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1.发明申请公开(公告)号：US20060280673A1
公开(公告)日：2006-12-14
申请号：US11451208
申请日：2006-06-12
申请人： Felice DiMascio
发明人： Felice DiMascio
IPC分类号： B01J21/00
CPC分类号： C01B11/024 , B01J21/12 , B01J21/16 , B01J23/42 , B01J37/0018 , B01J37/0203
摘要： A process for producing chlorine dioxide comprises flowing an aqueous acidified chlorite salt solution of into a catalyst element, wherein the catalyst element comprises an aluminosilicate hydrogel-bonded porous ceramic support defining a plurality of tortuous pathways and catalyst particles and/or catalytic sites disposed on surfaces defining the tortuous pathways; and contacting the aqueous solution of chlorous acid with the catalyst particles and/or catalytic sites to form chlorine dioxide in the aqueous solution.
摘要翻译： 一种生产二氧化氯的方法包括将含水酸化的亚氯酸盐溶液流入催化剂元件，其中催化剂元件包括界定多个曲折路径的硅铝酸盐水凝胶结合的多孔陶瓷载体，以及设置在表面上的催化剂颗粒和/或催化位点 界定曲折路径; 并使氯酸水溶液与催化剂颗粒和/或催化部位接触，以在水溶液中形成二氧化氯。
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公开(公告)号：US09719178B2
公开(公告)日：2017-08-01
申请号：US14193281
申请日：2014-02-28
申请人： Felice DiMascio , Heather D. Willauer , Dennis R. Hardy , Frederick Williams , M. Kathleen Lewis
发明人： Felice DiMascio , Heather D. Willauer , Dennis R. Hardy , Frederick Williams , M. Kathleen Lewis
CPC分类号： C25B1/10 , C01B31/20 , C01B32/50 , C02F2001/46185 , C02F2201/46115 , C25B1/00 , C25B9/10 , Y02E60/366
摘要： An electrochemical cell for the continuous acidification of alkaline water sources and recovery of carbon dioxide with simultaneous continuous hydrogen gas production having a center compartment, an electrolyte-free anode compartment having a mesh anode in direct contact with an ion permeable membrane, an endblock in direct contact with the anode where the endblock provides a gas escape route behind the anode, an electrolyte-free cathode compartment having a mesh cathode in direct contact with an ion permeable membrane, and an endblock in direct contact with the cathode where the endblock provides a gas escape route behind the cathode. Current applied to the electrochemical cell for generating hydrogen gas also lowers the pH of the alkaline water to produce carbon dioxide with no additional current or power. Also disclosed is the related method for continuously acidifying alkaline water sources and recovering carbon dioxide with continuous hydrogen gas production.
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公开(公告)号：US07476307B2
公开(公告)日：2009-01-13
申请号：US10773797
申请日：2004-02-05
申请人： Felice DiMascio
发明人： Felice DiMascio
CPC分类号： C01B11/024 , C25B1/22 , C25B15/08
摘要： Processes for generating chlorine dioxide generally include acidifying an alkali metal chlorite solution; and contacting the acidified alkali metal chlorite solution with a solid phase chlorine-containing material to produce chlorine dioxide. An exemplary system for generating chlorine dioxide generally includes a water source in fluid communication with a conduit that is fluidly connected to a vessel, wherein the vessel comprises a housing, an inlet in fluid communication with the housing and the conduit, an outlet, and a solid phase chlorine-containing material disposed within the housing; an acid source downstream from the water source in fluid communication with the conduit; and a chlorite ion source in fluid communication with the conduit downstream from the acid source. Various means are provided for the acid source.
摘要翻译： 产生二氧化氯的方法通常包括酸化碱金属亚氯酸盐溶液; 并将酸化的碱金属亚氯酸盐溶液与固相含氯物质接触以产生二氧化氯。 用于产生二氧化氯的示例性系统通常包括与流体连接到容器的导管流体连通的水源，其中容器包括壳体，与壳体和导管流体连通的入口，出口和 设置在壳体内的固相含氯材料; 水源下游的酸源与导管流体连通; 以及与酸源下游的导管流体连通的亚氯酸盐离子源。 为酸源提供了各种方法。
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4.发明申请公开(公告)号：US20070034570A1
公开(公告)日：2007-02-15
申请号：US11502778
申请日：2006-08-11
申请人： Felice DiMascio
发明人： Felice DiMascio
IPC分类号： B01D65/02
CPC分类号： B01D69/08 , B01D61/12 , B01D65/02 , B01D2311/06 , B01D2321/168 , B01D2311/10 , B01D2311/14 , B01D2311/16
摘要： A process for reducing and/or eliminating biofilm growth and removal thereof formed during operation of pressure-induced filtration systems such as reverse osmosis systems. The systems and methods are particularly suitable for use with pressure-driven membrane filtration, including microfiltration, ultrafiltration, nanofiltration and reverse osmosis.
摘要翻译： 用于减少和/或消除在压力诱导的过滤系统如反渗透系统的操作期间形成的生物膜生长和去除的方法。 该系统和方法特别适用于压力驱动膜过滤，包括微滤，超滤，纳滤和反渗透。
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公开(公告)号：US20050252786A1
公开(公告)日：2005-11-17
申请号：US10514175
申请日：2002-07-17
申请人： Felice DiMascio
发明人： Felice DiMascio
IPC分类号： B01D61/46 , C01B11/00 , C01B11/02 , C25B1/24 , C25B1/26 , C25B9/06 , C25B9/16 , C25C7/00 , C25D17/00
摘要： An electrolytic process and apparatus (20) for oxidizing inorganic or organic species is disclosed. The process and apparatus includes contacting a solution containing the inorganic or organic species with an electrocatalytic material disposed in the electrolytic reactor (200). Also disclosed is a process for fabricating a ceramic catalyst material for use in the electrolytic reactors (200) and processes.
摘要翻译： 公开了用于氧化无机或有机物质的电解方法和装置（20）。 该方法和设备包括使含有无机或有机物质的溶液与设置在电解反应器（200）中的电催化材料接触。 还公开了一种用于制造用于电解反应器（200）的陶瓷催化剂材料和方法的方法。
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公开(公告)号：US06913741B2
公开(公告)日：2005-07-05
申请号：US10065259
申请日：2002-09-30
申请人： Felice DiMascio
发明人： Felice DiMascio
CPC分类号： C01B11/00 , C01B11/024 , C01B11/08
摘要： A system and process for oxidizing inorganic or organic species is disclosed. The system and process includes feeding a dilute aqueous alkali metal halite solution into a cation exchange column, wherein the cation exchange column contains a cation exchange material; contacting the dilute aqueous alkali metal halite solution with the cation exchange material to produce an effluent containing halous acid; feeding the effluent containing halous acid into a catalytic reactor containing a catalytic material; and contacting the halous acid containing effluent with the catalytic material to produce a halogen oxide.
摘要翻译： 公开了用于氧化无机或有机物质的系统和方法。 该系统和方法包括将稀碱水溶液碱盐水溶液进料到阳离子交换柱中，其中阳离子交换柱含有阳离子交换材料; 使稀碱金属盐水溶液与阳离子交换材料接触以产生含有卤酸的流出物; 将含有卤酸的流出物进料到含有催化材料的催化反应器中; 并将含卤代的流出物与催化材料接触以产生卤素氧化物。
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公开(公告)号：US20050095192A1
公开(公告)日：2005-05-05
申请号：US10986610
申请日：2004-11-12
申请人： Felice DiMascio
发明人： Felice DiMascio
CPC分类号： C01B11/00 , C01B11/024 , C01B11/08
摘要： A system and process for oxidizing inorganic or organic species is disclosed. The system and process includes feeding a dilute aqueous alkali metal halite solution into an cation exchange column, wherein the cation exchange column contains a cation exchange material; contacting the dilute aqueous alkali metal halite solution with the cation exchange material to produce an effluent containing halous acid; feeding the effluent containing halous acid into a catalytic reactor containing a catalytic material; and contacting the halous acid containing effluent with the catalytic material to produce a halogen oxide.
摘要翻译： 公开了用于氧化无机或有机物质的系统和方法。 该系统和方法包括将稀碱水溶碱金属盐水溶液进料到阳离子交换柱中，其中阳离子交换柱含有阳离子交换材料; 使稀碱金属盐水溶液与阳离子交换材料接触以产生含有卤酸的流出物; 将含有卤酸的流出物进料到含有催化材料的催化反应器中; 并将含卤代的流出物与催化材料接触以产生卤素氧化物。
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公开(公告)号：US5868915A
公开(公告)日：1999-02-09
申请号：US717781
申请日：1996-09-23
CPC分类号： B01D61/48 , B01J47/08 , C02F1/42 , C02F1/469 , C02F1/4695 , C02F2103/08
摘要： An improved electrodeionization apparatus and method are provided. The electrodeionization apparatus includes electrolyte compartments, ion-concentrating, and ion-depleting compartments, having electroactive media therein. The electroactive media can be induced to have a reversible change in its chemical or electrical properties upon imposition of an external electrical field or the presence of an electrically charged substance. The change in chemical or electrical properties of the media results in a desired change in the transport or chemical properties of the media. The incorporation of the improved electroactive media also provides for an improved, and more reliable electrodeionization process in applications requiring chemical and temperature resistance media, where localized pH shifts would be harmful to the product being deionized, under temperature and chemical conditions of the liquid to be processed, or under circumstances where traditional media would tend to foul.
摘要翻译： 提供了一种改进的电去电离装置和方法。 电去离子装置包括其中具有电活性介质的电解质隔室，离子浓缩和离子消耗隔间。 在施加外部电场或带电物质的存在时，可以诱导电活性介质在其化学或电学性质上具有可逆的变化。 介质的化学或电学性质的变化导致介质的运输或化学性质的期望的变化。 改进的电活性介质的并入还提供了在需要化学和耐温介质的应用中的改进的和更可靠的电去离子法，其中局部pH偏移将对待去离子的产物在待处理的液体的温度和化学条件下是有害的 处理或在传统媒体倾向犯规的情况下。
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公开(公告)号：US10046990B2
公开(公告)日：2018-08-14
申请号：US13153656
申请日：2011-06-06
申请人： Felice DiMascio
发明人： Felice DiMascio
IPC分类号： C02F1/00 , C02F1/48 , C02F1/72 , C02F1/76 , C02F1/78 , C02F1/469 , C02F1/467 , C25B1/26 , C25B1/34 , C25C1/00
摘要： The invention is directed to an apparatus and methods of its use to generate chlorine dioxide. The apparatus comprises three cation exchange resin chambers in fluidic communication to convert chlorite salt into chlorine dioxide. Unlike previous converters, the invention utilizes an novel method of acidifying some of the chlorite to produce a more effective process. The invention can achieve a 100% theoretical yield which is s significant improvement over the 80% theoretical yield in previous attempts using non-acidifying chemistry. The method also avoids the need for expensive catalysts.
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10.发明授权公开(公告)号：US08663365B2
公开(公告)日：2014-03-04
申请号：US13571383
申请日：2012-08-10
CPC分类号： C02F1/20 , B01D19/0031 , B01D61/00 , B01D63/02 , B01D2311/13 , B01D2311/18 , C01B32/50 , C02F1/44 , C02F1/66 , C02F2103/08 , C02F2209/06 , C02F2301/063 , Y02C10/10
摘要： A method for recovering carbon dioxide from acidified seawater using a membrane contactor and passing seawater with a pH less than or equal to 6 over the outside of a hollow fiber membrane tube while applying vacuum or a hydrogen sweep gas to the inside of the hollow fiber membrane tube, wherein up to 92% of the re-equilibrated [CO2]T is removed from the natural seawater.
摘要翻译： 一种使用膜接触器从酸化海水中回收二氧化碳的方法，并且在中空纤维膜管的外侧通过pH小于或等于6的海水，同时向中空纤维膜的内部施加真空或氢气吹扫气体 管，其中至多92％的再平衡的[CO 2] T从天然海水中去除。
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