Abstract:
A phthalocyanine compound of a structural formula of phthalocyanine represented by the general formula (1): ##STR1## wherein 1 to 8 of a total 16 positions are substituted with a phenoxy group, the phenoxy group at either of the ortho positions is substituted with an aryl group which may be substituted, all the atoms in the aryl group and the substituents at the residual ortho positions excluding the hydrogen atoms assume a total atomic radius of not less than 6.0 .ANG., and a central atom group M contains a metal atom of not less than trivalence, a bromine-substituent of the compound, a phthalocyanine composition comprising the phthalocyanine compound and the bromine atom-containing phthalocyanine compound, and an optical recording medium containing it in a recording layer.
Abstract:
A photosensitive resin coloring composition for use in a color filter containing a resin and a dye. The dye is manufactured with one member selected from the class consisting of a combination of (A)+(B) groups, a combination of (A)+(C) groups, a combination of (B)+(C) groups, and a combination of (A)+(B)+(C) groups, wherein (A) represents a group of quinizarine compounds, (B) represents a group of anthraquinone compounds, and (C) represents a group of phthalocyanine compounds.
Abstract:
A method for producing a novel phthalocyanine compound which excels in yield and purity, allows no introduction of a chlorine atom into the phthalocyanine skeleton, and possesses relatively bulky substituents is provided. This method is characterized by causing an orthophthalonitrile compound having a substituent exhibiting smaller .sigma..sub.p values than .sigma..sub.m values in the Hammett's rule to react with a metal oxide in the presence of a compound forming in the aqueous solution thereof at 25.degree. C. an acid or conjugate acid having a dissociation index pKa (the logarithmic value of the reciprocal of the dissociation constant of the acid or conjugate acid) of not more than 7.0.
Abstract:
A benzene halide is produced with high purity at a high yield by heating a halogen-substituted benzene carboxylic acid in the presence of a basic catalyst in a solvent.
Abstract:
2,3,5,6-Tetrafluorophenyl (meth)acrylates represented by the general formula I: ##STR1## wherein R is H or CH.sub.3 and X is H or CN are disclosed. These compounds are obtained by the reaction of 4-cyano-substituted or unsubstituted 2,3,5,6-tetrafluorophenols with (meth)acrylic acid chloride.
Abstract:
This invention is to provide a novel quinizarin compound which has a quinizarin structure represented by a following formula (1) having one to four of the 5, 6, 7, and 8 positions and at least either the 6 or 7 position formed of at least one member selected from the class consisting of secondary amino groups, alkylthio groups, and optionally substituted phenylthio groups, and having the remaining positions thereof formed of at least one member selected from the class consisting of hydrogen atom, halogen atoms, amino group, hydroxy group, alkoxy groups, and optionally substituted phenoxy groups, a method for the production thereof, and a dye, an electrophotographic grade color toner composition, a thermal-transfer recording sheet, an optical recording medium, an ink jet grade ink composition and a color filter severally comprising the quinizarin compound. ##STR1##
Abstract:
A novel fluorine-containing phthalocyanine compound represented by the following formula (I): ##STR1## wherein Y is ##STR2## wherein R.sub.1 and R.sub.2 are independently a hydrogen atom or a C1-C8 alkyl group; R.sub.3 and R.sub.4 are independently a C1-C8 alkyl group; X is a hydrogen atom, a C1-C4 alkyl group, a C1-C4 alkoxyl group or a halogen atom; Z is a hydrogen atom, a C1-C4 alkyl group, a C1-C4 alkoxyl group, a C1-C4 alkoxycarbonyl group or a halogen atom; W is a C1-C4 alkoxyl group; e, f, g, h and j are independently an integer of 1 or 2; n is an integer of 1 to 8; and p and q are independently an integer of 1 to 6; a to d are an integer of 0 to 2 with the proviso that the sum of a to d is 1 to 8; and M is a non-metal, a metal, a metal oxide, a metal carbonyl or a metal halide, and further, a method of producing a fluorine-containing phthalocyanine compound represented by the above formula (I).
Abstract:
A flash fixing toner comprising a binding resin, a coloring agent, and an infrared absorbent, the infrared absorbent having the largest absorption wavelength in the range of 750-1100 nm, and the infrared absorbent being solved in or being finely dispersed in the binding resin.
Abstract:
A nuclear halogenated aromatic compound possessing cyano groups is produced by a method using as a raw material an aromatic compound which possesses cyano groups and assumes a solid state at room temperature and subjecting the raw material to a procedure comprising a step of melting and transporting the compound by a means transport-melting, a step of vaporizing the compound, a step of mixing the compound with a halogen gas, and a step of causing the vapor of the compound to react with the halogen gas in vapor phase in the presence of a catalyst sequentially in the order mentioned, which comprises maintaining a content of a self-condensate of the aromatic compound possessing cyano groups which arise during the melting of the aromatic compound possessing cyano groups in a gas of the compound which reacts with the halogen gas to a level of not more than 2.5 mol % based on the compound. The catalyst used in the method is activated carbon such that the average pore radius thereof determined by the nitrogen adsorption method is not less than 12.2 .ANG. and the cumulative pore volume of the portion of the activated carbon having pore radiuses in the range of 5-100 .ANG. determined by the steam adsorption method is not less than 0.45 g/cc.
Abstract translation:具有氰基的核卤代芳族化合物是通过使用具有氰基并在室温下呈现固态的芳族化合物作为原料的方法制备的,并使原料经历包括熔融和输送化合物的步骤 通过输送熔融的方法,使化合物蒸发的步骤,将化合物与卤素气体混合的步骤以及在催化剂存在下使化合物的蒸气与气相反应的步骤 按照上述顺序依次进行,其包括将与卤素气体反应的化合物的气体中具有氰基的芳香族化合物熔融时产生的具有氰基的芳香族化合物的自缩合物的含量保持在一定水平 不大于2.5摩尔%。 该方法中使用的催化剂是活性炭,使得其通过氮吸附法测定的平均孔半径不小于12.2安培,并且具有孔半径的活性炭部分的累积孔体积在5-100范围内 蒸汽吸附法测定的ANGSTROM不低于0.45 g / cc。
Abstract:
An electrophotographic plate-making quality matrix plate provided on an electroconductive substrate thereof with a photosensitive layer formed of an alkali-soluble binder resin containing an organic photoelectroconductive compound, which matric plate is characterized by the fact that said organic photoelectroconductive compound is a zinc phthalocyanine represented by the general formula I: ##STR1## wherein R is a --SZ group (where Z is a phenyl group, a phenyl group substituted with an alkyl group of 1 to 5 carbon atoms, or a naphthyl group), and said binder resin is a copolymer obtained by polymerizing a monomer mixture comprising (a) at least one compound selected from the group consisting of hydroxyalkyl acrylates and hydroxyalkyl methacrylates, (b) at least one copolymerizable unsaturated carboxylic acid, (c) at least one styrene compound, and (d) at least one compound selected from among acrylic esters other than said hydroxyalkyl acryaltes of (a).