公开(公告)号：US10585225B2

公开(公告)日：2020-03-10

申请号：US15726881

申请日：2017-10-06

Applicant: FUJIFILM Corporation

Inventor： Miho Asahi ,  Ayako Matsumoto ,  Shuntaro Ibuki ,  Shinya Watanabe ,  Hajime Nakayama ,  Naoya Shibata

IPC: G02B5/30 ,  G02B27/28 ,  B32B27/18 ,  G09F9/00 ,  B32B27/00 ,  G02B1/14 ,  B32B27/22 ,  G02F1/1335 ,  C08J7/04

Abstract: A transparent film includes: a base material; and at least one scratch resistant layer of which indentation hardness is 300 MPa or greater and of which a thickness is 50 to 1,000 nm on an outermost surface of the transparent film at one side or both sides of the base material, and a number of times of folding endurance of the transparent film measured by an MIT testing machine according to JIS P8115 (2001) is 1,000 times or greater.

公开(公告)号：US09903982B2

公开(公告)日：2018-02-27

申请号：US15059899

申请日：2016-03-03

Applicant: FUJIFILM Corporation

Inventor： Naoya Shibata ,  Miho Asahi ,  Hajime Nakayama ,  Ayako Matsumoto

IPC: G02B27/00 ,  G02B1/118 ,  G02B1/111 ,  G02B1/14 ,  G02B5/30 ,  C03C17/00

CPC classification number: G02B1/118 ,  C03C17/007 ,  C03C17/008 ,  C03C2217/43 ,  C03C2217/445 ,  C03C2217/465 ,  C03C2217/475 ,  C03C2217/478 ,  C03C2217/732 ,  G02B1/111 ,  G02B1/14 ,  G02B5/3033

Abstract: An antireflection article includes a substrate; and an antireflection layer containing a binder resin and inorganic particles, wherein the inorganic particles are particles having an average primary particle diameter of 150 nm to 250 nm and a CV value of 4% or less, 99.9% or more of the inorganic particles are perfectly spherical particles, the antireflection layer includes a moth eye structure composed of an unevenness shape formed by the inorganic particles on a surface of the antireflection layer, and an area occupancy ratio of the inorganic particles on the surface of the antireflection layer is 25% to 64%.

公开(公告)号：US11827727B2

公开(公告)日：2023-11-28

申请号：US18055660

申请日：2022-11-15

Applicant: FUJIFILM Corporation

Inventor： Soichiro Watanabe ,  Yutaka Nozoe ,  Takashi Iizumi ,  Akio Tamura ,  Tomoaki Yokota ,  Keisuke Yoshimasa ,  Ayako Matsumoto

IPC: C08F220/58 ,  C08L33/24 ,  C09K19/54 ,  G02B5/30 ,  B32B27/30 ,  C09K19/56

CPC classification number: C08F220/585 ,  C08L33/24 ,  C09K19/542 ,  G02B5/3016 ,  B32B27/30 ,  B32B2457/20 ,  B32B2457/202 ,  B32B2457/206 ,  C09K19/56 ,  C09K2019/548 ,  C09K2323/02 ,  C09K2323/025 ,  C09K2323/03 ,  C09K2323/035

Abstract: A photo-alignment polymer has a repeating unit represented by Formula (1), in Formula (1), R1 represents a hydrogen atom or a substituent, X represents —O—, —S—, or —NR2—, in which R2 represents a hydrogen atom or a substituent, L1 represents a single bond or a divalent linking group, P represents a photo-aligned group, and A represents an acid-cleavage group which is decomposed by an action of acid to produce a polar group

公开(公告)号：US20190011607A1

公开(公告)日：2019-01-10

申请号：US16130327

申请日：2018-09-13

Applicant: FUJIFILM Corporation

Inventor： Ayako Matsumoto ,  Shuntaro Ibuki

IPC: G02B1/14 ,  F21V8/00

Abstract: Provided are an optical film including a base material, and a hard coat layer, in which a refractive index of the base material at a wavelength of 550 nm is 1.60 or more, a difference between a refractive index of the base material at a wavelength of 435 nm and a refractive index of the base material at a wavelength of 610 nm is 0.11 or more, and a peak intensity PV value of a power spectrum obtained by subjecting a reflectivity spectrum of the optical film to fast Fourier transform is 0.3 or less, a polarizing plate having the optical film and an image display device.

公开(公告)号：US09874659B2

公开(公告)日：2018-01-23

申请号：US15059899

申请日：2016-03-03

Applicant: FUJIFILM Corporation

Inventor： Naoya Shibata ,  Miho Asahi ,  Hajime Nakayama ,  Ayako Matsumoto

IPC: G02B27/00 ,  G02B1/118 ,  G02B1/111 ,  G02B1/14 ,  G02B5/30 ,  C03C17/00

Abstract: An antireflection article includes a substrate; and an antireflection layer containing a binder resin and inorganic particles, wherein the inorganic particles are particles having an average primary particle diameter of 150 nm to 250 nm and a CV value of 4% or less, 99.9% or more of the inorganic particles are perfectly spherical particles, the antireflection layer includes a moth eye structure composed of an unevenness shape formed by the inorganic particles on a surface of the antireflection layer, and an area occupancy ratio of the inorganic particles on the surface of the antireflection layer is 25% to 64%.

公开(公告)号：US11644604B2

公开(公告)日：2023-05-09

申请号：US16130327

申请日：2018-09-13

Applicant: FUJIFILM Corporation

Inventor： Ayako Matsumoto ,  Shuntaro Ibuki

IPC: G02B5/30 ,  G02F1/1335 ,  B32B27/18 ,  B32B27/34 ,  B32B7/023 ,  G02B1/14 ,  F21V8/00

CPC classification number: G02B5/305 ,  B32B7/023 ,  B32B27/18 ,  B32B27/34 ,  G02B1/14 ,  G02B5/30 ,  G02B5/3033 ,  G02B6/0026 ,  G02B6/0056 ,  G02F1/1335 ,  B32B2307/418 ,  B32B2307/42 ,  B32B2457/20

Abstract: Provided are an optical film including a base material, and a hard coat layer, in which a refractive index of the base material at a wavelength of 550 nm is 1.60 or more, a difference between a refractive index of the base material at a wavelength of 435 nm and a refractive index of the base material at a wavelength of 610 nm is 0.11 or more, and a peak intensity PV value of a power spectrum obtained by subjecting a reflectivity spectrum of the optical film to fast Fourier transform is 0.3 or less, a polarizing plate having the optical film and an image display device.

公开(公告)号：US10338276B2

公开(公告)日：2019-07-02

申请号：US14851722

申请日：2015-09-11

Applicant: FUJIFILM Corporation

Inventor： Miho Asahi ,  Kazuo Kamohara ,  Shuntaro Ibuki ,  Ayako Matsumoto ,  Daiki Wakizaka

IPC: G02B1/14 ,  G02B5/30 ,  G02B1/111 ,  G02B1/118

Abstract: There is provided an antireflective film, including: a plastic substrate; a infiltration layer; and an antireflective layer containing metallic oxide fine particles with an average primary particle diameter of 50 nm to 250 nm and a viscosity increasing compound, in this order, wherein the infiltration layer contains a polymer of a (meth)acrylate compound having a molecular weight of 400 or less, and the antireflective layer has a moth-eye structure including an uneven shape formed by the metallic oxide fine particles.

公开(公告)号：US11306188B2

公开(公告)日：2022-04-19

申请号：US16437378

申请日：2019-06-11

Applicant: FUJIFILM Corporation

Inventor： Ayako Matsumoto ,  Shuntaro Ibuki ,  Chihiro Masuda

IPC: G02B1/14 ,  C08J7/046 ,  B05D3/12 ,  B29C43/24 ,  B32B7/02 ,  C09D5/33 ,  C09D7/61 ,  C09D135/02

Abstract: An optical film has a base material and a hardcoat layer, in which a pencil hardness is 2H or higher, the number of times of folding endurance measured by an MIT tester is 1000 or more, an incident ray is made incident on the optical film from −60° with respect to a normal direction of the optical film, an angle width within which 10% of outgoing ray peak intensity is obtained is 6° or less, and an intensity of outgoing ray at 50° from the normal direction is 1% or less of the outgoing ray peak intensity. A method for manufacturing an optical film has a step of applying a hardcoat layer forming composition to a base material to provide a coating film, and a step of curing the coating film while bringing the coating film into contact with one smooth metal roll.

公开(公告)号：US10399309B2

公开(公告)日：2019-09-03

申请号：US15280052

申请日：2016-09-29

Applicant: FUJIFILM Corporation

Inventor： Miho Asahi ,  Ayako Matsumoto ,  Shuntaro Ibuki ,  Makoto Uchimura

IPC: B32B27/20 ,  B29D11/00 ,  B32B27/30 ,  G02B1/118 ,  G02B5/30 ,  G02B5/02

Abstract: An antireflection film includes: a substrate; and an antireflection layer formed with a composition containing metal oxide particles having surface hydroxyl groups as particles for forming a moth eye structure, and two compounds having (meth)acryloyl groups, where the antireflection layer contains a binder resin including at least one of a structure derived from the two (meth)acryloyl groups, and the moth eye structure has an irregular shape formed with the metal oxide particles on a surface on a side opposite to an interface on the substrate side, and in the irregular shape of the antireflection layer, B/A is a ratio between a distance A between peaks of adjacent convex portions and a distance B between a center between peaks of the adjacent convex portions and a concave portion is 0.5 or greater.

公开(公告)号：US10718887B2

公开(公告)日：2020-07-21

申请号：US15883594

申请日：2018-01-30

Applicant: FUJIFILM Corporation

Inventor： Ayako Matsumoto ,  Daiki Wakizaka ,  Shuntaro Ibuki

IPC: G02B27/00 ,  G02B1/118 ,  B32B7/02 ,  G02B1/14 ,  B32B3/26 ,  B32B27/20 ,  B32B3/30 ,  B32B27/06 ,  G02B1/04 ,  B05D5/06 ,  B05D3/06 ,  B05D3/02 ,  B05D1/28

Abstract: The present invention provides a method of manufacturing an antireflection film, including the successive steps of: applying a composition including a curable compound (a1), a plurality of particles (a2), and a solvent on a substrate, and volatilizing the solvent to provide a layer (a), the layer (a) having a portion in which the particles (a2) do not exist, and the portion having a thickness being 0.8 times the average primary particle diameter of the particles (a2) or greater; curing a portion of the curable compound (a1); causing a portion of the curable compound (a1) to permeate the substrate or to be volatilized so as to form an uneven shape; and curing the curable compound (a1) remained in the layer (a).