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公开(公告)号：US06037439A
公开(公告)日：2000-03-14
申请号：US131751
申请日：1998-08-10
CPC分类号： C08G2/10
摘要： To provide a process for stable and continuous production of a polyacetal resin, mainly comprising a copolymer of 1,3-dioxolane and trioxane under the presence of a catalyst, in a high yield on an industrial scale for a long period of time. In the continuous production of a polyacetal resin by mixing 1,3-dioxolane with boron trifluoride and/or a coordination compound of boron trifluoride and then, mixing the obtained mixture with trioxane to conduct bulk polymerization in a polymerization machine, 1,3-dioxolane is brought into contact with boron trifluoride and/or a coordination compound of boron trifluoride while feeding both at the same direction and they are mixed together for 0.1 to 30 seconds under the condition of at least 0.1 m/sec of the linear velocity of the mixture and subsequently mixed with trioxane.
摘要翻译： 为了提供在催化剂存在下主要包含1,3-二氧戊环和三恶烷的共聚物的聚缩醛树脂的稳定和连续生产方法，长期以工业规模高产率。 在通过将1,3-二氧戊环与三氟化硼和/或三氟化硼的配位化合物混合来连续制备聚缩醛树脂之后，将得到的混合物与三恶烷混合以在聚合机中进行本体聚合，将1,3-二氧戊环 与三氟化硼和/或三氟化硼的配位化合物接触，同时在相同方向进料，并在混合物的线速度至少为0.1m / sec的条件下混合0.1至30秒 随后与三恶烷混合。
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公开(公告)号：US5929195A
公开(公告)日：1999-07-27
申请号：US115625
申请日：1998-07-14
摘要： A branched or crosslinked polyacetal resin is excellent in blow moldability, has impact resistances such as plane impact resistance, and the smoothness of the inner surfaces of moldings produced therefrom, and is suitable for molding, particularly blow molding. It can be produced by the bulk polymerization of (A) trioxane with (B) a cyclic ether and/or cyclic formal and (C) a polyfunctional glycidyl ether compound in the presence of (D) a cationic polymerization catalyst, a mixture prepared by mixing the cyclic ether and/or cyclic formal (B) with the polyfunctional glycidyl ether compound (C) and the cationic polymerization catalyst (D) is added to trioxane (A) to conduct the polymerization.
摘要翻译： 支化或交联的聚缩醛树脂具有优异的吹塑成型性，耐冲击性如平面抗冲击性，以及由其制成的模制品的内表面的平滑度，并且适于成型，特别是吹塑。 在（D）阳离子聚合催化剂存在下，通过（A）三恶烷与（B）环醚和/或环状缩甲醛和（C）多官能缩水甘油醚化合物的本体聚合可以制备， 将环醚和/或环状缩甲醛（B）与多官能缩水甘油醚化合物（C）和阳离子聚合催化剂（D）混合，加入到三恶烷（A）中进行聚合。
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公开(公告)号：US20060058457A1
公开(公告)日：2006-03-16
申请号：US10540142
申请日：2004-06-03
申请人： Kuniaki Kawaguchi
发明人： Kuniaki Kawaguchi
摘要： It is a purpose of the present invention to provide a polyacetal resin composition that contains a glass inorganic filler, improves adhesiveness between the glass inorganic filler and the polyacetal resin, and attains excellent mechanical strength. A polyacetal resin composition comprises 100 parts by weight of a polyacetal resin component (A) and 3-200 parts by weight of a glass in organic filler (B), wherein said polyacetal resin component (A) consists of 99.9-80 parts by weight of a polyacetal resin (A1) having hydroxyl groups at 0-20 mmol/kg in the molecule and 0.1-20 parts by weight of a modified polyacetal resin (A2) having hydroxyl groups at 50-2,000 mmol/kg in the molecule.
摘要翻译： 本发明的目的是提供含有玻璃无机填料的聚缩醛树脂组合物，提高玻璃无机填料与聚缩醛树脂之间的粘合性，并且获得优异的机械强度。 聚缩醛树脂组合物包含100重量份聚缩醛树脂组分（A）和3-200重量份有机填料（B）中的玻璃，其中所述聚缩醛树脂组分（A）由99.9-80重量份 的分子中具有0〜20mmol / kg的羟基的聚缩醛树脂（A1）和0.1〜20重量份的在分子中具有50-2,000mmol / kg羟基的改性聚缩醛树脂（A2）。
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公开(公告)号：US06642321B1
公开(公告)日：2003-11-04
申请号：US09787955
申请日：2001-03-23
IPC分类号： C08L5900
CPC分类号： C08L59/02 , C08G2/22 , C08L59/04 , C08L2666/16
摘要： To provide a polyacetal resin composition which is highly rigid and has excellent surface hardness, sliding characteristics, etc. That is, a polyacetal resin composition, produced by blending 100 parts by weight of a polyacetal resin (A) with 0.01-100 part(s) by weight of a branched polyacetal copolymer (B) which is obtained by copolymerization of 100 parts by weight of trioxane (a), 0.01-10 part(s) by weight of a monofunctional glycidyl compound (b) and 0-20 part(s) by weight of a cyclic ether compound (c) which is copolymerizable with trioxane.
摘要翻译： 提供高刚性且具有优异的表面硬度，滑动特性等的聚缩醛树脂组合物。即，将100重量份聚缩醛树脂（A）与0.01-100份（s） ）通过100重量份三恶烷（a），0.01-10重量份的单官能缩水甘油基化合物（b）和0-20份（重量）的共聚得到的支链聚缩醛共聚物（B） s）与三恶烷可共聚的环醚化合物（c）。
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公开(公告)号：US5132068A
公开(公告)日：1992-07-21
申请号：US584329
申请日：1990-09-19
申请人： Toshio Nakane , Yukihiko Kageyama , Hiroaki Konuma , Kenji Hijikata , Kenji Hijikata , Kuniaki Kawaguchi
发明人： Toshio Nakane , Yukihiko Kageyama , Hiroaki Konuma , Kenji Hijikata , Kenji Hijikata , Kuniaki Kawaguchi
IPC分类号： B29C71/02 , B29K67/00 , B29L7/00 , C08G63/191 , C08G63/199 , C08G63/672 , C08J5/18
CPC分类号： C08J5/18 , C08G63/672 , C08J2367/02 , Y10S264/907
摘要： A process for producing a transparent film includes forming a melt from a copolyester having structural units represented by the following formulas I and II, respectively: ##STR1## wherein R groups may be the same or different from each other are each selected from the group consisting of--CH.sub.2 CH.sub.2, --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --, --CH--CH.sub.2 --, ##STR2## and the molar fraction ratio of the structural units of formula II to the total structural units of formulas I and II is between 0.02 to 0.020, which a melt of the copolyester is formed into a film, rapidly quenched to solidify the copolyester and impart low crystallinity thereto. The solidified film is aged at a temperature of 60 degree centigrade or below, and then heat-treated at a temperature between the glass transition point (Tg) of the copolyester and no greater than 2.degree. C. below the melting point of the copolyester minus 2.
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公开(公告)号：US06583203B2
公开(公告)日：2003-06-24
申请号：US09869805
申请日：2001-07-05
IPC分类号： C08K534
摘要： To offer a resin material in which various properties such as excellent appearance and rigidity inherent to a polyacetal resin are maintained and a weather (light) resistance is improved. That is, a branched polyacetal resin composition comprising 100 parts by weight of a branched polyacetal copolymer (A) having an oxymethylene group as the main repeating unit and having a branching unit represented by the following formula (I), 0.01 to 5 parts by weight of a weather (light) resistant stabilizer (B) and 0.01 to 5 parts by weight of a hindered amine substance (C): wherein m and n each is an integer of 0 to 5; the sum of m+n is 1 to 5; and R is a monovalent organic group having a molecular weight of 40 to 1000.
摘要翻译： 提供一种树脂材料，其中保持聚缩醛树脂固有的优异的外观和刚性等各种性能，并提高耐候性（耐光性）。 即，含有100重量份作为主要重复单元的具有甲醛基的支链聚缩醛共聚物（A）和由下式（I）表示的支化单元的支链聚缩醛树脂组合物，其为0.01〜5重量份 耐光稳定剂（B）和0.01〜5重量份的受阻胺物质（C）：其中m和n各自为0至5的整数; m + n的和为1〜5; R为分子量为40〜1000的一价有机基团。
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公开(公告)号：US5300332A
公开(公告)日：1994-04-05
申请号：US15181
申请日：1993-02-11
申请人： Kuniaki Kawaguchi , Toshio Nakane , Kenji Hijikata
发明人： Kuniaki Kawaguchi , Toshio Nakane , Kenji Hijikata
IPC分类号： C08G63/672 , C08G63/20 , C08G63/66 , C08G63/688 , B32B1/00
CPC分类号： C08G63/6884 , C08G63/20 , Y10T428/13 , Y10T428/2913
摘要： A modified polyester resin is the reaction product of:(A) an acid component mainly comprised of terephthalic acid, 2,6-naphthalene dicarboxylic acid or a lower alcohol ester thereof,(B) a diol component mainly comprising an alkylene glycol having 2 to 8 carbon atoms, and(C) an aromatic sulfonic acid compound of the following general formula (1):HO(RO).sub.n --Ar--SO.sub.3 M (1) where Ar represents a benzene or naphthale ring, n represents an integer from 1 to 10, R represents a group selected from among alkylenes having 2 or 3 carbon atoms and when n is 2 or more, R may be the same as or different from one another, and M represents an alkali metal selected from lithium, sodium and potassium. The modified polyester resin also satisfies the following formulas (2) and (3):0.25.ltoreq.x.ltoreq.100 (meq/kg) (2)2.ltoreq.(x/CEG).times.100.ltoreq.150 (%) (3) where x represents the amount of the aromatic sulfonic acid compound represented by the above general formula (1) introduced thereinto and CEG represents the amount of the carboxy end groups, and x and CEG are each expressed in millequivalent per kilogram (meq/kg) of the polymer.
摘要翻译： 改性聚酯树脂是以下物质的反应产物：（A）主要由对苯二甲酸，2,6-萘二甲酸或其低级醇酯组成的酸组分，（B）主要包含亚烷基二醇的二醇组分， 8个碳原子，和（C）以下通式（1）的芳香族磺酸化合物：HO（RO）n -Ar-SO 3 M（1）其中Ar表示苯或萘环，n表示1〜 10，R表示选自具有2或3个碳原子的亚烷基，当n为2以上时，R可以相同或不同，M表示选自锂，钠，钾的碱金属。 改性聚酯树脂也满足下式（2）和（3）：0.25 <= x <= 100（meq / kg）（2）2 <=（x / CEG）* 100 <= 150（％） ）其中x表示引入其中的上述通式（1）表示的芳族磺酸化合物的量，CEG表示羧基端基的量，x和CEG各自以千克当量每千克表示（meq / kg） 的聚合物。
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8.发明授权Thermoforming process for forming a sheet of polybutylene terephthalate into a transparent container 失效将聚苯乙烯聚苯乙烯薄片制成透明容器的热成型工艺
公开(公告)号：US5213754A
公开(公告)日：1993-05-25
申请号：US675266
申请日：1991-03-26
IPC分类号： B29B11/10 , B29B11/14 , B29C51/00 , B29C51/02 , B29C51/42 , B29D22/00 , B29K67/00 , B29K105/32 , B29L22/00 , B65D1/00 , C08G63/12 , C08G63/18 , C08G63/672
CPC分类号： B29C51/002 , B29C51/426 , C08G63/672 , B29K2067/00 , B29K2995/0026
摘要： A transparent polyester container is produced by melt-molding a copolyester resin containing 75 to 98 molar % of repeating units of an ester of terephthalic acid with 1,4-butanediol with the balance mainly containing repeating units of an ester of terephthalic acid with an alkylene oxide adduct of a bisphenol compound, rapidly cooling the molding to prepare a sheet having a low crystallinity, maturing the sheet at a temperature selected so as to meet a requirement represented by the following formula (1) to prepare a sheet satisfying a requirement represented by the following formula (2) and subjecting the sheet to thermoforming through the use of a cavity mold at a temperature falling within a range represented by the following formula (3):______________________________________ Ta .ltoreq. Tcc (.degree.C.) (1) (.DELTA.Hcc).sub.a .gtoreq. 5 (J/g) (2) Tcc + 2 .ltoreq. Tb .ltoreq. Tm - 2 (.degree.C.) (3) ______________________________________ whereinTa is the maturing temperature (.degree.C.),Tb is the cavity mold temperature (.degree.C.),Tcc is the cold crystallization temperature (.degree.C.),Tm is the melting point (.degree.C.) of the resin, and(.DELTA.Hcc).sub.a is the quantity of heat (J/g) of cold crystallization of the sheet after maturing.
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公开(公告)号：US06753368B2
公开(公告)日：2004-06-22
申请号：US09869808
申请日：2001-07-05
IPC分类号： C08K509
CPC分类号： C08K5/103 , C08G2/18 , C08L59/04 , C08L2666/22
摘要： To provide a resin material in which various properties such as excellent appearance and rigidity inherent to a polyacetal resin are maintained and to which the antistatic property is given. That is, a branched polyacetal resin composition, comprising 100 parts by weight of a branched polyacetal copolymer (A) having an oxymethylene group as the main repeating unit and having a branching unit represented by the following formula (I), and 0.1 to 30 parts by weight of a compound (B) having a polyalkylene ether unit as the main constituting component and/or 0.01 to 10 parts by weight of an ester (C) of fatty acid with polyhydroxyl alcohol having a hydroxyl group: wherein m and n each is an integer of 0 to 5; the sum of m+n is 1 to 5; and R is a monovalent organic group having a molecular weight of 40 to 1000.
摘要翻译： 提供一种树脂材料，其中保持聚缩醛树脂固有的优异外观和刚性等各种性能，并提供抗静电性能。 即，含有作为主要重复单元的具有氧亚甲基的支链聚缩醛共聚物（A）100重量份，具有下述通式（I）所示的分支单元的支链聚缩醛树脂组合物和0.1〜30重量份 的具有聚亚烷基醚单元作为主要成分的化合物（B）和/或0.01至10重量份的具有羟基的多羟基醇的脂肪酸酯（C）：其中m和n各自为 0到5的整数; m + n的和为1〜5; R为分子量为40〜1000的一价有机基团。
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10.发明授权
公开(公告)号：US5300572A
公开(公告)日：1994-04-05
申请号：US897673
申请日：1992-06-12
CPC分类号： C08L67/02 , C08L23/08 , C08L23/0876 , C08L51/06 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/03
摘要： Moldable polyester resin compositions and molded articles therefrom include, based on the total weight of all resin components:(A) between 2 to 98% by weight of a compatibilizing metal sulfonate group-containing aromatic polyester copolymer which is the polycondensation reaction product of (a) an aromatic dicarboxylic acid or its ester-forming derivative, (b) a diol compound or its ester-forming derivative, and (c) an ester-forming compound containing a metal sulfonate group;(B) between 2 to 98% by weight of an additive resin which is one of (B-I) an olefin copolymer which is the copolymerization reaction product between an olefin with at least one of an .alpha.,.beta.-unsaturated carboxylic acid or its derivative and a vinyl alcohol or its ester, and (B-II) a polyamide resin; and, optionally(C) between 0 to 96% by weight of a non-compatibilizing aromatic polyester resin.The ester-forming compound containing a metal sulfonate group is preferably incorporated into the main polymer chain of the compatibilizing aromatic polyester resin in an amount between 0.01 to 15 molar percent.
摘要翻译： 可模塑的聚酯树脂组合物及其模塑制品包括：基于所有树脂组分的总重量：（A）2-98重量％的相容的含金属磺酸盐基团的芳族聚酯共聚物，其是（a ）芳族二羧酸或其酯形成衍生物，（b）二醇化合物或其酯形成衍生物，和（c）含有金属磺酸盐基团的酯形成化合物; （B）2〜98重量％的添加树脂，其为（BI）烯烃共聚物之一，其为烯烃与（α），（β-）不饱和羧酸中的至少一种之间的共聚反应产物 或其衍生物和乙烯醇或其酯，和（B-II）聚酰胺树脂; 和（C）0〜96重量％的非相容性芳族聚酯树脂。 含有金属磺酸盐基的酯形成化合物优选以0.01〜15摩尔％的量并入相容性芳族聚酯树脂的主聚合物链中。
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