CONTROLLED CURE FOR COMPOSITIONS COMPRISING ACETOACETYLATED RESINS

    公开(公告)号:US20200181324A1

    公开(公告)日:2020-06-11

    申请号:US16705345

    申请日:2019-12-06

    摘要: This invention relates to a curable composition comprising: I. Component (I) comprising a resin having at least one functional group selected from the group consisting of β-ketoester and malonate functional groups; II. Component (II) comprising at least one curing agent having at least one aldehyde functional group, wherein said Component (II) is optionally latent; III. Component (III) comprising at least one amine, salts thereof, or combinations thereof; wherein before addition of Component (III), the reactivity of the composition is delayed by at least one of the following: (III)(a) at least one of said Components (I), (II), and (III), or any reaction product thereof, or any combination thereof is a solid; or at least one of Components (II) or (III) or any combination thereof is insoluble in the resin under pot life conditions; or (III)(b) at least one said amine is first reacted with at least one aldehyde, ketone, acetal or ketal, or mixtures thereof, optionally, to form a solid; (III)(c) at least one said amine is first reacted with a portion of Component (II), wherein the reaction product thereof is optionally reacted or combined subsequently with additional amounts of either or both of Components (II) and (III), and, prior to reaction of Components (I)-(III), and is optionally combined with at least one amine reactivity delayer; or (III)(d) at least one said amine is first reacted with all of Component (II) wherein the reaction product is a combination of Components (II) and (III) and no additional amounts of Component (II) or Component (III) are reacted with said composition; or combinations of reaction products as described in (III)(d); and optionally, IV. Component (IV) comprising at least one reactivity delayer which is combined with Component (II), or Component (III), or a combination thereof.