Abstract:
To provide a process for producing a lithium-containing composite oxide for a positive electrode of a lithium secondary battery, which has a large volume capacity density, high safety, excellent durability for charge and discharge cycles and excellent low temperature characteristics.
Abstract:
To provide a process for producing a surface modified lithium-containing composite oxide, which is excellent in discharge capacity, volume capacity density, safety, durability for charge and discharge cycles and an excellent rate property, at a low production cost. The present invention is characterized in that a process for producing a surface modified lithium-containing composite oxide, wherein a lithium titanium composite oxide is contained in the surface layer of particles of a lithium-containing composite oxide represented by the formula: LipNxMyOzFa, where N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, Sn, alkaline earth metal elements and transition metal elements other than Co, Mn and Ni, 0.9≦p≦1.3, 0.9≦x≦2.0, 0≦y≦0.1, 1.9≦z≦4.2, and 0≦a≦0.05, which comprises impregnating a solution having a lithium source and a titanium source dissolved therein, followed by heat treatment at a determined temperature, to obtain the surface modified lithium-containing composite oxide, wherein the titanium contained in the surface layer is from 0.01 to 1.95 mol %.
Abstract:
The present invention provides a lithium-containing composite oxide for a positive electrode for a lithium secondary battery, which has a large volume capacity density and high safety, and excellent durability for charge and discharge cycles and charge and discharge rate property, and its production method.The lithium-containing composite oxide is represented by the general formula LipNxMyOzFa (where N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, Sn, alkaline earth metal elements and transition metal elements other than Co, Mn and Ni, 0.9≦p≦1.2, 0.965≦x
Abstract translation:本发明提供一种锂二次电池用正极用锂复合氧化物,其具有体积容量密度大,安全性高,充放电循环耐久性,充放电率特性及其制造方法 。 含锂复合氧化物由通式LipNxMyOzFa(其中N是选自Co,Mn和Ni中的至少一种元素)表示,M是选自Al,Sn,碱性中的至少一种元素 土壤金属元素和除Co,Mn和Ni之外的过渡金属元素,0.9 <= p <= 1.2,0.965 <= x <2.00,0