公开(公告)号：US3814703A

公开(公告)日：1974-06-04

申请号：US25251472

申请日：1972-05-08

Applicant: KANSAI PAINT CO LTD

Inventor： NAKAYAMA H ,  ASADA K

IPC: C08F8/40 ,  C08F8/44 ,  C08F291/00 ,  H01B1/12 ,  H01B1/00 ,  H01C

CPC classification number: H01B1/122 ,  C08F8/40 ,  C08F8/44 ,  C08F291/00 ,  C08F230/02 ,  C08F228/02

Abstract: THIS INVENTION RELATES TO A COMPOSITION FOR FORMING AN ELECTRICALLY CONDUCTIVE RESIN FILM, WHICH COMPRISES (A) RESINOUS COMPOUND OBTAINED BY INTRODUCING ETHYLENICALLY CARBON-CARBON UNSATURATIONS IN A RANGE OF 0.3$10-3 TO 3$10-3 MOL PER ONE GRAM OF THE RESINOUS COMPOUND AND PHOSPHORIC ACID GROUPS OF NOT MORE THAN 2$10-3 MOL PER ONE GRAM OF THE RESINOUS COMPOUNDS AS PENDANT GROUPS INTO A MOLECULAR CHAIN OF ACRYLIC COPOLYMER HAVING FROM ABOUT 3000 TO ABOUT 50,000 OF A NUMBER AVERAGE MOLECULAR WEIGHT AND HAVING FUNCTIONAL GROUPS IN THE RANGE OF 1$10-3 TO 5$10-3 MOL PER ONE GRAM OF THE ACRYLIC COPOLYMER OR INTO A MOLECUALR CHAIN OF POLYVINYL ALCOHOL HAVING FROM ABOUT 100 TO ABOUT 5000 OF POLUMERIZATION DEGREE AND HAVING MORE THAN ABOUT 50% OF THE DEGREE OF HYDROLUSIS, AND (B) A POLYMERIZABLE ETHYLENICALLY UNSATURATED COMPOUND HAVING AN IONIC FREE GROUP OR ADMIXTURE THEREOF SELECTED FROM THE GROUP CONSISTING OF SULFOALKYL ACRYLATES OR METHACRYLATES OR SALTS THEREOF REPRESENTED BY THE FOLLOWING GENERAL FORMULA:

CH2=C(-R1)-COO-R2-SO3(-) M(+)

WHEREIN R1 IS HYDROGEN ATOM OR METHYL GROUP, R2 IS AN ALKYLENE GROUP HAVING 2 TO 4 CARBON ATOMS, M1 AND M2, WHICH MAY BE THE SAME OR DIFFERENT, HYDROGEN ATOM, SODIUM, LITHIUM, POTASSIUM, COPPER, MAGNESIUM, ALUMINUM, AMMONIUM GROUP, METHYL AMINE GROUP OR ETHYL AMINE GROUP, AND M IS THE SAME AS MENTIONED ABOVE, AND MAY FURTHER COMPOSE (C) OTHER POLYMERIZABLE ETHYLENICALLY UNSATURATED COMPOUND AND/OR (D) POLYMERIZATION INITIATOR AND/OR AN ADDITIVE.

(CH2=C(-R1)-COO-R2-O-)2-P(=O)-O(-) M(+)

CH2=C(-R1)-COO-R2-O-P(=O)(-O(-))2 M1(+) M2(+) OR

WHEREIN R1 IS HYDROGEN ATOM OR A METHYL GROUP, R2 IS AN ALKYLENE GROUP HAVING 1 TO 5 CARBON ATOMS, AND M IS HYDROGEN ATOM, SODIUM, LITHIUM, POTASSIUM, COPPER, MAGNESIUM, ALUMINIUM, AMMONIUM GROUP, METHYL AMINE GROUP OR ETHYL AMINE GROUP, AND PHOSPHORIC ACID ESTERS OR PHOSPHATE ESTERS OF 2-HYDOXYALKYL ACRYLATES OR METHACRYLATES REPRESENTED BY THE FOLLOWING GENERAL FORMULA:

公开(公告)号：US3850770A

公开(公告)日：1974-11-26

申请号：US35040073

申请日：1973-04-12

Applicant: KANSAI PAINT CO LTD

Inventor： JUNA K ,  AIHARA T ,  KITA N ,  ASADA K ,  IMAI T ,  NAKAYAMA H

IPC: C08G18/48 ,  C08G18/67 ,  C08G18/76 ,  G03F7/038 ,  B01J1/10 ,  C08F29/36 ,  C08G41/04

CPC classification number: G03F7/038 ,  C08G18/4825 ,  C08G18/672 ,  C08G18/7642 ,  Y10S430/116 ,  Y10S525/92 ,  C08G18/48

Abstract: Photopolymerizable compositions comprise (1) 40 to 80% by weight of unsaturated acrylurethane resin prepared by reacting a diisocyanate monomer with polyhydric alcohols, and then reacting said reaction product with a polymerizable acrylate ester or methacrylate ester having a hydroxyl group, (2) 60 to 20% by weight of a polymer which is compatible with said unsaturated acrylurethane resin and is soluble in dilute aqueous alkali solutions or alcohols, and (3) a photo-sensitizer which is capable of hardening said unsaturated acrylurethane resin under irradiation of actinic rays.

Abstract translation: 可光聚合组合物包含（1）40至80重量％的通过使二异氰酸酯单体与多元醇反应制备的不饱和丙烯酸类聚氨酯树脂，然后使所述反应产物与具有羟基的可聚合丙烯酸酯或甲基丙烯酸酯反应，（2）60至 20重量％的与所述不饱和丙烯酸类氨基甲酸酯树脂相容的聚合物，并且可溶于稀碱水溶液或醇，和（3）能够在光化射线照射下硬化所述不饱和丙烯酸类聚氨酯树脂的光敏剂。

公开(公告)号：US3847846A

公开(公告)日：1974-11-12

申请号：US26229372

申请日：1972-06-13

Applicant: KANSAI PAINT CO LTD

Inventor： ASADA K

IPC: C08F291/10 ,  H01B1/12 ,  C08F3/50

CPC classification number: H01B1/122 ,  C08F291/10 ,  C08F228/02 ,  C08F230/02

Abstract: 1. A COMPOSITION FOR PREPARING ELECTROCONDUCTIVE RESIN WHICH COMPRISES: (A) ONE OR MORE MEMBERS SELECTED FROM THE GROUP CONSISTING OF: (I) COMPOUNDS REPRESENTED BY THE FOLLOWING GENERAL FORMULA:

(H2C=C(-R1)-COO-(C(-R2)(-R3))N-SO3)X-M1

IN WHICH R1 IS A HYDROGEN ATOM OR A METHYL GROUP; EACH OF R2 AND R3 IS A HYDROGEN OR HALOGEN ATOM; N IS AN INTEGER FROM 1 TO 5; X IS AN INTEGER FROM 1 TO 3; AND M1 IS A HYDROGEN ATOM, NA, LI, K, AG, CU, MG, CA, ZN, BA, AL, AMMONIUM OR AMINE, (II) COMPOUNDS REPRESENTED BY THE FOLLOWING GENERAL FORMULA:

H2C=C(-R4)-COO-(C(-R5)(-R6))P-O-P(=O)(-O-M2)-O-M3

IN WHICH R4 IS A HYDROGEN ATOM OR A METHYL GROUP; EACH OF R5 AND R6 IS A HYDROGEN OR HALOGEN ATOM; P IS AN INTEGER FROM 1 TO 4; AND EACH OF M2 AND M3 IS A HYDROGEN ATOM, NA, LI, K, AG, AMMONIUM OR AMINE, AND (III) COMPOUNDS REPRESENTED BY THE FOLLOWING GENERAL FORMULA:

((H2C=C(-R7)-COO-(C(-R9)(-R8))Q-O)2-P(=O)-O)X-M3

IN WHICH R7 IS A HYDROGEN ATOM OR METHYL GROUP; EACH OF R8 AND R9 IS HYDROGEN OR HALOGEN ATOM; Q IS AN INTEGER FROM 1 TO 4; X IS AN INTEGER FROM 1 TO 3; AND M4 IS A HYDROGEN ATOM, NA, LI, K, AG, CU, MG, CA, ZN, BA, AL, AMMONIUM OR AMINE, AND (B) COMPOUNDS WHICH CONTAIN VICINAL EPOXY GROUPS IN THE MOLECULES.