公开(公告)号：US09254483B2

公开(公告)日：2016-02-09

申请号：US14035194

申请日：2013-09-24

Applicant: KOREA INSTITUTE OF ENERGY RESEARCH

Inventor： Hee Yeon Kim ,  Nam Jo Jeong ,  Seong Ok Han

IPC: B01J37/34 ,  B01J31/06 ,  B01J23/28 ,  B01J23/42 ,  B01J23/75 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  C01B3/40 ,  C01B31/08 ,  C10G2/00

CPC classification number: B01J37/341 ,  B01J23/28 ,  B01J23/42 ,  B01J23/75 ,  B01J23/755 ,  B01J31/06 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/34 ,  B01J37/343 ,  C01B3/40 ,  C01B32/324 ,  C01B2203/1052 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/70 ,  Y02P20/52

Abstract: The present disclosure relates to a catalyst having metal catalyst nanoparticles supported on natural cellulose fibers and a method of preparing the same, whereby natural cellulose fibers are subjected to specific pretreatment to increase a surface area and form defects on the surface thereof and metal catalyst nanoparticles are then supported on the cellulose catalyst support in a highly dispersed state, thereby providing improved catalysis while allowing production of the catalyst at low cost. The catalyst may be utilized for various catalytic reactions.

Abstract translation: 本发明涉及一种具有负载在天然纤维素纤维上的金属催化剂纳米颗粒的催化剂及其制备方法，其中天然纤维素纤维进行特定预处理以增加表面积并在其表面形成缺陷，并且金属催化剂纳米颗粒为 然后以高度分散的状态负载在纤维素催化剂载体上，从而提供改进的催化，同时以低成本制备催化剂。 催化剂可用于各种催化反应。

公开(公告)号：US20140087939A1

公开(公告)日：2014-03-27

申请号：US14030070

申请日：2013-09-18

Applicant: Korea Institute of Energy Research

Inventor： Hee Yeon Kim ,  Seok Yong Hong ,  Hyun Uk Kim

IPC: B01J23/42

CPC classification number: B01J23/42 ,  B01J21/04 ,  B01J23/28 ,  B01J23/44 ,  B01J23/462 ,  B01J23/52 ,  B01J23/75 ,  B01J23/755 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J35/002 ,  B01J35/008 ,  B01J37/0217 ,  B01J37/0244 ,  B01J37/084 ,  B01J37/12 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1047 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/142 ,  Y02P20/52

Abstract: A metal-carbon composite supported catalyst for hydrogen production using co-evaporation and a method of preparing the same, wherein the catalyst is configured such that a metal-carbon composite having a core-shell structure resulting from co-evaporation is supported on the surface of an oxide-based support coated with carbon, thereby maintaining superior durability without agglomeration even in a catalytic reaction at a high temperature. Because part or all of the surface of metal is covered with the carbon shell, even when the catalyst is applied under severe reaction conditions including high temperatures, long periods of time, acidic or alkaline states, etc., the metal particles do not agglomerate or are not detached, and do not corrode, thus exhibiting high performance and high durability. Therefore, inactivation of the catalyst or the generation of side reactions can be prevented, so that the catalyst can be efficiently utilized in hydrogen production.

Abstract translation: 一种使用共蒸发的氢制造用金属 - 碳复合材料负载型催化剂及其制备方法，其特征在于，所述催化剂构成为具有由共蒸发得到的核 - 壳结构的金属 - 碳复合体被支撑在所述表面上 的涂覆有碳的氧化物基载体，从而即使在高温下的催化反应中也保持优异的耐久性而没有附聚。 由于金属表面的一部分或全部被碳壳覆盖，所以即使催化剂在包括高温，长时间，长时间，酸性或碱性状态等苛刻的反应条件下被使用，金属颗粒也不会聚集或 不分离，不腐蚀，因此表现出高性能和高耐久性。 因此，可以防止催化剂的失活或副反应的产生，从而可以有效地利用催化剂进行制氢。

公开(公告)号：US09768442B2

公开(公告)日：2017-09-19

申请号：US14927302

申请日：2015-10-29

Applicant: KOREA INSTITUTE OF ENERGY RESEARCH

Inventor： Seong Ok Han ,  Hee Yeon Kim ,  In Sub Han ,  Se Young Kim ,  Young Hoon Seong ,  Doo Won Seo

IPC: H01M4/133 ,  H01M4/04 ,  H01M4/1395 ,  H01M10/0525 ,  H01M4/38

CPC classification number: H01M4/133 ,  H01M4/0471 ,  H01M4/1395 ,  H01M4/381 ,  H01M10/0525

Abstract: Provided are a carbon electrode particularly suitable to be used as a negative electrode of an energy storing apparatus and the like and a method for manufacturing the same by forming the carbon electrode by heat-treating a natural carbon material such as a natural fiber sheet including a natural fiber or cellulose sheet including a natural cellulose fiber which is a natural material other than a petroleum-based material or a petroleum-based synthetic material to reduce manufacturing cost, shorten a manufacturing process, minimize discharge of a hazardous substance, and uniformly maintain storage capacitance even in repeated charging and discharging when being applied to the energy storing apparatus. The carbon electrode includes any one of an alkaline metal particle and an alkaline earth metal particle having an average particle size of less than 100 nm which is formed on a surface in a process of carbonizing a natural carbon material.

公开(公告)号：US09566567B2

公开(公告)日：2017-02-14

申请号：US14030070

申请日：2013-09-18

Applicant: Korea Institute of Energy Research

Inventor： Hee Yeon Kim ,  Seok Yong Hong ,  Hyun Uk Kim

IPC: B01J23/42 ,  B01J37/02 ,  B01J37/08 ,  B01J37/12 ,  B01J21/04 ,  B01J23/28 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/75 ,  B01J23/755 ,  B01J29/04 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J35/00 ,  C01B3/40

CPC classification number: B01J23/42 ,  B01J21/04 ,  B01J23/28 ,  B01J23/44 ,  B01J23/462 ,  B01J23/52 ,  B01J23/75 ,  B01J23/755 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J35/002 ,  B01J35/008 ,  B01J37/0217 ,  B01J37/0244 ,  B01J37/084 ,  B01J37/12 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1047 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/142 ,  Y02P20/52

Abstract: A metal-carbon composite supported catalyst for hydrogen production using co-evaporation and a method of preparing the same, wherein the catalyst is configured such that a metal-carbon composite having a core-shell structure resulting from co-evaporation is supported on the surface of an oxide-based support coated with carbon, thereby maintaining superior durability without agglomeration even in a catalytic reaction at a high temperature. Because part or all of the surface of metal is covered with the carbon shell, even when the catalyst is applied under severe reaction conditions including high temperatures, long periods of time, acidic or alkaline states, etc., the metal particles do not agglomerate or are not detached, and do not corrode, thus exhibiting high performance and high durability. Therefore, inactivation of the catalyst or the generation of side reactions can be prevented, so that the catalyst can be efficiently utilized in hydrogen production.

Abstract translation: 一种使用共蒸发的氢制造用金属 - 碳复合材料负载型催化剂及其制备方法，其特征在于，所述催化剂构成为具有由共蒸发得到的核 - 壳结构的金属 - 碳复合体被支撑在所述表面上 的涂覆有碳的氧化物基载体，从而即使在高温下的催化反应中也保持优异的耐久性而没有附聚。 由于金属表面的一部分或全部被碳壳覆盖，所以即使催化剂在包括高温，长时间，长时间，酸性或碱性状态等苛刻的反应条件下被使用，金属颗粒也不会聚集或 不分离，不腐蚀，因此表现出高性能和高耐久性。 因此，可以防止催化剂的失活或副反应的产生，从而可以有效地利用催化剂进行制氢。

公开(公告)号：US20160126537A1

公开(公告)日：2016-05-05

申请号：US14927302

申请日：2015-10-29

Applicant: KOREA INSTITUTE OF ENERGY RESEARCH

Inventor： Seong Ok Han ,  Hee Yeon Kim ,  In Sub Han ,  Se Young Kim ,  Young Hoon Seong ,  Doo Won Seo

IPC: H01M4/133 ,  H01M4/1395 ,  H01M4/04 ,  H01M10/0525 ,  H01M4/38

CPC classification number: H01M4/133 ,  H01M4/0471 ,  H01M4/1395 ,  H01M4/381 ,  H01M10/0525

Abstract: Provided are a carbon electrode particularly suitable to be used as a negative electrode of an energy storing apparatus and the like and a method for manufacturing the same by forming the carbon electrode by heat-treating a natural carbon material such as a natural fiber sheet including a natural fiber or cellulose sheet including a natural cellulose fiber which is a natural material other than a petroleum-based material or a petroleum-based synthetic material to reduce manufacturing cost, shorten a manufacturing process, minimize discharge of a hazardous substance, and uniformly maintain storage capacitance even in repeated charging and discharging when being applied to the energy storing apparatus. The carbon electrode includes any one of an alkali metal particle and an alkali earth metal particle having an average particle size of less than 100 nm which is formed on a surface in a process of carbonizing a natural carbon material.

Abstract translation: 提供特别适合用作能量存储装置等的负极的碳电极及其制造方法，其通过对天然纤维片材等天然碳材料进行热处理而形成碳电极，所述天然纤维片材包括 天然纤维或纤维素片，其包括作为石油基材料或石油基合成材料以外的天然材料的天然纤维素纤维，以降低制造成本，缩短制造过程，使有害物质的排出最小化，并均匀地保持储存 当施加到能量存储装置时，即使在重复的充电和放电中也是电容器。 该碳电极包括在碳化天然碳材料的过程中在表面上形成的平均粒径小于100nm的碱金属颗粒和碱土金属颗粒中的任一种。