2)2 in the electrolyte solution is more than 5 weight % and 20 weight % or less.
Abstract:
The purpose of the present invention is to provide a secondary cell in which a decrease in energy density is inhibited. In order to achieve this purpose, this secondary cell has a positive electrode in which a positive electrode active material layer is provided on a positive electrode collector, and a negative electrode in which a negative electrode active material layer is provided on a negative electrode collector; the positive electrode active material layer and the negative electrode active material layer are laminated so as to face each other with a separator interposed therebetween; the negative electrode active material layer has a greater area than the positive electrode active material layer; and a thin section is provided in at least a part of the negative electrode active material layer at a location where the negative electrode active material layer does not face the positive electrode active material layer.
Abstract:
A purpose of the present invention is to provide a lithium ion secondary battery which has further improved life characteristics. The lithium ion secondary battery of the present invention is characterized by comprising a positive electrode comprising a positive electrode active material that operates at 4.5 V or more with respect to lithium, and an electrolyte solution comprising an electrolyte solvent comprising a fluorinated ether, a cyclic sulfonic acid ester and LiN(FSO2)2.
Abstract:
A purpose of the present invention is to provide a lithium ion secondary battery having improved battery characteristics. The lithium ion secondary battery according to the present invention comprises a negative electrode comprising a negative electrode active material comprising a silicon material and an electrolyte solution comprising an electrolyte solvent comprising an open chain sulfone compound, a fluorinated cyclic carbonate and an open chain carbonate and a supporting salt comprising LiN(FSO2)2.
Abstract:
In order to provide a negative electrode for a lithium secondary battery providing a high electrode density, i.e., a high volumetric energy density, and improved in life characteristics and a lithium secondary battery using the negative electrode, the present invention uses a negative electrode for a lithium secondary battery, in which a negative electrode active material layer (2a, 2b) formed on a negative electrode current collector 3 comprises at least first particles 4, second particles 5 and a binder 6, the first particles 4 are formed of SiOχ (0
Abstract:
A lithium ion secondary battery excellent in cycle characteristics and rate characteristics is provided. The present invention relates to a lithium secondary battery having an electrolyte solution comprising one or more compounds selected from a fluorinated ether and a fluorinated phosphate ester and a separator comprising an aramid resin.
Abstract:
The purpose of the present invention is to provide a lithium secondary battery which has improved service life characteristics by suppressing a decomposition reaction of the electrolyte solution in the field of batteries that operate at high voltages or are assumed to be used at high temperatures for a long period of time. The present invention relates to an electrolyte solution for a secondary, which is characterized by containing a sulfone compound, a fluorine-containing cyclic acetal compound and a cyclic carbonate in a specific composition; and a secondary battery which uses this electrolyte solution for a secondary battery.
Abstract:
The purpose of the present embodiment is to provide a lithium secondary battery which is assumed to be operated at a high voltage or to be used at high temperatures for a long period of time, and which has improved life characteristics by suppressing a decomposition reaction of the electrolyte solution. The present embodiment relates to an electrolyte solution for a secondary battery containing a sulfone compound, a fluorine containing ether and an acid anhydride at a specific composition, and a secondary battery which uses this electrolyte solution for a secondary battery.