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公开(公告)号:US20150344811A1
公开(公告)日:2015-12-03
申请号:US14727916
申请日:2015-06-02
IPC分类号: C10M161/00
CPC分类号: C10M161/00 , C10M2201/066 , C10M2203/1006 , C10M2209/11 , C10M2209/111 , C10M2219/062 , C10M2219/068 , C10M2223/045 , C10M2223/065 , C10N2210/06 , C10N2230/06 , C10N2230/42 , C10N2230/45 , C10N2230/54 , C10N2240/102 , C10N2240/104
摘要: A lubricating oil composition having a sulphated ash content of less than or equal to 1.2 mass % as determined by ASTM D874 and a phosphorous content of less than or equal to 0.12 mass % as determined by ASTM D5185, which lubricating oil composition comprises or is made by admixing: an oil of lubricating viscosity, in a major amount; an oil-soluble or oil-dispersible polymeric friction modifier as an additive in an effective minor amount; and, at least one oil-soluble or oil-dispersible molybdenum compound as an additive in an effective minor amount.
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公开(公告)号:US20170349853A1
公开(公告)日:2017-12-07
申请号:US15611842
申请日:2017-06-02
IPC分类号: C10M145/28 , F01M9/02 , C10M137/10 , C10M129/44 , C10M129/54 , C10M129/70
CPC分类号: C10M145/28 , C10M129/44 , C10M129/54 , C10M129/70 , C10M137/10 , C10M165/00 , C10M2207/128 , C10M2207/262 , C10M2207/281 , C10M2209/104 , C10M2209/109 , C10M2209/112 , C10M2223/045 , C10N2220/021 , C10N2230/04 , C10N2230/06 , C10N2230/10 , C10N2230/12 , C10N2230/18 , C10N2230/52 , C10N2240/10 , F01M9/02
摘要: An additive package is disclosed for preparing an automotive crankcase lubricating oil composition for an internal combustion engine. The additive package is made by admixing: (i) 50 mass % or less of an oil of lubricating viscosity; (ii) 50 mass % or less of at least one overbased metal detergent, preferably at least one overbased metal hydroxybenzoate detergent; (iii) 50 mass % or less of an oil-soluble block or graft co-polymer of at to least one polymeric block A which is derived from a hydroxycarboxylic acid and at least one polyalkylene block B which is a residue of a polyalkylene glycol, and (iv) optionally, at least one further additive selected from a dispersant, an antioxidant and/or an antiwear agent. The additive package includes less than 2.00 mass % preferably less than 1.50 mass %, of a friction modifier which is a monoester of a C5 to C30 carboxylic acid and which is free of nitrogen.Component (ii) is preferably an overbased metal hydroxybenzoate detergent.Component (iii) acts as a friction modifier and can be used as a replacement for a friction modifier such as glycerol monooleate.The additive package exhibits improved stability.
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公开(公告)号:US20190161696A1
公开(公告)日:2019-05-30
申请号:US16201009
申请日:2018-11-27
发明人: Andrew D. Schwarz , Manuel Hartweg , Beatrice Cattoz , Daniel J. Phillips , Anthony J. Strong , Remzi Becer
IPC分类号: C10M149/12 , C08G73/02 , C10M169/04
摘要: A lubricating composition comprises a major amount of an oil of lubricating viscosity and 0.01 to 25 percent by weight based on the weight of the composition, of a poly(2-oxazoline) polymer. The polymer has the repeat unit: —N(COR1)CH2CH2— wherein the number of repeat units (n) in the polymer is an integer between 4 and 1000, such as between 4 and 500. The polymer carries an inorganic or organic nucleophilic polymerisation terminating group (t), and an initiator group (i) connected to the N atom of a repeat unit, the initiator group (i) being effective to initiate the polymerisation of linear, branched or cyclic hydrocarbyl moieties. At least 5% of the total number of the groups R1 in the polymer comprise alkenyl groups having between 15 and 20 carbon atoms.
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公开(公告)号:US20150344810A1
公开(公告)日:2015-12-03
申请号:US14727914
申请日:2015-06-02
IPC分类号: C10M161/00
CPC分类号: C10M161/00 , C10M2201/066 , C10M2203/1006 , C10M2209/11 , C10M2209/111 , C10M2219/062 , C10M2219/068 , C10M2223/045 , C10M2223/065 , C10N2210/06 , C10N2230/06 , C10N2230/42 , C10N2230/45 , C10N2230/54 , C10N2240/102 , C10N2240/106
摘要: A lubricating oil composition having a sulphated ash content of less than or equal to 1.2 mass % as determined by ASTM D874 and a phosphorous content of less than or equal to 0.12 mass % as determined by ASTM D5185, which lubricating oil composition comprises or is made by admixing: an oil of lubricating viscosity, in a major amount; an oil-soluble or oil-dispersible polymeric friction modifier as an additive in an effective minor amount; and, at least one oil-soluble or oil-dispersible molybdenum compound as an additive in an effective minor amount.
摘要翻译: 根据ASTM D874测定的硫酸盐灰分含量小于或等于1.2质量%的润滑油组合物,并且通过ASTM D5185测定的磷含量小于或等于0.12质量%,该润滑油组合物包含或制成 通过混合:大量润滑粘度的油; 油溶性或油分散性聚合物摩擦改进剂作为有效微量的添加剂; 和至少一种油溶性或油分散性钼化合物作为有效微量的添加剂。
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公开(公告)号:US11208611B2
公开(公告)日:2021-12-28
申请号:US16883249
申请日:2020-05-26
IPC分类号: C10M149/10 , C10M101/00 , C10M107/00 , C10M169/04 , C10N30/00 , C10N40/25 , C10N20/02 , C10N30/04 , C10N30/06
摘要: A lubricating oil composition comprising at least 50 percent by mass, based on the mass of the composition of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of a polymer comprising units (a) and one or both units (b) and (c): —N(COR1)(CH2)x— (a) —NH(CH2)y— (b) —N(CH2CH2-k(CH3)kCOOR2)(CH2)z (c) where the total number (n) of units (a), (b) and (c) is an integer between 4 and 500; wherein x, y and z are independently 2 or 3; wherein k is zero or 1. The polymer shows good solubility in the lubricating oil and provides friction modification. A method of synthesising a polymer is also disclosed.
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公开(公告)号:US20210214498A1
公开(公告)日:2021-07-15
申请号:US17149016
申请日:2021-01-14
发明人: Jungyeon Kim , Valentin P. Beyer , Remzi Becer , Beatrice N. Cattoz , Anthony J. Strong , Andrew D. Schwarz , Daniel J. Phillips
IPC分类号: C08G73/02 , C10M149/12 , C07D263/14
摘要: A polymer comprising units having the structure (I): wherein x is 2 or 3, wherein L is (CH2)y, where y is an integer from 1 to 10, or wherein L is CH(CH3)CH2S(CH2)z, where z is an integer from 1 to 5; wherein [Q] is absent or is a polymerised moiety consisting of units having the structure (II): wherein R is a hydrocarbyl group, or a hydrocarbyl group containing one or more heteroatoms, wherein R may be linear, branched or cyclic, saturated or unsaturated, and wherein R has from 1 to 30 carbon atoms; wherein [Q] either consists of identical units of structure (II), or wherein [Q] consists of more than one different units of structure (II), differing in group R; and wherein X is a halogen or another chain terminating group. The polymers may find use as additives in lubricating compositions where they provide friction improvement and wear reduction.
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公开(公告)号:US20200369976A1
公开(公告)日:2020-11-26
申请号:US16883249
申请日:2020-05-26
IPC分类号: C10M149/10 , C10M169/04 , C10M101/00 , C10M107/00
摘要: A lubricating oil composition comprising at least 50 percent by mass, based on the mass of the composition of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of a polymer comprising units (a) and one or both units (b) and (c): —N(COR1)(CH2)x— (a) —NH(CH2)y— (b) —N(CH2CH2-k(CH3)kCOOR2)(CH2)z (c) where the total number (n) of units (a), (b) and (c) is an integer between 4 and 500; wherein x, y and z are independently 2 or 3; wherein k is zero or 1. The polymer shows good solubility in the lubricating oil and provides friction modification. A method of synthesising a polymer is also disclosed.
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公开(公告)号:US20190161698A1
公开(公告)日:2019-05-30
申请号:US16201045
申请日:2018-11-27
发明人: Andrew D. Schwarz , Manuel Hartweg , Beatrice Cattoz , Daniel J. Phillips , Anthony J. Strong , Remzi Becer
IPC分类号: C10M149/12 , C08G73/02 , C10M169/04
摘要: A lubricating composition comprises a major amount of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of an oil-soluble copolymer, The copolymer comprises units (a) and units (b): —N(COR1)CH2CH2— (a) —N(COR2)CH2CH2CH2— (b) wherein the polymer carries an inorganic or organic nucleophilic polymerisation terminating group (t), and an initiator group (i) connected to the N atom of a repeat unit (a) or (b), the initiator group (i) being effective to initiate the polymerisation of linear branched or cyclic hydrocarbyl moieties. R1 and R2 are the same or different and comprise a single or a mixture of linear, branched or cyclic hydrocarbyl groups having 1-50 carbon atoms, some or all having 12-50 carbon atoms, or of at least one macro-monomeric hydrocarbyl group with more than 50 carbon atoms.
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公开(公告)号:US20150344812A1
公开(公告)日:2015-12-03
申请号:US14727923
申请日:2015-06-02
IPC分类号: C10M161/00
CPC分类号: C10M161/00 , C10M2203/1006 , C10M2209/111 , C10M2223/045 , C10N2210/02 , C10N2230/06 , C10N2230/12 , C10N2230/42 , C10N2230/45 , C10N2240/102 , C10N2240/106
摘要: A lubricating oil composition having a sulphated ash content of less than or equal to 1.2 mass % as determined by ASTM D874 and a phosphorous content of less than or equal to 0.12 mass % as determined by ASTM D5185, which lubricating oil composition comprises or is made by admixing: an oil of lubricating viscosity, in a major amount; an oil-soluble or oil-dispersible polymeric friction modifier as an additive in an effective minor amount; and, an oil-soluble or oil-dispersible dihydrocarbyl dithiophosphate metal salt as an additive in an effective minor amount.
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公开(公告)号:US11505650B2
公开(公告)日:2022-11-22
申请号:US17149016
申请日:2021-01-14
发明人: Jungyeon Kim , Valentin P. Beyer , Remzi Becer , Beatrice N. Cattoz , Anthony J. Strong , Andrew D. Schwarz , Daniel J. Phillips
IPC分类号: C08G73/02 , C07D263/14 , C10M149/12
摘要: A polymer comprising units having the structure (I): wherein x is 2 or 3, wherein L is (CH2)y, where y is an integer from 1 to 10, or wherein L is CH(CH3)CH2S(CH2)z, where z is an integer from 1 to 5; wherein [Q] is absent or is a polymerised moiety consisting of units having the structure (II): wherein R is a hydrocarbyl group, or a hydrocarbyl group containing one or more heteroatoms, wherein R may be linear, branched or cyclic, saturated or unsaturated, and wherein R has from 1 to 30 carbon atoms; wherein [Q] either consists of identical units of structure (II), or wherein [Q] consists of more than one different units of structure (II), differing in group R; and wherein X is a halogen or another chain terminating group. The polymers may find use as additives in lubricating compositions where they provide friction improvement and wear reduction.
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