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公开(公告)号:US08722227B2
公开(公告)日:2014-05-13
申请号:US13975474
申请日:2013-08-26
Applicant: Massachusetts Institute of Technology
Inventor: Yet-Ming Chiang , W. Craig Carter , Bryan Y. Ho , Mihai Duduta , Pimpa Limthongkul
IPC: H01M4/36
CPC classification number: H01M8/188 , B60L11/1875 , B60L11/1898 , H01M8/20 , Y02E60/528 , Y02T10/705 , Y02T90/34
Abstract: Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.
Abstract translation: 描述了氧化还原流动装置,其中正极或负极活性材料中的至少一个是半固体或是冷凝离子存储电活性材料,并且其中至少一个电极活性材料被输送到 并且从发生电化学反应的组件产生电能。 半固体的电子导电性通过向悬浮液中添加导电颗粒和/或通过半固体中的固体的表面改性(例如,通过用更多的电子传导涂层材料涂覆固体以增加功率而增加) 的设备)。 公开了高能量密度和高功率氧化还原流量装置。 本文描述的氧化还原流动装置还可以包括一个或多个本发明的设计特征。 此外,还描述了用于氧化还原流动装置的发明化学物质。
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公开(公告)号:US20180034090A1
公开(公告)日:2018-02-01
申请号:US15618076
申请日:2017-06-08
Inventor: Yet-Ming Chiang , W. Craig Carter , Bryan Y. Ho , Mihai Duduta , Pimpa Limthongkul
CPC classification number: H01M8/188 , B60L50/72 , B60L58/27 , H01M8/20 , Y02E60/528 , Y02T10/705 , Y02T90/34
Abstract: Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.
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公开(公告)号:US20170200966A1
公开(公告)日:2017-07-13
申请号:US15387225
申请日:2016-12-21
Applicant: Massachusetts Institute of Technology
Inventor: Yet-Ming Chiang , William Henry Woodford , Frank Y. Fan , Zheng Li , Nir Baram , Kyle C. Smith , W. Craig Carter , Gareth H. McKinley , Ahmed Helal
CPC classification number: H01M8/188 , H01M4/382 , H01M4/5825 , H01M4/625 , H01M8/20 , H01M8/225 , H01M12/08 , Y02E60/128 , Y02E60/528
Abstract: The present invention generally relates to energy storage devices, and to metal sulfide energy storage devices in particular. Some aspects of the invention relate to energy storage devices comprising at least one flowable electrode, wherein the flowable electrode comprises an electroactive metal sulfide material suspended and/or dissolved in a carrier fluid. In some embodiments, the flowable electrode further comprises a plurality of electronically conductive particles suspended and/or dissolved in the carrier fluid, wherein the electronically conductive particles form a percolating conductive network. An energy storage device comprising a flowable electrode comprising a metal sulfide electroactive material and a percolating conductive network may advantageously exhibit, upon reversible cycling, higher energy densities and specific capacities than conventional energy storage devices.
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公开(公告)号:US20150125764A1
公开(公告)日:2015-05-07
申请号:US14514954
申请日:2014-10-15
Applicant: Massachusetts Institute of Technology
Inventor: Kyle Christopher Smith , W. Craig Carter , Yet-Ming Chiang
CPC classification number: H01M8/04746 , C02F1/4691 , C02F2201/46 , C25B1/003 , C25F3/02 , C25F7/00 , H01M8/188 , H01M8/20 , H01M12/06 , H01M12/08
Abstract: Flow battery. The battery includes high energy density fluid electrodes having a selected non-Newtonian rheology and structure for providing intermittent flow pulses of controlled volume and duration of the fluid electrodes, the structure adapted to promote interfacial slip to improve flow uniformity. The battery disclosed herein provides a potential solution to large-scale electrical energy storage needs.
Abstract translation: 流动电池 电池包括具有选择的非牛顿流变学和结构的高能量密度流体电极,用于提供流体电极的受控体积和持续时间的间歇流动脉冲,该结构适于促进界面滑移以改善流动均匀性。 本文公开的电池提供了对大规模电能存储需求的潜在解决方案。
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公开(公告)号:US20240274855A1
公开(公告)日:2024-08-15
申请号:US18605709
申请日:2024-03-14
Inventor: Yet-Ming Chiang , W. Craig Carter , Bryan Y. Ho , Mihal Duduta , Pimpa Limthongkul
CPC classification number: H01M8/188 , B60L50/72 , B60L58/27 , H01M8/20 , Y02E60/50 , Y02T10/70 , Y02T90/40
Abstract: Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.
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公开(公告)号:US10230124B2
公开(公告)日:2019-03-12
申请号:US14557924
申请日:2014-12-02
Applicant: Massachusetts Institute of Technology
Inventor: Brandon James Hopkins , Alexander H. Slocum , Xinwei Chen , Yet-Ming Chiang , Frank Yongzhen Fan , Ahmed Helal , Zheng Li , Kyle C. Smith , W. Craig Carter
IPC: H01M8/18 , H01M8/20 , H01M8/04276
Abstract: The flow cell includes first and second reservoirs having a selected volume containing a flowable redox electrode. A membrane separates charged and discharged material. An energy-extraction region includes electronically conductive porous current collectors through or adjacent to which the flowable redox electrodes flow and to which charge transfer occurs. Structure is provided for altering orientation of the flow cell whereby gravity induces flow of the flowable redox electrode between the first and second reservoirs to deliver power. By varying the angle of the cell, flow rate and power delivered on discharge or the charge rate on charge may be varied.
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公开(公告)号:US20130344367A1
公开(公告)日:2013-12-26
申请号:US13975474
申请日:2013-08-26
Applicant: Massachusetts Institute of Technology
Inventor: Yet-Ming Chiang , W. Craig Carter , Bryan Y. Ho , Mihai Duduta , Pimpa Limthongkul
CPC classification number: H01M8/188 , B60L11/1875 , B60L11/1898 , H01M8/20 , Y02E60/528 , Y02T10/705 , Y02T90/34
Abstract: Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.
Abstract translation: 描述了氧化还原流动装置,其中正极或负极活性材料中的至少一个是半固体或是冷凝离子存储电活性材料,并且其中至少一个电极活性材料被输送到 并且从发生电化学反应的组件产生电能。 半固体的电子导电性通过向悬浮液中添加导电颗粒和/或通过半固体中的固体的表面改性(例如,通过用更多的电子传导涂层材料涂覆固体以增加功率而增加) 的设备)。 公开了高能量密度和高功率氧化还原流量装置。 本文描述的氧化还原流动装置还可以包括一个或多个本发明的设计特征。 此外,还描述了用于氧化还原流动装置的发明化学物质。
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