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公开(公告)号:US20220219981A1
公开(公告)日:2022-07-14
申请号:US17572547
申请日:2022-01-10
发明人: Yuon Chiu , Haiyou Wang , Haluk Kopkalli , Christian Jungong , Haridasan K. Nair , Rajiv Ratna Singh , Daniel C. Merkel , Tao Wang , Terris Yang , Richard Wilcox
摘要: A method of removing water from a mixture of iodine (I2) and water includes providing a mixture comprising iodine and water and: contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a concentrated acid to absorb water from the mixture, separating the water from mixture by distillation, contacting the mixture with a gas that is inert to iodine (I2), contacting the mixture with hydrogen iodide (HI), or combinations thereof.
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2.
公开(公告)号:US20190352242A1
公开(公告)日:2019-11-21
申请号:US16529287
申请日:2019-08-01
发明人: Yuon Chiu , Stephen A. Cottrell , Gustavo Cerri , Jennifer W. McClaine , Tao Wang , Rajiv Ratna Singh , Rajiv Banavali
IPC分类号: C07C17/386 , B01D3/14 , B01D3/36 , C07C19/01 , C07C21/18 , C07C17/38 , B01D3/00 , C01B7/19 , C07C17/383 , B01D3/06
摘要: The present disclosure provides separation processes for removing heavy organics that are formed in various production processes of HCFO-1233zd(E). Such separation processes allow for the recovery and/or separation of the heavy organics from reactants that are used to form HCFO-1233zd(E), including HF. Such separation or recovery processes may utilize various separation techniques (e.g., decanting, liquid-liquid separation, distillation, and flash distillation) and may also utilize the unique properties of azeotropic or azeotrope-like compositions. Recovery of the heavy organic that is substantially free from HF may allow for their use in subsequent manufacture processes or disposal.
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公开(公告)号:US20240165447A1
公开(公告)日:2024-05-23
申请号:US18400106
申请日:2023-12-29
发明人: Haluk Kopkalli , Jennifer W. McClaine , Tao Wang , Richard Wilcox , Yuon Chiu , Hang T. Pham
CPC分类号: A62D1/0057 , B01D3/143 , B01D3/36 , B01D11/04 , C08J9/125 , C08J9/127 , C08J9/147 , C09K3/30 , C09K5/044 , C09K5/048 , C08J2203/10 , C08J2203/144 , C08J2203/182 , C09K2205/128 , C09K2205/24 , C09K2205/32
摘要: Heterogeneous azeotrope or azeotrope-like compositions comprising trifluoroiodomethane (CF3I) and water which may include from about 47.7 wt. % to about 99.0 wt. % trifluoroiodomethane (CF3I) and from about 1.0 wt. % to about 52.3 wt. % water and having a boiling point between about 18.0° C. and about 19.0° C. at a pressure of between about 58.0 psia and about 60.0 psia. The azeotrope or azeotrope-like compositions may be used to separate impurities from trifluoroiodomethane (CF3I).
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公开(公告)号:US20220219980A1
公开(公告)日:2022-07-14
申请号:US17572542
申请日:2022-01-10
发明人: Yuon Chiu , Haluk Kopkalli , Tao Wang , Kevin Uhrich
IPC分类号: C01B7/14 , B01J20/18 , B01J20/34 , B01D53/14 , B01D53/26 , B01D53/04 , B01D7/00 , B01D5/00 , B01D53/28
摘要: Methods of recovering iodine (I2) from a stream including iodine (I2) vapor and at least one of: an inert gas and water vapor can include contacting the stream with an alkaline solution to form an iodide salt, contacting the stream with an adsorbent to selectively adsorb water from the stream, contacting the stream with a concentrated acid to absorb the water vapor from the stream, desublimating or condensing the iodine (I2) vapor to form solid or liquid iodine (I2), or contacting the stream with a material to condense or de-sublimate the iodine (I2) vapor from the stream as the material at least one of: absorbs latent heat through a phase change of the material and absorbs sensible heat.
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公开(公告)号:US20220080243A1
公开(公告)日:2022-03-17
申请号:US17466694
申请日:2021-09-03
发明人: Haluk Kopkalli , Jennifer W. McClaine , Tao Wang , Richard Wilcox , Yuon Chiu , Hang T. Pham
摘要: Heterogeneous azeotrope or azeotrope-like compositions comprising trifluoroiodomethane (CF3I) and water which may include from about 47.7 wt. % to about 99.0 wt. % trifluoroiodomethane (CF3I) and from about 1.0 wt. % to about 52.3 wt. % water and having a boiling point between about 18.0° C. and about 19.0° C. at a pressure of between about 58.0 psia and about 60.0 psia. The azeotrope or azeotrope-like compositions may be used to separate impurities from trifluoroiodomethane (CF3I).
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公开(公告)号:US20240279151A1
公开(公告)日:2024-08-22
申请号:US18570428
申请日:2022-07-11
发明人: Haluk Kopkalli , Daniel C. Merkel , Haiyou Wang , Terris Yang , Richard Wilcox , Tao Wang , Jennifer W. McClaine , Gavin Towler , Haridasan K. Nair
CPC分类号: C07C51/64 , B01D3/40 , B01D11/0492
摘要: The present disclosure provides a method of removing iodine (I2) and iodine-containing species from processes for producing trifluoroiodomethane (CF3I). The present disclosure further provides another method of removing iodine and iodine-containing species from trifluoroacetyl iodide (TFAI).
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公开(公告)号:US20220219979A1
公开(公告)日:2022-07-14
申请号:US17572544
申请日:2022-01-10
发明人: Yuon Chiu , Haiyou Wang , Haluk Kopkalli , Christian Jungong , Haridasan K. Nair , Rajiv Ratna Singh , Daniel C. Merkel , Tao Wang , Terris Yang , Richard Wilcox
摘要: A method of removing water from a mixture of hydrogen iodide (HI) and water includes providing a mixture comprising hydrogen iodide and water and contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a weak acid to absorb water from the mixture and/or separating the water from hydrogen iodide (HI) by azeotropic distillation to produce anhydrous hydrogen iodide (HI).
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8.
公开(公告)号:US20180194703A1
公开(公告)日:2018-07-12
申请号:US15850724
申请日:2017-12-21
发明人: Yuon Chiu , Stephen A. Cottrell , Gustavo Cerri , Jennifer W. McClaine , Tao Wang , Rajiv Ratna Singh , Rajiv Banavali
IPC分类号: C07C17/386 , C07C21/18 , C07C19/01 , B01D3/06 , B01D3/36
CPC分类号: C07C17/386 , B01D3/009 , B01D3/06 , B01D3/143 , B01D3/36 , B01D2257/2047 , B01D2257/70 , C01B7/196 , C07C17/38 , C07C17/383 , C07C19/01 , C07C21/18 , Y02P20/127
摘要: The present disclosure provides separation processes for removing heavy organics that are formed in various production processes of HCFO-1233zd(E). Such separation processes allow for the recovery and/or separation of the heavy organics from reactants that are used to form HCFO-1233zd(E), including HF. Such separation or recovery processes may utilize various separation techniques (e.g., decanting, liquid-liquid separation, distillation, and flash distillation) and may also utilize the unique properties of azeotropic or azeotrope-like compositions. Recovery of the heavy organic that is substantially free from HF may allow for their use in subsequent manufacture processes or disposal.
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