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![Preparation of 3-[5′-(3,4-bis(hydroxymethyl)benzyloxy)-2′-ethyl-2-propylbiphenyl-4-yl]pentan-3-ol](/abs-image/US/2009/12/29/US07638657B2/abs.jpg.150x150.jpg)
1.发明授权Preparation of 3-[5′-(3,4-bis(hydroxymethyl)benzyloxy)-2′-ethyl-2-propylbiphenyl-4-yl]pentan-3-ol 失效制备3- [5' - （3,4-双（羟甲基）苄氧基）-2'-乙基-2-丙基联苯-4-基]戊-3-醇公开(公告)号：US07638657B2
公开(公告)日：2009-12-29
申请号：US11802029
申请日：2007-05-18
Applicant: Eric Terranova , Sebastien Daver , Christine Marty , Jean-Claude Pascal
Inventor： Eric Terranova , Sebastien Daver , Christine Marty , Jean-Claude Pascal
CPC classification number: C07C41/26 , C07C37/20 , C07C39/12 , C07C45/673 , C07C45/71 , C07C49/83 , C07C49/84 , C07C43/23
Abstract: 3-[5′-(3,4-bis(hydroxymethyl)benzyloxy)-2′-ethyl-2-propylbiphenyl-4-yl]pentan-3-ol is prepared from the novel intermediate, 6-ethyl-4′-(1-ethyl-1-hydroxypropyl)-2′-propylbiphenyl-3-ol.
Abstract translation: 由新型中间体6-乙基-4'-氧代-3,4-二氢吡啶制备3- [5' - （3,4-双（羟甲基）苄氧基）-2'-乙基-2-丙基联苯-4-基]戊-3-醇， （1-乙基-1-羟丙基）-2'-丙基联苯-3-醇。
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2.发明申请NOVEL PHENYLBORONIC ACID COMPOUNDS AND INTERMEDIATES AND PROCESSES FOR THE PREPARATION THEREOF 审中-公开新型苯硼酸化合物及其制备方法及其制备方法公开(公告)号：US20100145105A1
公开(公告)日：2010-06-10
申请号：US12635255
申请日：2009-12-10
Applicant: Eric Terranova , Jean-Claude Pascal
Inventor： Eric Terranova , Jean-Claude Pascal
IPC: C07C43/205
Abstract: Vitamin D derivatives, notably non-steroidal vitamin D derivatives, are prepared from novel disubstituted phenylboronic acid compounds having the formula (I): and also from the novel intermediates having the formulae (1), (2), (3) and (10):
Abstract translation: 维生素D衍生物，特别是非甾体维生素D衍生物，由具有式（I）的新型二取代苯基硼酸化合物制备：以及具有式（1），（2），（3）和（10）的新型中间体 ）：
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3.发明申请公开(公告)号：US20100087669A1
公开(公告)日：2010-04-08
申请号：US12635299
申请日：2009-12-10
Applicant: Eric TERRANOVA , Jean-Claude Pascal
Inventor： Eric TERRANOVA , Jean-Claude Pascal
Abstract: Vitamin D derivatives, notably non-steroidal vitamin D derivatives, are prepared from novel disubstituted phenylboronic acid compounds having the formula (I): and also from the novel intermediates having the formulae (1), (2), (3) and (10):
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![Novel method for the preparation of 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid](/abs-image/US/2008/04/17/US20080091045A1/abs.jpg.150x150.jpg)
4.发明申请Novel method for the preparation of 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid 有权用于制备6- [3-（1-金刚烷基）-4-甲氧基苯基] -2-萘甲酸的新方法公开(公告)号：US20080091045A1
公开(公告)日：2008-04-17
申请号：US11905955
申请日：2007-10-05
Applicant: Eric Terranova , Jean-Claude Pascal
Inventor： Eric Terranova , Jean-Claude Pascal
IPC: C07C51/367
CPC classification number: C07C51/367 , C07C65/24
Abstract: A novel method for preparing 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid includes a Suzuki reaction between 3-adamantyl-4-methoxyphenylboronic acid of formula (II): and 6-bromo-2-naphthoic acid of formula (III):
Abstract translation: 制备6- [3-（1-金刚烷基）-4-甲氧基苯基] -2-萘甲酸的新方法包括式（II）的3-金刚烷基-4-甲氧基苯基硼酸与6-溴-2 式（III）的萘甲酸：
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![Method for the preparation of 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid](/abs-image/US/2009/03/03/US07498461B2/abs.jpg.150x150.jpg)
5.发明授权Method for the preparation of 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid 有权6- [3-（1-金刚烷基）-4-甲氧基苯基] -2-萘甲酸的制备方法公开(公告)号：US07498461B2
公开(公告)日：2009-03-03
申请号：US11905955
申请日：2007-10-05
Applicant: Eric Terranova , Jean-Claude Pascal
Inventor： Eric Terranova , Jean-Claude Pascal
IPC: C07C63/34
CPC classification number: C07C51/367 , C07C65/24
Abstract: A novel method for preparing 6-[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid includes a Suzuki reaction between 3-adamantyl-4-methoxyphenylboronic acid of formula (II): and 6-bromo-2-naphthoic acid of formula (III):
Abstract translation: 制备6- [3-（1-金刚烷基）-4-甲氧基苯基] -2-萘甲酸的新方法包括式（II）的3-金刚烷基-4-甲氧基苯基硼酸与6-溴-2 式（III）的萘甲酸：
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Patent Agency Ranking
6.发明申请公开(公告)号：US20070015931A1
公开(公告)日：2007-01-18
申请号：US11454859
申请日：2006-06-19
Applicant: Eric Terranova , Jean-Claude Pascal
Inventor： Eric Terranova , Jean-Claude Pascal
IPC: C07F5/02
Abstract: Vitamin D derivatives, notably non-steroidal vitamin D derivatives, are prepared from novel disubstituted phenylboronic acid compounds having the formula (I): and also from the novel intermediates having the formulae (1), (2), (3) and (10):
Abstract translation: 维生素D衍生物，特别是非甾体维生素D衍生物，由具有式（I）的新型二取代苯基硼酸化合物制备：以及具有式（1），（2），（3）和（10）的新型中间体 ）：
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7.发明授权公开(公告)号：US07659421B2
公开(公告)日：2010-02-09
申请号：US11454859
申请日：2006-06-19
Applicant: Eric Terranova , Jean-Claude Pascal
Inventor： Eric Terranova , Jean-Claude Pascal
IPC: C07F5/04
Abstract: Vitamin D derivatives, notably non-steroidal vitamin D derivatives, are prepared from novel disubstituted phenylboronic acid compounds having the formula (I): and also from the novel intermediates having the formulae (1), (2), (3) and (10):
Abstract translation: 维生素D衍生物，特别是非甾体维生素D衍生物，由具有式（I）的新型二取代苯基硼酸化合物制备：以及具有式（1），（2），（3）和（10）的新型中间体 ）：
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8.发明授权7,7-disubstituted (5H,9H)-6,8-dioxabenzocycloheptene compounds useful in the synthesis of non-steroidal analogues of vitamin D 失效可用于合成维生素D的非甾体类似物的7,7-二取代（5H，9H）-6,8-二氧杂环苯并环庚烯化合物公开(公告)号：US07319155B2
公开(公告)日：2008-01-15
申请号：US11598784
申请日：2006-11-14
Applicant: Eric Terranova , Jean-Claude Pascal
Inventor： Eric Terranova , Jean-Claude Pascal
IPC: C07D321/00 , C07D323/00 , C07D317/72 , C07C33/18 , C07C33/34
CPC classification number: C07C29/17 , C07D321/10 , C07F9/65527 , C07C33/26 , C07C33/46
Abstract: Novel 7,7-disubstituted (5H,9H)-6,8-dioxabenzocycloheptene compounds having the structural formula (I): are useful intermediates in the synthesis of non-steroidal derivatives of vitamin D.
Abstract translation: 具有结构式（I）的新型7,7-二取代（5H，9H）-6,8-二氧杂环苯并环庚烯化合物：在维生素D的非甾体衍生物的合成中是有用的中间体。
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![Preparation of 3-[5'-(3,4-bis(hydroxymethyl)benzyloxy)-2'-ethyl-2-propylbiphenyl-4-yl]pentan-3-ol](/abs-image/US/2007/12/06/US20070282136A1/abs.jpg.150x150.jpg)
9.发明申请Preparation of 3-[5'-(3,4-bis(hydroxymethyl)benzyloxy)-2'-ethyl-2-propylbiphenyl-4-yl]pentan-3-ol 失效制备3- [5' - （3,4-双（羟甲基）苄氧基）-2'-乙基-2-丙基联苯-4-基]戊-3-醇公开(公告)号：US20070282136A1
公开(公告)日：2007-12-06
申请号：US11802029
申请日：2007-05-18
Applicant: Eric Terranova , Sebastien Daver , Christine Marty , Jean-Claude Pascal
Inventor： Eric Terranova , Sebastien Daver , Christine Marty , Jean-Claude Pascal
CPC classification number: C07C41/26 , C07C37/20 , C07C39/12 , C07C45/673 , C07C45/71 , C07C49/83 , C07C49/84 , C07C43/23
Abstract: 3-[5′-(3,4-bis(hydroxymethyl)benzyloxy)-2′-ethyl-2-propylbiphenyl-4-yl]pentan-3-ol is prepared from the novel intermediate, 6-ethyl-4′-(1-ethyl-1-hydroxypropyl)-2′-propylbiphenyl-3-ol
Abstract translation: 由新型中间体6-乙基-4'-氧代-3,4-二氢吡啶制备3- [5' - （3,4-双（羟甲基）苄氧基）-2'-乙基-2-丙基联苯-4-基]戊-3-醇， （1-乙基-1-羟丙基）-2'-丙基联苯-3-醇
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10.发明申请Novel 7,7-disubstituted (5H,9H)-6,8-dioxabenzocycloheptene compounds useful in the synthesis of non-steroidal analogues of vitamin D 失效用于合成维生素D的非甾体类似物的新型7,7-二取代（5H，9H）-6,8-二氧杂环苯并环庚烯化合物公开(公告)号：US20070117989A1
公开(公告)日：2007-05-24
申请号：US11598784
申请日：2006-11-14
Applicant: Eric Terranova , Jean-Claude Pascal
Inventor： Eric Terranova , Jean-Claude Pascal
IPC: C07F9/28 , C07D323/00
CPC classification number: C07C29/17 , C07D321/10 , C07F9/65527 , C07C33/26 , C07C33/46
Abstract: Novel 7,7-disubstituted (5H,9H)-6,8-dioxabenzocycloheptene compounds having the structural formula (I): are useful intermediates in the synthesis of non-steroidal derivatives of vitamin D.
Abstract translation: 具有结构式（I）的新型7,7-二取代（5H，9H）-6,8-二氧杂环苯并环庚烯化合物：在维生素D的非甾体衍生物的合成中是有用的中间体。
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