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    Curable perfluoropolyether compositions and rubber or gel articles comprising the same
    1.
    发明申请
    Curable perfluoropolyether compositions and rubber or gel articles comprising the same 审中-公开
    可固化的全氟聚醚组合物和包含其的橡胶或凝胶制品

    公开(公告)号：US20050277731A1

    公开(公告)日：2005-12-15

    申请号：US11148360

    申请日：2005-06-09

    申请人： Kenichi Fukuda ,  Mikio Shiono ,  Hirofumi Kishita

    发明人： Kenichi Fukuda ,  Mikio Shiono ,  Hirofumi Kishita

    IPC分类号： C08G65/00 ,  C08K3/36 ,  C08K5/54 ,  C08L71/02 ,  C08G77/06 ,  C08L83/00

    CPC分类号： C08K5/5406 ,  C08K3/36 ,  C08L71/02 ,  C08L83/00

    摘要： Perfluoropolyether compositions are provided comprising (A) a linear perfluoropolyether compound containing at least two alkenyl groups, having a perfluoropolyether structure comprising recurring units —CaF2aO— in its backbone, and having a Mw of 10,000-100,000; (B) an organosilicon compound containing at least two silicon atom-bonded hydrogen atoms; (C) a reinforcing filler; (D) a hydrosilylation catalyst; and (E) a polyfluoromonoalkenyl compound containing one alkenyl group and having a perfluoropolyether structure in its backbone. The compositions cure into rubber or gel products having improved acid resistance.

    摘要翻译： 提供了全氟聚醚组合物，其包含（A）含有至少两个烯基的直链全氟聚醚化合物，其具有包含其主链中的重复单元-CA 2 CO 2 O-的全氟聚醚结构 ，Mw为10,000-100,000; （B）含有至少两个与硅原子键合的氢原子的有机硅化合物; （C）增强填料; （D）氢化硅烷化催化剂; 和（E）在其主链中含有一个烯基并具有全氟聚醚结构的多氟单链烯基化合物。 组合物固化成具有改善的耐酸性的橡胶或凝胶产品。

    Curable perfluoropolyether compositions and rubber or gel articles comprising the same
    2.
    发明授权
    Curable perfluoropolyether compositions and rubber or gel articles comprising the same 有权
    可固化的全氟聚醚组合物和包含其的橡胶或凝胶制品

    公开(公告)号：US08119760B2

    公开(公告)日：2012-02-21

    申请号：US12468721

    申请日：2009-05-19

    申请人： Kenichi Fukuda ,  Mikio Shiono ,  Hirofumi Kishita

    发明人： Kenichi Fukuda ,  Mikio Shiono ,  Hirofumi Kishita

    IPC分类号： C08G77/24

    CPC分类号： C08K5/5406 ,  C08K3/36 ,  C08L71/02 ,  C08L83/00

    摘要： Perfluoropolyether compositions are provided comprising: (A) a linear perfluoropolyether compound containing at least two alkenyl groups, having a perfluoropolyether structure comprising recurring units —CaF2aO— in its backbone, and having a molecular weight of 10,000 to 100,000; (B) an organosilicon compound containing at least two silicon atom-bonded hydrogen atoms; (C) a reinforcing filler; (D) a hydrosilylation catalyst; and (E) a polyfluoromonoalkenyl compound containing one alkenyl group and having a perfluoropolyether structure in its backbone. The compositions cure into rubber or gel products having improved acid resistance.

    摘要翻译： 提供了全氟聚醚组合物，其包含：（A）包含至少两个烯基的直链全氟聚醚化合物，其全氟聚醚结构在其主链中包含重复单元-CaF 2，其分子量为10,000至100,000; （B）含有至少两个与硅原子键合的氢原子的有机硅化合物; （C）增强填料; （D）氢化硅烷化催化剂; 和（E）在其主链中含有一个烯基并具有全氟聚醚结构的多氟单链烯基化合物。 组合物固化成具有改善的耐酸性的橡胶或凝胶产品。

    Organosilicon compounds and method of making
    4.
    发明授权
    Organosilicon compounds and method of making 失效
    有机硅化合物及其制备方法

    公开(公告)号：US6114562A

    公开(公告)日：2000-09-05

    申请号：US366788

    申请日：1999-08-04

    申请人： Kenichi Fukuda ,  Hirofumi Kishita

    发明人： Kenichi Fukuda ,  Hirofumi Kishita

    IPC分类号： C07F7/18 ,  C02F7/08 ,  C02F7/18

    CPC分类号： C07F7/1844 ,  C07F7/184

    摘要： Novel organosilicon compounds having a perfluoroalkyl or perfluoropolyether group and at least one ethynyl group are useful as an agent for controlling hydrosilylation reaction between a --SiH group-bearing compound and a --CH.dbd.CH.sub.2 group-bearing compound.

    摘要翻译： 具有全氟烷基或全氟聚醚基团和至少一个乙炔基的新型有机硅化合物可用作控制含-SiH基的化合物和含-CH-CH2基团的化合物之间的氢化硅烷化反应的试剂。

    Cyclotrisiloxane and process for producing the same
    7.
    发明授权
    Cyclotrisiloxane and process for producing the same 失效
    环三硅氧烷及其制备方法

    公开(公告)号：US5403945A

    公开(公告)日：1995-04-04

    申请号：US147486

    申请日：1993-11-05

    申请人： Hirofumi Kishita ,  Kouichi Yamaguchi ,  Kenichi Fukuda ,  Nobuyuki Kobayashi

    发明人： Hirofumi Kishita ,  Kouichi Yamaguchi ,  Kenichi Fukuda ,  Nobuyuki Kobayashi

    IPC分类号： C07F7/21 ,  C07F7/08

    CPC分类号： C07F7/21

    摘要： A cyclotrisiloxane represented by the general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 may be the same or different and are each an alkyl group of 1 to 3 carbon atoms and X is a cyclohexyl group or an alkyl group expressed by the formula:--C.sub.n H.sub.2n+1where n is an integer of 4 to 15. The cyclotrisiloxane is useful as an intermediate for producing silicone oils and silicone rubbers, and the obtained silicone oils and silicone rubbers are excellent in lubricity.

    摘要翻译： 由通式（1）表示的环三硅氧烷：其中R 1，R 2，R 3，R 4和R 5可以相同或不同，并且各自是1至3个碳原子的烷基，X是环己基 基团或由下式表示的烷基-CnH 2 n + 1其中n为4至15的整数。环三硅氧烷可用作制备硅油和硅橡胶的中间体，所得硅油和硅橡胶具有优异的 润滑性。

    Chain organopolysiloxane and process for producing the same
    8.
    发明授权
    Chain organopolysiloxane and process for producing the same 失效
    链有机聚硅氧烷及其制造方法

    公开(公告)号：US5374702A

    公开(公告)日：1994-12-20

    申请号：US196848

    申请日：1994-02-15

    申请人： Hiroshi Inomata ,  Hirofumi Kishita ,  Kouichi Yamaguchi ,  Kenichi Fukuda ,  Yoshikazu Saito ,  Nobuyuki Kobayashi

    发明人： Hiroshi Inomata ,  Hirofumi Kishita ,  Kouichi Yamaguchi ,  Kenichi Fukuda ,  Yoshikazu Saito ,  Nobuyuki Kobayashi

    IPC分类号： C08G77/24 ,  C08G77/34 ,  C08G77/06

    CPC分类号： C08G77/34 ,  C08G77/24

    摘要： A chain organopolysiloxane is obtained by polymerizing a fluorine-containing cyclotrisiloxane of the general formula: ##STR1## (wherein R.sup.1 is a monovalent hydrocarbon group, and Rf is a perfluoroalkyl group or perfluoroalkyl ether group)in the presence of a lithium silanolate catalyst, silylating the resulting polymerization product, and treating the silylated product at a temperature of not lower than 100.degree. C. under a reduced pressure of not higher than 10.sup.-1 mmHg to remove volatile components therefrom. The organopolysiloxane is essentially free of volatile low-molecular siloxanes. Therefore, the chain organopolysiloxane can be used without the problems which might arise from the volatile low-molecular siloxanes, such as evaporation of low-molecular siloxanes from a cured rubber product with the result of electrical-contact troubles.

    摘要翻译： 通过在硅酸铝锂催化剂的存在下聚合具有以下通式的含氟环三硅氧烷获得链有机聚硅氧烷：其中R 1是一价烃基，Rf是全氟烷基或全氟烷基醚基团，甲硅烷基化 得到的聚合产物，并在不低于10-1mmHg的减压下在不低于100℃的温度下处理甲硅烷基化产物，以从其中除去挥发性组分。 有机聚硅氧烷基本上不含挥发性低分子硅氧烷。 因此，可以使用链有机聚硅氧烷，而不会由挥发性低分子量硅氧烷引起的问题，例如由于电接触问题导致的硫化橡胶产物的低分子量硅氧烷的蒸发。

    METHOD FOR BONDING POLYAMIDE RESIN AND FLUOROELASTOMER
    9.
    发明申请
    METHOD FOR BONDING POLYAMIDE RESIN AND FLUOROELASTOMER 审中-公开
    用于粘结聚酰胺树脂和氟橡胶的方法

    公开(公告)号：US20090130318A1

    公开(公告)日：2009-05-21

    申请号：US12265328

    申请日：2008-11-05

    申请人： Mikio Shiono ,  Kenichi Fukuda ,  Shinichi Sato

    发明人： Mikio Shiono ,  Kenichi Fukuda ,  Shinichi Sato

    IPC分类号： B05D3/02

    CPC分类号： C09J5/02 ,  C08J5/122 ,  C08J2327/12 ,  C08J2377/00 ,  C09J2421/008 ,  C09J2427/008 ,  C09J2477/008

    摘要： A bond between fluoroelastomer and polyamide resin is established by applying a silane-based primer composition to a surface of polyamide resin, heat treating at 100-200° C., applying a liquid fluoroelastomer composition to the primer coat at room temperature to 100° C., and heat curing at 100-200° C. for bonding the fluoroelastomer to the polyamide resin. The bond between fluoroelastomer and polyamide resin is maintained over a long period of time even in transmission oils.

    摘要翻译： 通过将硅烷类底漆组合物涂布在聚酰胺树脂的表面上，在100〜200℃下进行热处理，将液态含氟弹性体组合物在室温〜100℃下涂布在底涂层上，建立了含氟弹性体和聚酰胺树脂之间的键 并在100-200℃下热固化，以将含氟弹性体粘合到聚酰胺树脂上。 含氟弹性体和聚酰胺树脂之间的粘合剂即使在变速箱油中也能长期保持。