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1.发明授权
公开(公告)号：US5565521A
公开(公告)日：1996-10-15
申请号：US450432
申请日：1995-05-25
摘要： Chlorinated and chlorosulfonated polyethylenes are produced by chlorinating substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear rate at onset of gross melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n and at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5 and their method of manufacture are disclosed. The chlorosulfonated polyethylenes are produced by treating the chlorinated polyethylenes with a mixture of gaseous chlorine and sulfur dioxide.
摘要翻译： 氯化和氯磺化的聚乙烯通过氯化基本上线性的烯烃聚合物来制备，所述烯烃聚合物的熔体流动比为I 10 / I 2≥5.63，分子量分布，Mw / Mn，由下式定义：Mw / Mn < I2）-4.63，总熔体断裂开始时的临界剪切速率比具有大约相同的I2和Mw / Mn的直链烯烃聚合物的表面熔融断裂开始时的临界剪切速率至少高50％，并且至少 约0.01个长支链/ 1000个碳，分子量分布约为1.5至约2.5，并且其制造方法被公开。 通过用氯气和二氧化硫的混合物处理氯化聚乙烯来制备氯磺化的聚乙烯。
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2.发明授权
公开(公告)号：US5668220A
公开(公告)日：1997-09-16
申请号：US686299
申请日：1996-07-19
摘要： Chlorinated and chlorosulfonated polyethylenes are produced by chlorinating substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .gtoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear rate at onset of gross melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and Mw/Mn and at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5 and their method of manufacture are disclosed. The chlorosulfonated polyethylenes are produced by treating the chlorinated polyethylenes with a mixture of gaseous chlorine and sulfur dioxide.
摘要翻译： 氯化和氯磺化的聚乙烯是通过氯化基本上线性的烯烃聚合物生产的，该烯烃聚合物的熔体流动比为I10 / I2，≥5.63，分子量分布，Mw / Mn，由下式定义：Mw / Mn> / =（I10 / I2）-4.63，总熔体断裂开始时的临界剪切速率比具有大约相同的I2和Mw / Mn的直链烯烃聚合物的表面熔融断裂开始时的临界剪切速率至少高50％，并且至少 约0.01个长支链/ 1000个碳，分子量分布约为1.5至约2.5，并且其制造方法被公开。 通过用氯气和二氧化硫的混合物处理氯化聚乙烯来制备氯磺化的聚乙烯。
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3.发明授权
公开(公告)号：US5525679A
公开(公告)日：1996-06-11
申请号：US279735
申请日：1994-07-25
摘要： Chlorinated and chlorosulfonated polyethylenes are produced by chlorinating substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear rate at onset of gross melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and Mw/Mn and at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5 and their method of manufacture are disclosed. The chlorosulfonated polyethylenes are produced by treating the chlorinated polyethylenes with a mixture of gaseous chlorine and sulfur dioxide.
摘要翻译： 氯化和氯磺化的聚乙烯通过氯化基本上线性的烯烃聚合物来制备，所述烯烃聚合物的熔体流动比为I 10 / I 2≥5.63，分子量分布，Mw / Mn，由下式定义：Mw / Mn < I2）-4.63，总熔体断裂开始时的临界剪切速率比具有大约相同的I2和Mw / Mn的直链烯烃聚合物的表面熔融断裂开始时的临界剪切速率至少高50％，并且至少 约0.01个长支链/ 1000个碳，分子量分布约为1.5至约2.5，并且其制造方法被公开。 通过用氯气和二氧化硫的混合物处理氯化聚乙烯来制备氯磺化的聚乙烯。
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