公开(公告)号：US10414702B2

公开(公告)日：2019-09-17

申请号：US14769702

申请日：2014-02-18

Applicant: IFP ENERGIES NOUVELLES ,  Arkema France

Inventor： Catherine Laroche ,  Damien Leinekugel Le Cocq ,  Philibert LeFlaive ,  Frederic Augier ,  Ludivine Bouvier ,  Cecile Lutz ,  Sylvie Szendrovics ,  Quitterie Persillon

IPC: C07C7/12 ,  C07C7/13 ,  B01D15/18 ,  B01J20/18 ,  B01J20/28

Abstract: Process for separating xylenes starting from a feed comprising cuts of isomers of aromatic hydrocarbons containing 8 carbon atoms, in a simulated moving bed, by selective adsorption of a xylene isomer in the presence of a desorbent, by means of particles of agglomerated zeolitic adsorbent based on zeolite crystals with a number-average diameter less than or equal to 1.2 μm, wherein the number-average diameter of said particles of adsorbent is between 150 μm and 500 μm and the mechanical strength measured by the Shell method series SMS1471-74 adapted for agglomerates with a size below 500 μm is greater than or equal to 2 MPa.

公开(公告)号：US10421706B2

公开(公告)日：2019-09-24

申请号：US15551754

申请日：2016-02-17

Applicant: IFP Energies Nouvelles ,  Compagnie Generale des Etablissements Michelin

Inventor： Romain Richard ,  Damien Leinekugel Le Cocq ,  Marc Jacquin ,  Margarita Dorato ,  Nuno Pacheco ,  Claire Rannoux

IPC: C07C67/08 ,  C07C1/213 ,  C07C67/54 ,  C07C67/58 ,  C07C69/08 ,  C07C69/16 ,  C07C69/28

Abstract: The invention relates to a conversion method that is fed with a diol feedstock that comprises at least 90% by weight of diol and a carboxylic acid feedstock that comprises at least 80% by weight of carboxylic acid. The method comprising at least: An esterification step which is fed with at least the diol feedstock and at least the carboxylic acid feedstock, wherein the carboxylic acid/diol molar ratio at the inlet of the esterification step is between 2 and 6, the esterification step comprises at least one reactive distillation column that has a mixed reaction/separation zone located between two separation zones; and A water elimination step that is fed with distillate from the esterification step that comprises water and producing at least one water effluent.

公开(公告)号：US10150717B2

公开(公告)日：2018-12-11

申请号：US15918222

申请日：2018-03-12

Applicant: IFP Energies Nouvelles

Inventor： Alexandre Vonner ,  Damien Leinekugel Le Cocq ,  Catherine Laroche ,  Pascal Etienne

IPC: C07C7/13 ,  B01D15/18

Abstract: The present invention describes a process for the simulated moving bed separation of xylenes, in which the operating conditions are optimized by means of a specific relationship between the cycle time and the flow rate of the desorbant.

公开(公告)号：US10035739B2

公开(公告)日：2018-07-31

申请号：US15326836

申请日：2015-06-10

Applicant: IFP Energies nouvelles

Inventor： Heloise Dreux ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq

IPC: C07C5/27

CPC classification number: C07C5/2737 ,  C07C5/2775 ,  C07C7/005 ,  C07C7/04 ,  C07C7/13 ,  C07C2529/40 ,  C07C2529/74 ,  C07C15/08

Abstract: The present invention describes a process for the production of high-purity paraxylene from a xylenes cut capable of containing ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two isomerization units.

公开(公告)号：US20140319025A1

公开(公告)日：2014-10-30

申请号：US14360322

申请日：2012-10-16

Applicant: IFP ENERGIES NOUVELLES

Inventor： Fredèric Augier ,  Arnaud Baudot ,  Jeremy Gazarian ,  Damien Leinekugel Le Cocq

IPC: C10G21/12

CPC classification number: C10G53/12 ,  C10G19/02 ,  C10G19/08 ,  C10G21/08 ,  C10G21/12 ,  C10G21/28 ,  C10G21/30 ,  C10G53/06

Abstract: Process of extracting sulphur-containing compounds from a hydrocarbon cut of the gasoline or LPG type by liquid-liquid extraction with a soda solution employing a unit (2) for pretreatment of the feedstock to be treated located upstream of the unit (4) for extraction with soda, said pretreatment unit consisting of a first pretreatment reactor operating in batch mode followed by a second continuous reactor of the piston type operating in piston mode.

Abstract translation: 从汽油或LPG型烃馏分中提取含硫化合物的方法，采用液体萃取法，采用单位（2）进行液 - 液萃取，用于预处理位于单元（4）上游的待处理原料用于提取 所述预处理单元包括以分批模式操作的第一预处理反应器，随后是以活塞模式操作的活塞式第二连续反应器。

公开(公告)号：US20140284250A1

公开(公告)日：2014-09-25

申请号：US14360385

申请日：2012-10-16

Applicant: IFP Energies Nouvelles

Inventor： Frederic Augier ,  Arnaud Baudot ,  Jeremy Gazarian ,  Damien Leinekugel Le Cocq

IPC: C10G21/28

CPC classification number: C10G21/28 ,  C10G19/02 ,  C10G21/08 ,  C10G21/30

Abstract: Process of extracting sulphur-containing compounds from a hydrocarbon cut of the gasoline or LPG type by liquid-liquid extraction with a soda solution employing a unit (2) for pretreatment of the feedstock to be treated placed upstream of the extraction unit (4), the soda being introduced into the extraction column (4) in the form of two circuits operating either in parallel, or in series.

Abstract translation: 通过液体 - 液体萃取法从汽油或LPG型烃馏分中提取含硫化合物的方法，该苏打溶液采用单位（2）预处理待处理的原料，置于提取单元（4）的上游， 苏打水以并行或串联运行的两个回路的形式引入萃取塔（4）。

公开(公告)号：US10363494B2

公开(公告)日：2019-07-30

申请号：US15581237

申请日：2017-04-28

Applicant: IFP Energies nouvelles

Inventor： Frederic Augier ,  Frederic Bazer-Bachi ,  Vincent Coupard ,  Damien Leinekugel Le Cocq

IPC: B01D3/00

Abstract: The present invention describes a device for supplying the catalytic zone of a reactive distillation column using a liquid stream as the reaction stream, the flow of liquid in the reactive zone being of the upflow type and gas not encountering the liquid in the reactive zone.

公开(公告)号：US10214467B2

公开(公告)日：2019-02-26

申请号：US15982649

申请日：2018-05-17

Applicant: IFP Energies nouvelles

Inventor： Alexandre Vonner ,  Damien Leinekugel Le Cocq ,  Catherine Laroche ,  Pascal Etienne

IPC: C07C7/13 ,  B01D15/18

Abstract: The present invention describes a process for the simulated moving bed separation of xylenes which can be used for the treatment of paraxylene-rich feeds (more than 25% by weight of paraxylene), in which the operating conditions are optimized by means of a specific relationship between the cycle time and the desorbant flow rate.

公开(公告)号：US09708550B2

公开(公告)日：2017-07-18

申请号：US14360322

申请日：2012-10-16

Applicant: IFP ENERGIES NOUVELLES

Inventor： Frederic Augier ,  Arnaud Baudot ,  Jeremy Gazarian ,  Damien Leinekugel Le Cocq

IPC: C10G19/02 ,  C10G19/08 ,  C10G21/08 ,  C10G21/28 ,  C10G53/06 ,  C10G53/12 ,  C10G21/30 ,  C10G21/12

CPC classification number: C10G53/12 ,  C10G19/02 ,  C10G19/08 ,  C10G21/08 ,  C10G21/12 ,  C10G21/28 ,  C10G21/30 ,  C10G53/06

Abstract: Process of extracting sulphur-containing compounds from a hydrocarbon cut of the gasoline or LPG type by liquid-liquid extraction with a soda solution employing a unit (2) for pretreatment of the feedstock to be treated located upstream of the unit (4) for extraction with soda, said pretreatment unit consisting of a first pretreatment reactor operating in batch mode followed by a second continuous reactor of the piston type operating in piston mode.

公开(公告)号：US09447001B2

公开(公告)日：2016-09-20

申请号：US14095404

申请日：2013-12-03

Applicant: IFP Energies nouvelles

Inventor： Pascal Etienne ,  Philibert Leflaive ,  Damien Leinekugel Le Cocq ,  Catherine Laroche

IPC: C07C7/12 ,  C07C7/13 ,  B01D15/18 ,  B01J20/18 ,  B01J20/28

CPC classification number: C07C7/13 ,  B01D15/1828 ,  B01D15/1842 ,  B01J20/186 ,  B01J20/28011 ,  B01J20/2803 ,  C07C15/08

Abstract: This invention describes a process for separation of xylenes for the purpose of the production of high-purity metaxylene, a simulated countercurrent process using at least one adsorber with a limited cumulative total level (Hcu) of adsorbent at a surface velocity (Vsl) that is less than 2 cm/s.

Abstract translation: 本发明描述了用于生产高纯度间二甲苯的二甲苯的分离方法，使用至少一种具有吸附剂的累积总量（Hcu）的吸附剂的表面速度（Vsl）为至少一种吸附剂的模拟逆流方法 小于2厘米/秒。