公开(公告)号：US20210283579A1

公开(公告)日：2021-09-16

申请号：US17181444

申请日：2021-02-22

Applicant: LUCITE INTERNATIONAL UK LIMITED

Inventor： Adam Cullen ,  David William Johnson ,  Ian Andrew York

IPC: B01J21/08 ,  B01J23/04 ,  B01J35/02 ,  B01J37/02

Abstract: A catalyst has a modified silica support and comprises a modifier metal, zirconium and/or hafnium, and a catalytic metal on the modified support. The catalyst has at least a proportion, typically, at least 25%, of modifier metal present in moieties having a total of up to 2 modifier metal atoms. The moieties may be derived from a monomeric and/or dimeric cation source.
A method of production: provides a silica support with isolated silanol groups with optional treatment to provide isolated silanol groups (—SiOH) at a level of

公开(公告)号：US20160297739A1

公开(公告)日：2016-10-13

申请号：US15188349

申请日：2016-06-21

Applicant: Lucite International UK Limited

Inventor： Ian Andrew York ,  Sabina Zieman

IPC: C07C67/343 ,  C07C51/353 ,  B01J27/24 ,  C01B21/097 ,  C01B21/082

CPC classification number: C07C67/343 ,  B01J23/18 ,  B01J23/20 ,  B01J27/16 ,  B01J27/1811 ,  B01J27/1813 ,  B01J27/24 ,  B01J37/036 ,  C01B21/0821 ,  C01B21/097 ,  C07C51/353 ,  C07C57/04 ,  C07C69/54

Abstract: The invention relates to a method of producing an ethylenically unsaturated carboxylic acid or ester, preferably an α, β ethylenically unsaturated carboxylic acid or ester. The method includes contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester in the presence of a catalyst and optionally in the presence of an alcohol. The catalyst comprises a nitrided metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is selected from the metals of group 2, 3, 4, 13 (called also IIIA) or 14 (called also IVA) of the periodic table and M2 is selected from the metals of groups 5 or 15 (called also VA) of the periodic table. The invention extends to a catalyst system.

Abstract translation: 本发明涉及一种制备烯属不饱和羧酸或酯，优选α，β-烯属不饱和羧酸或酯的方法。 该方法包括在催化剂存在下和任选在醇存在下使甲醛或其合适的来源与羧酸或酯接触。 催化剂包括具有至少两种金属阳离子M1和M2的氮化金属氧化物，其中M1选自第2,3,4,13族（也称为IIIA）或14（也称为IVA）的金属， 周期表和M2选自元素周期表第5或15族（也称为VA）的金属。 本发明延伸到催化剂体系。

公开(公告)号：US20160228857A1

公开(公告)日：2016-08-11

申请号：US15099854

申请日：2016-04-15

Applicant: Lucite International UK Limited

Inventor： Sabina Ziemian ,  Ian Andrew York

IPC: B01J27/18

CPC classification number: B01J27/1806 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J27/18 ,  B01J27/182 ,  B01J35/002 ,  B01J35/02 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/03 ,  C07C67/30 ,  C07C67/343 ,  C07C69/54

Abstract: A method of producing an ethylenically unsaturated carboxylic acid or ester such as (meth) acrylic acid or alkyl esters thereof, for example, methyl methacrylate is described. The process comprises the steps of contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester, for example, propionic acid or alkyl esters thereof in the presence of a catalyst and optionally an alcohol. The catalyst comprises group II metal phosphate crystals having rod or needle like morphology or a suitable source thereof. The phosphate may be a hydroxyapatite, pyrophosphate, hydroxyphosphate, PO42− phosphate or mixtures thereof. The group II metal may be selected from Ca, Sr, Ba or mixtures thereof, for example, strontium hydroxyapatite and calcium hydroxyapatite. A catalyst system comprising a crystalline metal phosphate catalyst and a catalyst support is also described. The metal phosphate has rod/needle like morphology.

公开(公告)号：US20140364645A1

公开(公告)日：2014-12-11

申请号：US14371250

申请日：2013-01-14

Applicant: Lucite International UK Limited

Inventor： Ian Andrew York ,  Sabina Ziemian

IPC: C07C51/377 ,  B01J27/18 ,  C07C67/317

CPC classification number: C07C51/377 ,  B01J27/10 ,  B01J27/12 ,  B01J27/1806 ,  B01J35/002 ,  B01J35/026 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/038 ,  C07C51/353 ,  C07C67/317 ,  C07C67/343 ,  C07C2527/18 ,  C07C69/54 ,  C07C57/04

Abstract: A method of producing an ethylenically unsaturated, typically, an α, β ethylenically unsaturated carboxylic acid or ester is described. The method comprises the steps of contacting formaldehyde, or a source of formaldehyde, with a carboxylic acid or ester in the presence of a catalyst and optionally in the presence of an alcohol. The catalyst comprises barium phosphate leaf or plate shaped/like crystals, or a source thereof. A catalyst system is also described. The catalyst system comprises a crystalline barium phosphate catalyst and optionally a catalyst support.

Abstract translation: 烯键式不饱和的，通常为α，bgr; 烯键式不饱和羧酸或酯。 该方法包括在催化剂存在下和任选在醇存在下使甲醛或甲醛源与羧酸或酯接触的步骤。 该催化剂包括磷酸钡叶或板状晶体或其来源。 还描述了催化剂体系。 催化剂体系包括结晶的磷酸钡催化剂和任选的催化剂载体。

公开(公告)号：US20150238942A1

公开(公告)日：2015-08-27

申请号：US14432430

申请日：2013-10-01

Applicant: LUCITE INTERNATIONAL UK LIMITED

Inventor： Ian Andrew York ,  Trevor Huw Morris

IPC: B01J23/92 ,  B01J38/64 ,  C07C51/353 ,  B01J23/04

CPC classification number: C07C51/353 ,  B01J21/08 ,  B01J23/04 ,  B01J23/92 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/1019 ,  B01J38/485 ,  B01J38/64 ,  G06F11/3632 ,  G06F11/3656 ,  Y02P20/584 ,  C07C57/04

Abstract: A process for regenerating a silica-supported depleted alkali metal catalyst is described. The level of alkali metal on the depleted catalyst is at least 0.5 mol % and the silica support is a zero-gel. The process comprises the steps of contacting the silica supported depleted alkali metal catalyst with a solution of a salt of the alkali metal in a solvent system that has a polar organic solvent as the majority component. A re-impregnated catalyst prepared by the process of the invention any comprising a silicazero-gel support and a catalytic metal selected from an alkali metal in the range 0.5-5 mol % on the catalyst, wherein the surface area of the silica support is

Abstract translation: 描述了二氧化硅负载的贫碱金属催化剂的再生方法。 贫化催化剂上的碱金属含量至少为0.5mol％，二氧化硅载体为零凝胶。 该方法包括以下步骤：使二氧化硅负载的贫碱金属催化剂与碱金属盐的溶液在具有极性有机溶剂作为主要组分的溶剂体系中接触。 通过本发明的方法制备的再浸渍的催化剂，其任何包含硅氮烷凝胶载体和选自催化剂上0.5-5mol％范围的碱金属的催化金属，其中二氧化硅载体的表面积< 还描述了180m 2 / g。 本发明适用于制备烯属不饱和酸或酯的方法，包括使式R 1 -CH 2 -COOR 3的链烷酸或酯与甲醛或合适的甲醛源接触。

公开(公告)号：US10301250B2

公开(公告)日：2019-05-28

申请号：US15188349

申请日：2016-06-21

Applicant: Lucite International UK Limited

Inventor： Ian Andrew York ,  Sabina Zieman

IPC: C07C67/343 ,  C07C51/353 ,  B01J23/18 ,  B01J23/20 ,  B01J27/16 ,  B01J27/18 ,  B01J27/24 ,  B01J37/03 ,  C01B21/097 ,  C01B21/082

Abstract: A method of producing an ethylenically unsaturated carboxylic acid or ester, preferably an α, β ethylenically unsaturated carboxylic acid or ester. The method includes contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester in the presence of a catalyst and optionally in the presence of an alcohol. The catalyst includes a nitrided metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is selected from the metals of group 2, 3, 4, 13 (called also IIIA) or 14 (called also IVA) of the periodic table and M2 is selected from the metals of groups 5 or 15 (called also VA) of the periodic table.

公开(公告)号：US09782756B2

公开(公告)日：2017-10-10

申请号：US15099854

申请日：2016-04-15

Applicant: Lucite International UK Limited

Inventor： Sabina Ziemian ,  Ian Andrew York

IPC: B01J27/18 ,  C07C67/343 ,  B01J37/03 ,  B01J23/04 ,  B01J35/00 ,  B01J35/10 ,  B01J27/182 ,  B01J35/02 ,  C07C67/30 ,  B01J23/02 ,  B01J23/10

CPC classification number: B01J27/1806 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J27/18 ,  B01J27/182 ,  B01J35/002 ,  B01J35/02 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/03 ,  C07C67/30 ,  C07C67/343 ,  C07C69/54

Abstract: A method of producing an ethylenically unsaturated carboxylic acid or ester such as (meth) acrylic acid or alkyl esters thereof, for example, methyl methacrylate is described. The process comprises the steps of contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester, for example, propionic acid or alkyl esters thereof in the presence of a catalyst and optionally an alcohol. The catalyst comprises group II metal phosphate crystals having rod or needle like morphology or a suitable source thereof. The phosphate may be a hydroxyapatite, pyrophosphate, hydroxyphosphate, PO42− phosphate or mixtures thereof. The group II metal may be selected from Ca, Sr, Ba or mixtures thereof, for example, strontium hydroxyapatite and calcium hydroxyapatite. A catalyst system comprising a crystalline metal phosphate catalyst and a catalyst support is also described. The metal phosphate has rod/needle like morphology.

公开(公告)号：US20200269214A1

公开(公告)日：2020-08-27

申请号：US16646763

申请日：2018-09-13

Applicant: LUCITE INTERNATIONAL UK LIMITED

Inventor： Adam Cullen ,  David William Johnson ,  Ian Andrew York

IPC: B01J21/08 ,  B01J23/04 ,  B01J35/02 ,  B01J37/02

Abstract: A catalyst has a modified silica support and comprises a modifier metal, zirconium and/or hafnium, and a catalytic metal on the modified support. The catalyst has at least a proportion, typically, at least 25%, of modifier metal present in moieties having a total of up to 2 modifier metal atoms. The moieties may be derived from a monomeric and/or dimeric cation source. A method of production:— provides a silica support with isolated silanol groups with optional treatment to provide isolated silanol groups (—SiOH) at a level of

公开(公告)号：US10221121B2

公开(公告)日：2019-03-05

申请号：US15234751

申请日：2016-08-11

Applicant: Lucite International UK Limited

Inventor： Ian Andrew York ,  Trevor Huw Morris

IPC: B01J21/08 ,  B01J23/04 ,  B01J23/92 ,  B01J35/00 ,  B01J35/10 ,  B01J38/48 ,  B01J38/64 ,  C07C57/04 ,  G06F11/36 ,  C07C51/353

Abstract: A process for regenerating a silica-supported depleted alkali metal catalyst is described. The level of alkali metal on the depleted catalyst is at least 0.5 mol % and the silica support is a zero-gel. The process comprises the steps of contacting the silica supported depleted alkali metal catalyst with a solution of a salt of the alkali metal in a solvent system that has a polar organic solvent as the majority component. A re-impregnated catalyst prepared by the process of the invention any comprising a silica zero-gel support and a catalytic metal selected from an alkali metal in the range 0.5-5 mol % on the catalyst, wherein the surface area of the silica support is

公开(公告)号：US09504991B2

公开(公告)日：2016-11-29

申请号：US14432430

申请日：2013-10-01

Applicant: Lucite International UK Limited

Inventor： Ian Andrew York ,  Trevor Huw Morris

IPC: B01J23/92 ,  B01J23/04 ,  B01J38/64 ,  C07C51/353 ,  B01J38/48 ,  G06F11/36

CPC classification number: C07C51/353 ,  B01J21/08 ,  B01J23/04 ,  B01J23/92 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/1019 ,  B01J38/485 ,  B01J38/64 ,  G06F11/3632 ,  G06F11/3656 ,  Y02P20/584 ,  C07C57/04

Abstract: A process for regenerating a silica-supported depleted alkali metal catalyst is described. The level of alkali metal on the depleted catalyst is at least 0.5 mol % and the silica support is a zero-gel. The process comprises the steps of contacting the silica supported depleted alkali metal catalyst with a solution of a salt of the alkali metal in a solvent system that has a polar organic solvent as the majority component. A re-impregnated catalyst prepared by the process of the invention any comprising a silica zero-gel support and a catalytic metal selected from an alkali metal in the range 0.5-5 mol % on the catalyst, wherein the surface area of the silica support is

Abstract translation: 描述了二氧化硅负载的贫碱金属催化剂的再生方法。 贫化催化剂上的碱金属含量至少为0.5mol％，二氧化硅载体为零凝胶。 该方法包括以下步骤：使二氧化硅负载的贫碱金属催化剂与碱金属盐的溶液在具有极性有机溶剂作为主要组分的溶剂体系中接触。 通过本发明方法制备的再浸渍催化剂，其任一种包括二氧化硅零凝胶载体和选自催化剂上0.5-5mol％范围的碱金属的催化金属，其中二氧化硅载体的表面积为 还描述了<180m 2 / g。 本发明适用于制备烯属不饱和酸或酯的方法，包括使式R 1 -CH 2 -COOR 3的链烷酸或酯与甲醛或合适的甲醛源接触。