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公开(公告)号：US3907668A
公开(公告)日：1975-09-23
申请号：US45433374
申请日：1974-03-25
CPC分类号： B01J23/88 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/20 , C10G45/08
摘要： Sulfur-containing petroleum distillates are desulfurized with hydrogen and with a catalyst composite containing a Group VI-B hydrogenating component, at least one iron group hydrogenating component and alumina. The catalyst is prepared by calcining alumina having a bayerite content of 0-50 wt. percent, at a temperature of 800*-1600*F, impregnating the calcined alumina with the hydrogenating components and calcining the impregnated alumina at 800*-1600*F. The composite catalyst is characterized as having a pore volume of at least 0.5cc/g, a surface area of at least 150 m2/g and an average pore radius of 45 to 75 Angstrom units. At least 65 percent of the pore volume of the composite catalyst is in pores having a radius in the range of 50 - 300 Angstrom units.
摘要翻译： 含硫的石油馏出物用氢气和含有VI-B族氢化组分，至少一种铁基氢化组分和氧化铝的催化剂复合物脱硫。 该催化剂是通过煅烧具有0-50重量％的三羟铝石的氧化铝制备的。 的百分比，在800-116°F的温度下，用煅烧组分浸渍煅烧的氧化铝并在800-116℃下煅烧浸渍的氧化铝。复合催化剂的特征在于孔体积至少为0.5cc / g，表面积至少为150m 2 / g，平均孔半径为45〜75埃。 复合催化剂的至少65％的孔体积在半径在50-300埃单位范围内的孔中。
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公开(公告)号：US3876680A
公开(公告)日：1975-04-08
申请号：US32669273
申请日：1973-01-26
CPC分类号： B01J23/85 , B01J23/88 , B01J23/888 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/20 , C10G45/50
摘要： Aromatic hydrocarbons are hydrogenated in the presence of hydrogen and a catalyst composite comprising at least two hydrogenating agents and an alumina support having a controlled bayerite concentration, average pore radius, and pore volume distribution and further having been calcined at a temperature in the range of 800.degree.- 1,600.degree. F. (427.degree. 871.degree. C.) prior to impregnation of the hydrogenating agent.
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公开(公告)号：US3905893A
公开(公告)日：1975-09-16
申请号：US39036273
申请日：1973-08-22
CPC分类号： C10G65/04 , C10G2300/107
摘要： A multiple stage process is described for the catalytic hydrodesulfurization and hydrodemetallization of a residual petroleum oil boiling above the gasoline range. The product of the process comprises essentially material boiling above the gasoline range and comprises little material boiling below the initial boiling point of the residual oil feed. The hydrodesulfurization-demetallization process comprises an initial stage involving relatively high hydrogen pressure in the presence of a catalyst comprising a relatively low proportion of catalytically active hydrogenation metals. The process employs a final stage in series having a relatively lower hydrogen pressure and a catalyst comprising a relatively higher proportion of hydrogenation metals. The stream entering the final stage contains an amount up to 10, 20 or even 25 weight percent of the asphaltene content of the charge to the first stage while the effluent from the final stage is essentially free of asphaltenes.
摘要翻译： 描述了沸点高于汽油范围的残余石油的催化加氢脱硫和加氢脱金属的多阶段方法。 该方法的产物基本上在汽油范围之上的材料沸腾，并且包含沸点低于残油进料的初始沸点的少量材料。 加氢脱硫脱金属过程包括在催化剂存在下包含相对较低比例的催化活性氢化金属的相对高的氢气压力的初始阶段。 该方法采用具有相对较低的氢气压力的串联的最终阶段和包含相对较高比例的氢化金属的催化剂。 进入最后阶段的料流含有高达10,20或甚至25重量％的第一阶段装料的沥青质含量，而最终阶段的流出物基本上不含沥青质。
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公开(公告)号：US3898155A
公开(公告)日：1975-08-05
申请号：US42636373
申请日：1973-12-19
发明人： WILSON GEOFFREY R
CPC分类号： B01J35/10 , B01J23/85 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/109 , C10G2300/107
摘要： Heavy oils containing sulfur and at least 80 parts per million metals are simultaneously demetallized and desulfurized by contacting the oil under hydrogenation conditions with a catalyst composition comprising a Group VI-B metal and at least one Group VIII metal composited with alumina, said catalyst composition having an average pore diameter greater than 100 A units, from 10-40 percent of the total pore volume in macropores and from 6090 percent of the total pore volume in micropores, and at least 80 percent of the micropore volume being in pores having a diameter of at least 100 A units.
摘要翻译： 含硫量至少为80ppm的重油同时脱金属脱硫，通过在氢化条件下与油接触，与包含VI-B族金属和至少一种与矾土复合的Ⅷ族金属的催化剂组合物接触，所述催化剂组合物具有 平均孔径大于100A单位，占大孔中总孔体积的10-40％，微孔中总孔体积的60-90％，至少80％的微孔体积在孔中具有 直径至少为100 A单位。
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