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    Two-stage residual oil hydrodesulfurication process with ammonia addition
    1.
    发明授权
    Two-stage residual oil hydrodesulfurication process with ammonia addition 失效
    具有氨水添加剂的两阶段残留油加氢过程

    公开(公告)号：US3860511A

    公开(公告)日：1975-01-14

    申请号：US43458274

    申请日：1974-01-22

    申请人： GULF RESEARCH DEVELOPMENT CO

    发明人： BRUNN LOUIS W ,  FRAYER JAMES A ,  PARASKOS JOHN A

    IPC分类号： C10G65/04 ,  C10G23/02

    CPC分类号： C10G65/04

    摘要： A process for hydrodesulfurization of an asphaltic oil in the presence of a catalyst comprising Group VI and Group VIII metals on alumina in two stages in series wherein a greater quantity of catalyst is required in the second stage than in the first stage. Ammonia is added to the second stage to tend to equalize the amount of catalyst and the space velocity in each stage.

    摘要翻译： 在包含第Ⅵ族和第Ⅷ族金属的催化剂存在下在沥青油中加氢脱硫的方法分两个阶段进行，其中在第二阶段需要比第一阶段更大量的催化剂。 在第二阶段加入氨以倾向于使催化剂的量和每个阶段的空间速度相等。

    Plural stage residue hydrodesulfurization process
    4.
    发明授权
    Plural stage residue hydrodesulfurization process 失效
    多级残渣加氢脱硫工艺

    公开(公告)号：US3905893A

    公开(公告)日：1975-09-16

    申请号：US39036273

    申请日：1973-08-22

    申请人： GULF RESEARCH DEVELOPMENT CO

    发明人： CHRISTMAN ROBERT D ,  HENKE ALFRED M ,  PARASKOS JOHN A ,  WILSON GEOFFREY R ,  YANIK STEPHEN J

    IPC分类号： C10G65/04 ,  C10G34/00

    CPC分类号： C10G65/04 ,  C10G2300/107

    摘要： A multiple stage process is described for the catalytic hydrodesulfurization and hydrodemetallization of a residual petroleum oil boiling above the gasoline range. The product of the process comprises essentially material boiling above the gasoline range and comprises little material boiling below the initial boiling point of the residual oil feed. The hydrodesulfurization-demetallization process comprises an initial stage involving relatively high hydrogen pressure in the presence of a catalyst comprising a relatively low proportion of catalytically active hydrogenation metals. The process employs a final stage in series having a relatively lower hydrogen pressure and a catalyst comprising a relatively higher proportion of hydrogenation metals. The stream entering the final stage contains an amount up to 10, 20 or even 25 weight percent of the asphaltene content of the charge to the first stage while the effluent from the final stage is essentially free of asphaltenes.

    摘要翻译： 描述了沸点高于汽油范围的残余石油的催化加氢脱硫和加氢脱金属的多阶段方法。 该方法的产物基本上在汽油范围之上的材料沸腾，并且包含沸点低于残油进料的初始沸点的少量材料。 加氢脱硫脱金属过程包括在催化剂存在下包含相对较低比例的催化活性氢化金属的相对高的氢气压力的初始阶段。 该方法采用具有相对较低的氢气压力的串联的最终阶段和包含相对较高比例的氢化金属的催化剂。 进入最后阶段的料流含有高达10,20或甚至25重量％的第一阶段装料的沥青质含量，而最终阶段的流出物基本上不含沥青质。

    Multiple stage hydrodesulfurization with greater sulfur and metal removal in initial stage
    5.
    发明授权
    Multiple stage hydrodesulfurization with greater sulfur and metal removal in initial stage 失效
    初级阶段大型硫磺和金属去除的多阶段加氢脱硫

    公开(公告)号：US3876530A

    公开(公告)日：1975-04-08

    申请号：US39048173

    申请日：1973-08-22

    申请人： GULF RESEARCH DEVELOPMENT CO

    发明人： FRAYER JAMES A ,  KO DANIEL Y ,  PARASKOS JOHN A

    IPC分类号： C10G45/08 ,  C10G65/04 ,  C10G23/02

    CPC分类号： C10G45/08 ,  C10G2300/107

    摘要： A multiple stage process is described for the catalytic hydrodesulfurization and hydrodemetallization of a residual petroleum oil boiling above the gasoline range. The product of the process comprises essentially material boiling above the gasoline range and comprises little material boiling below the initial boiling point of the residual oil feed. The hydrodesulfurization-demetallization process comprises an initial stage involving relatively high hydrogen pressure in the presence of a catalyst comprising a relatively low proportion of catalytically active hydrogenation metals in which demetallization activity is high with an unaged catalyst but diminishes as the catalyst becomes aged. The process employs a final stage in series having a relatively lower hydrogen pressure and a catalyst comprising a relatively higher proportion of hydrogenation metals in which the demetallization activity is lower with an unaged catalyst but increases as the catalyst becomes aged. The stream entering the final stage contains an amount up to 10, 20 or even 25 weight percent of the asphaltene content of the charge to the first stage while the effluent from the final stage is essentially free of asphaltenes.

    Hydrodesulfurization of crude and residual oils at reduced space velocity
    8.
    发明授权
    Hydrodesulfurization of crude and residual oils at reduced space velocity 失效
    原油和残油在降低空间速度下的水解

    公开(公告)号：US3706657A

    公开(公告)日：1972-12-19

    申请号：US3706657D

    申请日：1970-12-31

    申请人： GULF RESEARCH DEVELOPMENT CO

    发明人： PARASKOS JOHN A ,  SOMERS ALLEN E

    IPC分类号： C10G45/02 ,  C10G23/02

    CPC分类号： C10G45/02 ,  C10G2300/107

    摘要： A PROCESS FOR HYDRODESULFURIZING A CRUDE OIL OR A RESIDUAL OIL COMPRISES PASSING THE OIL AND HYDROGEN OVER AN HDS CATALYST, WITH THE HDS CATALYST CYCLE BEING LIMITED BY THE MAXIMUM TEMPERATURE THAT THE REACTOR METALS CAN WITHSTAND AT THE PROCESS PRESSURE. AS THE HYDRODESULFURIZATION PROCEEDS, METALS FROM THE FEED OIL ARE DEPOSITED ON THE CATALYST UNTIL MAXIMUM POSSIBLE METALS LOADING ON THE CATALYST IS REACHED. AS THE PROCESS PROCEEDS, A CONTINUAL TEMPERATURE RISE IS REQUIRED TO ACHIEVE THE REQUIRED SULFUR REMOVAL UNTIL THE MAXIMUM OR CONSTRAINT TEMPERATURE IS REACHED. ACCORDING TO THIS INVENTION, IT HAS BEEN FOUND THAT BY MAINTAINING THE SPACE VELOCITY AT A SUFFICIENTLY LOW VALUE THE CATALYST EXPERIENCES MAXIMUM METALS LOADING BEFORE THE CONSTRAINT TEMPERATURE IS REACHED SO THAT FULL CATALYST LIFE IS UTILIZED.

    Fcc process utilizing divided catalyst injection
    9.
    发明授权
    Fcc process utilizing divided catalyst injection 失效
    FCC工艺利用分解的催化剂注射

    公开(公告)号：US3639228A

    公开(公告)日：1972-02-01

    申请号：US3639228D

    申请日：1969-10-28

    申请人： GULF RESEARCH DEVELOPMENT CO

    发明人： CARR NORMAN L ,  PARASKOS JOHN A ,  KO DANIEL Y

    IPC分类号： C10G11/18 ,  C01B33/28 ,  C10G11/20

    CPC分类号： C10G11/18

    摘要： A fluid catalytic cracking system in which hydrocarbon feed and a zeolite catalyst or a catalyst of comparable activity and/or selectivity to gasoline is charged to a reactor having a short residence time is improved by charging only a portion of the fresh or freshly regenerated catalyst which is used to the inlet of the reactor together with the hydrocarbon feed and charging the remainder of the freshly regenerated catalyst substantially without hydrocarbon feed downstream in the reactor. This arrangement results in a higher gasoline yield and a higher selectivity to gasoline in the reactor.

    摘要翻译： 一种流化催化裂化系统，其中将烃进料和沸石催化剂或具有与汽油相当的活性和/或选择性的催化剂加入到具有短停留时间的反应器中，通过仅装入一部分新鲜或新鲜再生的催化剂来改进， 与烃进料一起用于反应器入口，并将新鲜再生催化剂的剩余部分基本上不含有反应器下游的烃进料。 这种排列导致较高的汽油产率和较高的反应器汽油选择性。