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28 条记录 (耗时 0.015 秒)

    Liquid diphenylmethane diisocyanate compositions
    4.
    发明授权
    Liquid diphenylmethane diisocyanate compositions 失效
    液体二苯基甲烷二异氰酸酯组合物

    公开(公告)号：US4539156A

    公开(公告)日：1985-09-03

    申请号：US681568

    申请日：1984-12-14

    申请人： John E. Dewhurst ,  Jeffrey F. Dormish ,  Richard S. Pantone

    发明人： John E. Dewhurst ,  Jeffrey F. Dormish ,  Richard S. Pantone

    IPC分类号： C07C265/12 ,  C08G18/80 ,  C07C119/048

    CPC分类号： C07C263/18 ,  C08G18/7657 ,  C08G18/8019

    摘要： The present invention is directed to a process for the preparation of a stable, liquid adduct comprising reacting a mixture of 1,3-butane diol and propylene glycol with diphenylmethane diisocyanate at a temperature of from about 25.degree. C. to about 120.degree. C. in an amount such that the resultant product has an isocyanate group content of from about 20 to about 30 percent by weight, and wherein the ratio of mole equivalents of 1,3-butane diol to mole equivalents of propylene glycol is from 0.05:0.95 to 0.95:0.05, with the further proviso that(i) if the 4,4'-isomer content of the diphenylmethane diisocyanate is equal to or greater than 90 percent by weight, then said ratio is from 0.45:0.55 to 0.70:0.30, and(ii) if the 4,4'-isomer content of the diphenylmethane diisocyanate is less than 90 percent by weight, but not less than 70 percent by weight, then said ratio is from 0.30:0.70 to 0.85:0.15.The invention is also directed to a product produced from such process.

    摘要翻译： 本发明涉及制备稳定的液体加合物的方法，其包括在约25℃至约120℃的温度下使1,3-丁二醇和丙二醇的混合物与二苯基甲烷二异氰酸酯反应。 其量使得所得产物的异氰酸酯基含量为约20至约30重量％，并且其中1,3-丁二醇的摩尔当量与丙二醇的摩尔当量的比例为0.05:0.95至 0.95：0.05，另外条件是（i）如二苯基甲烷二异氰酸酯的4,4'-异构体含量等于或大于90重量％，则所述比例为0.45:0.55-0.70:0.30，和 （ii）如果二苯基甲烷二异氰酸酯的4,4'-异构体含量小于90重量％，但不小于70重量％，则所述比例为0.30:0.70至0.85:0.15。 本发明还涉及由这种方法生产的产品。

    Internal mold release agent for use in reaction injection molding
    7.
    发明授权
    Internal mold release agent for use in reaction injection molding 失效
    用于反应注射成型的内部脱模剂

    公开(公告)号：US4886838A

    公开(公告)日：1989-12-12

    申请号：US239153

    申请日：1988-08-31

    申请人： John E. Dewhurst

    发明人： John E. Dewhurst

    IPC分类号： C08K5/098 ,  C08K5/29 ,  C08K5/3445

    CPC分类号： C08K5/29 ,  C08K5/098 ,  C08K5/3445

    摘要： The present invention is directed to a novel mold release agent, a composition containing the mold release, and a method of use of the mold release. The mold release broadly comprises a zinc carboxylate and a specific salt of an amidine-group containing compound.

    摘要翻译： 本发明涉及一种新颖的脱模剂，含有脱模剂的组合物和使用脱模剂的方法。 脱模剂广泛地包括羧酸锌和含脒基化合物的特定盐。

    Rim polyurethane compositions containing internal mold release agents
    8.
    发明授权
    Rim polyurethane compositions containing internal mold release agents 失效
    含有内部脱模剂的轮胎聚氨酯组合物

    公开(公告)号：US4847307A

    公开(公告)日：1989-07-11

    申请号：US229897

    申请日：1988-08-08

    申请人： John E. Dewhurst ,  Stephen J. Harasin

    发明人： John E. Dewhurst ,  Stephen J. Harasin

    IPC分类号： B29C33/60 ,  B29C67/24 ,  C08G18/38 ,  C08G18/65 ,  C08K5/29 ,  C08L75/00

    CPC分类号： C08K5/29 ,  B29C33/60 ,  C08G18/3825 ,  C08G18/6535 ,  C08L75/00 ,  B29C67/246 ,  B29K2075/00 ,  C08G2120/00 ,  C08G2125/00

    摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may optionally be substituted by ether groups, ester groups, amide groups or amidine groups and may also optionally be terminated by isocyanate-reactive groups such as hydroxyl or amino groups, R.sub.4 corresponds to the definition of R.sub.1, R.sub.2 and R.sub.3, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group --NR.sub.2 R.sub.3 and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may, with one or both of the amidine nitrogens, also form a heterocyclic ring.The present invention is also directed to the amidine group-containing salt (iv) and to a polyol composition based on components (ii), (iii) and (iv).

    摘要翻译： 本发明涉及通过使包含（i）多异氰酸酯的反应混合物，（ii）具有至少两个羟基的高分子量聚合物的反应混合物来生产任选细胞的聚氨酯弹性体模制品或任选的细胞刚性结构聚氨酯​​的方法 基团，其分子量为400至约10,000，（iii）约5-50重量％，基于具有至少两个羟基的增链剂组分（ⅱ）的重量，和（iv）约0.05至 基于羧基官能硅氧烷和含有脒基的化合物（I）的盐的组分（ii）和（iii）的重量，10重量％，其中R 1，R 2和R 3是直的 或具有至多30个碳原子的支链，饱和或不饱和烃链，其可以任选被醚基，酯基，酰胺基或脒基取代，并且还可以任选地被异氰酸酯反应性基团例如氢 X或氨基，R 4对应于R 1，R 2和R 3的定义，但可以另外表示具有6至15个碳原子的芳族取代基或可以表示基团-NR 2 R 3，并且R 1，R 2，R 3和R 4可以与一个或多个 两个脒氮都形成杂环。 本发明还涉及含脒基盐（iv）和基于组分（ii），（iii）和（iv）的多元醇组合物。

    Rim polyurethane or polyurea compositions containing internal mold release agents
    10.
    发明授权
    Rim polyurethane or polyurea compositions containing internal mold release agents 失效
    含有内部脱模剂的环氧聚氨酯或聚脲组合物

    公开(公告)号：US4764540A

    公开(公告)日：1988-08-16

    申请号：US114262

    申请日：1987-11-04

    申请人： John E. Dewhurst ,  Stephen J. Harasin ,  Mark C. Cekoric ,  Saad M. Abouzahr

    发明人： John E. Dewhurst ,  Stephen J. Harasin ,  Mark C. Cekoric ,  Saad M. Abouzahr

    IPC分类号： B29C33/60 ,  B29C67/24 ,  C08G18/38 ,  C08G18/65 ,  C08K5/29 ,  C08L75/00 ,  C08G18/14

    CPC分类号： C08K5/29 ,  B29C33/60 ,  C08G18/3825 ,  C08G18/6535 ,  C08L75/00 ,  B29C67/246 ,  B29K2075/00 ,  C08G2120/00 ,  C08G2125/00

    摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two isocyanate-reactive groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two isocyanate-reactive groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may optionally be substituted by ether groups, ester groups, amide groups or amidine groups and may also optionally be terminated by isocyanate-reactive groups such as hydroxyl or amino groups,R.sub.4 corresponds to the definition of R.sub.1, R.sub.2 and R.sub.3, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group --NR.sub.2 R.sub.3 andR.sub.1, R.sub.2, R.sub.3 and R.sub.4 may, with one or both of the amidine nitrogens, also form a heterocyclic ring.The present invention is also directed to the amidine group-containing salt (iv) and to a isocyanate-reactive composition based on components (ii), (iii) and (iv).

    摘要翻译： 本发明涉及通过使含有（i）多异氰酸酯的反应混合物，（ii）具有至少两种异氰酸酯的高分子量聚合物的反应混合物反应生产任选细胞的聚氨酯弹性体模制品或任选的细胞刚性结构聚氨酯​​的方法 基于具有至少两个异氰酸酯反应性基团的增链剂组分（ii）的重量，（iv）约5-50重量％的分子量为约400至约10,000，（iii）约5至50重量％ ）基于羧基官能硅氧烷和含脒基的化合物（I）的盐的组分（ii）和（iii）的重量计约0.05至10重量％，其中R1，R2 并且R 3是具有至多30个碳原子的直链或支链饱和或不饱和烃链，其可以任选地被醚基，酯基，酰胺基或脒基取代，并且还可以任选被异氰酸酯反应 诸如羟基或氨基的基团R4对应于R 1，R 2和R 3的定义，但也可以另外表示具有6至15个碳原子的芳族取代基或可以表示基团-NR 2 R 3，并且R 1，R 2，R 3和R 4可以 与一个或两个脒鎓氮也形成杂环。 本发明还涉及含脒基盐（iv）和基于组分（ii），（iii）和（iv）的异氰酸酯反应性组合物。