公开(公告)号：US11456432B2

公开(公告)日：2022-09-27

申请号：US16759788

申请日：2018-11-01

申请人： IDEMITSU KOSAN CO.,LTD.

发明人： Takayasu Sado ,  Tetsuya Masuda ,  Yoshiaki Takahashi ,  Emiko Kambe

IPC分类号： H01L51/50 ,  H01L51/00 ,  H01L51/52

摘要： A top emission organic EL device includes an anode, hole transporting zone, emitting layer, electron transporting zone, and cathode in this order. The hole transporting zone includes: a first layer interposed between the anode and the emitting layer; and a second layer interposed between the first layer and the emitting layer. The first layer contains a first compound and the second layer contains a second compound. A film thickness of the first layer and the second layer satisfies a formula (1) and (2), respectively. A hole mobility μH1 of the first compound satisfies a formula (3) and a hole mobility μH2 of the second compound satisfies a formula (4), 100 nm≤d1≤300 nm  (1) 1 nm≤d2≤20 nm  (2) 1.0×10−4 [cm2/Vs]≤μH1≤1.0×10−1 [cm2/Vs]  (3) 1.0×10−10 [cm2/Vs]≤μH2≤1.0×10−6 [cm2/Vs]  (4).

公开(公告)号：US20180102485A1

公开(公告)日：2018-04-12

申请号：US15840848

申请日：2017-12-13

申请人： IDEMITSU KOSAN CO., LTD.

发明人： Sayaka MIZUTANI ,  Takayasu Sado

IPC分类号： H01L51/00 ,  C07D405/14 ,  C07D409/10 ,  C07D409/14 ,  C09K11/02 ,  C09K11/06 ,  H01L51/50 ,  C07D405/10

CPC分类号： H01L51/0067 ,  C07D405/10 ,  C07D405/14 ,  C07D409/10 ,  C07D409/14 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0055 ,  H01L51/0071 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/5004 ,  H01L51/5016 ,  H01L51/5072 ,  H01L51/5092 ,  H01L51/5096 ,  H01L2251/305 ,  H01L2251/552 ,  H01L2251/558

摘要： An organic EL device includes an anode, an emitting layer, an electron transporting zone and a cathode in this sequence, in which the electron transporting zone contains an aromatic heterocyclic derivative represented by a formula (1) below. In the formula (1), X1 to X3 are a nitrogen atom or CR1, and A is represented by a formula (2) below. In the formula (2), L1 is s single bond or a linking group, and HAr is represented by a formula (3) below. In the formula (3), Y1 is an oxygen atom, a sulfur atom or the like, and one of X11 to X18 is a carbon atom bonded to L1 by a single bond and the rest of X11 to X18 are a nitrogen atom or CR13.

公开(公告)号：US11362279B2

公开(公告)日：2022-06-14

申请号：US16901610

申请日：2020-06-15

申请人： IDEMITSU KOSAN CO., LTD.

发明人： Tomoki Kato ,  Takayasu Sado ,  Takahiro Fujiyama

IPC分类号： H01L51/00 ,  H01L51/50 ,  C09B11/04 ,  C09B57/00 ,  C07D333/76 ,  C07C211/61 ,  C07D307/91 ,  C07C255/58 ,  C07D405/12 ,  C07D409/12 ,  C07C217/80 ,  C07C217/92 ,  C07D209/86 ,  C09K11/06 ,  H01L51/52

摘要： An aromatic amine derivative represented by formula (1): wherein R1, R2, R3, L, Ar1, Ar2, k, m, and n are the same as defined in the specification, is useful as a material for an organic EL device and realizes an organic EL device with a high efficiency and a long lifetime even when driving it at a low voltage.

公开(公告)号：US10510964B2

公开(公告)日：2019-12-17

申请号：US15834156

申请日：2017-12-07

申请人： IDEMITSU KOSAN CO., LTD.

发明人： Sayaka Mizutani ,  Takayasu Sado

IPC分类号： H01L51/50 ,  H01L51/00 ,  C07D471/04 ,  C07D519/00

摘要： A compound is represented by a formula (1) below. In the formula (1), X1 to X8 each independently represent a carbon atom to be bonded to a group represented by the following formula (20), CRX or a nitrogen atom. At least one of X1 to X8 is a carbon atom to be bonded to the group represented by the following formula (2). RX is each independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, or the like.

公开(公告)号：US20180047917A1

公开(公告)日：2018-02-15

申请号：US15727667

申请日：2017-10-09

申请人： IDEMITSU KOSAN CO., LTD

发明人： Tetsuya INOUE ,  Mitsunori Ito ,  Tomoki Kato ,  Kumiko Gorai ,  Kazuki Nishimura ,  Takayasu Sado

IPC分类号： H01L51/00 ,  C07D405/14 ,  C09K11/02 ,  H05B33/14 ,  H01L51/50 ,  H01L51/05 ,  C07D403/14 ,  C09K11/06 ,  B82Y10/00

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  C07D403/14 ,  C07D405/14 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0036 ,  H01L51/0054 ,  H01L51/0067 ,  H01L51/0073 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H05B33/14

摘要： Provided are an organic electroluminescence device having high current efficiency and a long lifetime, and a biscarbazole derivative for realizing the device. The biscarbazole derivative has a specific substituent. The organic EL device has a plurality of organic thin-film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin-film layers contains the biscarbazole derivative.

公开(公告)号：US09847501B2

公开(公告)日：2017-12-19

申请号：US14358043

申请日：2012-11-21

申请人： IDEMITSU KOSAN CO., LTD.

发明人： Sayaka Mizutani ,  Takayasu Sado

IPC分类号： H01L51/50 ,  C07D405/14 ,  C07D409/14 ,  C07D491/048 ,  C09K11/06 ,  H05B33/14 ,  C07D471/04 ,  C07D487/06 ,  C07F7/08 ,  C07D519/00 ,  C09B57/00 ,  H01L51/00

CPC分类号： H01L51/5016 ,  C07D405/14 ,  C07D409/14 ,  C07D471/04 ,  C07D487/06 ,  C07D491/048 ,  C07D519/00 ,  C07F7/0812 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/0055 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5096 ,  H05B33/14

摘要： An aromatic heterocyclic derivative is represented by a formula (1) below. In the formula (1), X1 to X3 each are a nitrogen atom or CR1, with a proviso that at least one of X1 to X3 is a nitrogen atom. A is represented by a formula (2) and B is represented by a formula (4) below.

公开(公告)号：US09373802B2

公开(公告)日：2016-06-21

申请号：US14318738

申请日：2014-06-30

申请人： IDEMITSU KOSAN CO., LTD.

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Tomoki Kato ,  Kumiko Gorai ,  Kazuki Nishimura ,  Takayasu Sado

IPC分类号： H01L35/24 ,  H01L51/05 ,  C09K11/06 ,  H01L51/50 ,  H05B33/14 ,  C07D405/14 ,  C07D403/14 ,  H01L51/00 ,  B82Y10/00

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  C07D403/14 ,  C07D405/14 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0036 ,  H01L51/0054 ,  H01L51/0067 ,  H01L51/0073 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H05B33/14

摘要： Provided are an organic electroluminescence device having high current efficiency and a long lifetime, and a biscarbazole derivative for realizing the device. The biscarbazole derivative has a specific substituent. The organic EL device has a plurality of organic thin-film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin-film layers contains the biscarbazole derivative.

摘要翻译： 提供了具有高电流效率和长寿命的有机电致发光器件和用于实现器件的双咔唑衍生物。 双咔唑衍生物具有特定的取代基。 有机EL器件具有多个有机薄膜层，其包括在阴极和阳极之间的发光层，并且至少一层有机薄膜层含有双咔唑衍生物。

公开(公告)号：US20150287931A1

公开(公告)日：2015-10-08

申请号：US14410949

申请日：2013-06-20

申请人： IDEMITSU KOSAN CO., LTD. ,  MITSUI CHEMICALS, INC.

发明人： Tomoki Kato ,  Takayasu Sado ,  Takahiro Fujiyama

IPC分类号： H01L51/00 ,  C07D409/12 ,  C07D307/77 ,  C07D409/14 ,  C07D405/14 ,  C07F7/08 ,  C07D307/91 ,  C07D405/12

CPC分类号： H01L51/0061 ,  C07D307/77 ,  C07D307/91 ,  C07D405/12 ,  C07D405/14 ,  C07D409/12 ,  C07D409/14 ,  C07F5/025 ,  C07F7/0812 ,  C07F15/0033 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0094 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/5206 ,  H01L51/5221

摘要： An organic electroluminescence device having a long lifetime and a higher emission efficiency and a specific aromatic amine derivative which provides such an organic electroluminescence device are provided. In the specific aromatic amine derivative, a dibenzofuranyl group or a dibenzothiophenyl group is bonded via a p-phenylene and a heteroaryl group is bonded via a m-phenylene. The organic electroluminescence device includes a cathode, an anode and an organic thin film layer including one or more layers which is disposed between the cathode and the anode. The organic thin film layer includes at least one light emitting layer and at least one layer of the organic thin film layer includes the aromatic amine derivative singly or in combination.

摘要翻译： 提供具有长寿命和较高发射效率的有机电致发光器件和提供这种有机电致发光器件的特定芳族胺衍生物。 在特定的芳族胺衍生物中，二苯并呋喃基或二苯并噻吩基通过对亚苯基键合，杂芳基通过间亚苯基键合。 有机电致发光器件包括阴极，阳极和包括设置在阴极和阳极之间的一层或多层的有机薄膜层。 有机薄膜层包括至少一个发光层，并且至少一层有机薄膜层单独地或组合地包括芳族胺衍生物。

公开(公告)号：US20150263292A1

公开(公告)日：2015-09-17

申请号：US14424703

申请日：2013-08-29

申请人： IDEMITSU KOSAN CO., LTD. ,  MITSUI CHEMICALS, INC.

发明人： Tomoki Kato ,  Takayasu Sado ,  Takahiro Fujiyama

IPC分类号： H01L51/00 ,  C07D409/12 ,  C07D307/91 ,  C07D405/12

摘要： An aromatic amine derivative represented by formula (1): wherein HAr1, Ar2, L1, L2, and L3 are as defined in the specification, is useful as a material for constituting an organic EL device and realizes an organic EL device having a high efficiency and a long lifetime even when driving at a low voltage.

摘要翻译： 由式（1）表示的芳族胺衍生物：其中，HAr1，Ar2，L1，L2和L3如说明书中所定义，可用作构成有机EL器件的材料，实现了高效率的有机EL器件 并且即使在低电压下行驶也具有长寿命。

公开(公告)号：US12089492B2

公开(公告)日：2024-09-10

申请号：US17748108

申请日：2022-05-19

申请人： IDEMITSU KOSAN CO., LTD.

发明人： Sayaka Mizutani ,  Takayasu Sado

IPC分类号： H01L51/54 ,  C07D405/10 ,  C07D405/14 ,  C07D409/10 ,  C07D409/14 ,  C09K11/02 ,  C09K11/06 ,  H10K50/11 ,  H10K50/16 ,  H10K85/60 ,  H10K50/17 ,  H10K50/18 ,  H10K101/10 ,  H10K101/30 ,  H10K101/40 ,  H10K102/00 ,  H10K102/10

CPC分类号： H10K85/654 ,  C07D405/10 ,  C07D405/14 ,  C07D409/10 ,  C07D409/14 ,  C09K11/025 ,  C09K11/06 ,  H10K50/11 ,  H10K50/16 ,  H10K85/615 ,  H10K85/622 ,  H10K85/623 ,  H10K85/657 ,  H10K85/6574 ,  H10K85/6576 ,  C09K2211/1007 ,  C09K2211/1011 ,  H10K50/171 ,  H10K50/18 ,  H10K2101/10 ,  H10K2101/30 ,  H10K2101/40 ,  H10K2102/101 ,  H10K2102/351

摘要： An organic EL device includes an anode, an emitting layer, an electron transporting zone and a cathode in this sequence, in which the electron transporting zone contains an aromatic heterocyclic derivative represented by a formula (1) below. In the formula (1), X1 to X3 are a nitrogen atom or CR1, and A is represented by a formula (2) below. In the formula (2), L1 is s single bond or a linking group, and HAr is represented by a formula (3) below. In the formula (3), Y1 is an oxygen atom, a sulfur atom or the like, and one of X11 to X18 is a carbon atom bonded to L1 by a single bond and the rest of X11 to X18 are a nitrogen atom or CR13.