PROCESS FOR PRODUCTION OF CATHODE ACTIVE MATERIAL FOR LITHIUN ION SECONDARY BATTERY
    2.
    发明申请
    PROCESS FOR PRODUCTION OF CATHODE ACTIVE MATERIAL FOR LITHIUN ION SECONDARY BATTERY 有权
    用于生产用于锂离子二次电池的阴极活性材料的方法

    公开(公告)号:US20110033749A1

    公开(公告)日:2011-02-10

    申请号:US12606224

    申请日:2009-10-27

    Abstract: To provide a process for producing a surface modified lithium-containing composite oxide, which is excellent in discharge capacity, volume capacity density, safety, durability for charge and discharge cycles and an excellent rate property, at a low production cost. The present invention is characterized in that a process for producing a surface modified lithium-containing composite oxide, wherein a lithium titanium composite oxide is contained in the surface layer of particles of a lithium-containing composite oxide represented by the formula: LipNxMyOzFa, where N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, Sn, alkaline earth metal elements and transition metal elements other than Co, Mn and Ni, 0.9≦p≦1.3, 0.9≦x≦2.0, 0≦y≦0.1, 1.9≦z≦4.2, and 0≦a≦0.05, which comprises impregnating a solution having a lithium source and a titanium source dissolved therein, followed by heat treatment at a determined temperature, to obtain the surface modified lithium-containing composite oxide, wherein the titanium contained in the surface layer is from 0.01 to 1.95 mol %.

    Abstract translation: 为了提供一种生产成本低的放电容量,容量容量密度,安全性,充放电循环的耐久性和优异的速率特性的表面改性的含锂复合氧化物的方法。 本发明的特征在于一种表面改性的含锂复合氧化物的制造方法,其中,在下式表示的锂复合氧化物的表面层中含有锂钛复合氧化物,式中,N表示下式:LipNxMyOzFa,其中N 是选自Co,Mn和Ni中的至少一种元素,M是选自Al,Sn,碱土金属元素和Co,Mn和Ni以外的过渡金属元素中的至少一种元素,0.9 其中包括浸渍溶解有锂源和钛源的溶液,其中包括溶解在其中的锂源和溶解有钛源的溶液,随后 通过在确定的温度下进行热处理,得到表面改性的含锂复合氧化物,其中表面层中所含的钛为0.01〜1.95摩尔%。

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