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公开(公告)号:US11260375B2
公开(公告)日:2022-03-01
申请号:US16338015
申请日:2017-09-27
发明人: Monika Berweiler , Markus Göttlinger , Meike Roos , Matthias Schwarz , René Poss
IPC分类号: B01J23/755 , B01J25/02 , B01J35/02 , B01J35/04 , B01J35/10 , C07C29/17 , B01J37/00 , B01J37/08 , B01J37/02 , B01J23/26 , B01J23/28 , B01J23/745 , C07C31/20
摘要: The present invention relates to a process for preparing 1,4-butanediol (BDO) by hydrogenating 2-butyne-1,4-diol (BYD) or 4-hydroxybutanal (4-HBA) in the presence of a catalyst of the Raney type having a porous foam structure, wherein the macroscopic pores have sizes in the range of 100 to 5000 μm, and a bulk density of up to 0.8 kg/L.
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公开(公告)号:US11819832B2
公开(公告)日:2023-11-21
申请号:US17059448
申请日:2020-09-25
发明人: Meike Roos , René Poss , Monika Berweiler , Markus Göttlinger
IPC分类号: B01J25/02 , B01J35/10 , B01J37/00 , B01J35/04 , B01J37/02 , B01J37/08 , B01J8/06 , B01J19/30
CPC分类号: B01J25/02 , B01J8/06 , B01J19/305 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J35/1076 , B01J37/0018 , B01J37/0225 , B01J37/08 , B01J2208/023 , B01J2219/30475 , B01J2219/32286
摘要: A catalytic reactor for industrial-scale hydrogenation processes is described. The catalytic reactor contains a catalytic fixed bed that comprises a support structure and a catalyst. During operation of the reaction in the catalytic reactor, the fixed bed is filled with reaction medium to at least 85% by volume. A very high contact area of the catalyst with the reaction medium is at the same time provided. The support structure is formed from material webs having a thickness of 5 to 25 μm, with a crosslinking density of at least 3 mm−3 present. The support structure consists of metals selected from elements of groups 8, 6 and 11 of the periodic table of the elements and mixtures thereof.
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公开(公告)号:US20210275996A1
公开(公告)日:2021-09-09
申请号:US17059448
申请日:2020-09-25
发明人: Meike Roos , René POSS , Monika BERWEILER , Markus GÖTTLINGER
IPC分类号: B01J25/02 , B01J35/10 , B01J37/00 , B01J35/04 , B01J37/02 , B01J37/08 , B01J8/06 , B01J19/30
摘要: A catalytic reactor for industrial-scale hydrogenation processes is described. The catalytic reactor contains a catalytic fixed bed that comprises a support structure and a catalyst. During operation of the reaction in the catalytic reactor, the fixed bed is filled with reaction medium to at least 85% by volume. A very high contact area of the catalyst with the reaction medium is at the same time provided. The support structure is formed from material webs having a thickness of 5 to 25 μm, with a crosslinking density of at least 3 mm−3 present. The support structure consists of metals selected from elements of groups 8, 6 and 11 of the periodic table of the elements and mixtures thereof.
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公开(公告)号:US11993558B2
公开(公告)日:2024-05-28
申请号:US18113755
申请日:2023-02-24
发明人: Robert Franke , Meike Roos , Horst-Werner Zanthoff , Julia Bauer , Christoph Weber , Andrea Heinroth , Jan Benedikt Metternich
IPC分类号: C07C29/141 , B01J23/883 , B01J23/885 , B01J35/56 , B01J35/61 , B01J35/64
CPC分类号: C07C29/141 , B01J23/883 , B01J23/885 , B01J35/56 , B01J35/613 , B01J35/615 , B01J35/657
摘要: The present invention relates to a process for producing alcohols by hydrogenation of C9 aldehydes. The process according to the invention is performed in two consecutive hydrogenation stages, wherein the first hydrogenation stage employs an activated metal catalyst based on a nickel metal foam and the second stage employs a supported catalyst containing a catalytically active component from the group consisting of nickel, copper, chromium and mixtures thereof.
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公开(公告)号:US11090637B2
公开(公告)日:2021-08-17
申请号:US16338044
申请日:2017-09-27
发明人: Stefan Wieland , Meike Roos , René Poss
IPC分类号: B01J25/02 , B01J35/04 , B01J35/00 , B01J35/02 , B01J35/10 , B01J23/16 , B01J8/02 , B01J23/70 , B01J19/30 , C07C29/17 , B01J19/24 , B01J23/755 , B01J21/02 , C07C29/153
摘要: The present invention relates to a fixed bed of catalytically active metal foam bodies having a volume of not more than 500 mL which consist to an extent of at least 95 wt % of metals. The fixed bed is used for catalytic reactions in a three-phase reaction mixture.
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公开(公告)号:US12110265B2
公开(公告)日:2024-10-08
申请号:US18113749
申请日:2023-02-24
发明人: Robert Franke , Meike Roos , Horst-Werner Zanthoff , Julia Bauer , Christoph Weber , Andrea Heinroth , Jan Benedikt Metternich
IPC分类号: C07C29/141 , B01J21/04 , B01J23/72 , B01J23/755 , B01J35/56
CPC分类号: C07C29/141 , B01J21/04 , B01J23/72 , B01J23/755 , B01J35/56 , B01J2231/321
摘要: The present invention relates to a process for producing alcohols by hydrogenation of C4 to C20 aldehydes. The process according to the invention is performed in two consecutive hydrogenation stages, wherein the first hydrogenation stage employs an activated metal catalyst based on a nickel metal foam and the second stage employs a supported catalyst containing a catalytically active component from the group consisting of nickel, copper, chromium and mixtures thereof.
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公开(公告)号:US12076790B2
公开(公告)日:2024-09-03
申请号:US17053340
申请日:2020-09-25
发明人: René Poss , Monika Berweiler , Meike Roos
CPC分类号: B22F3/1137 , B22F1/05 , B22F3/1146 , B22F2003/242 , B22F2003/248 , B22F2301/052 , B22F2303/30
摘要: The present invention relates to processes for producing metal foam bodies, in which metal-containing powders that may comprise aluminium and chromium or molybdenum are applied to metal foam bodies that may comprise nickel, cobalt, copper and iron and then treated thermally, wherein the highest temperature in the thermal treatment of the metal foam bodies is in the range from 680 to 715° C., and wherein the total duration of the thermal treatment within the temperature range from 680 to 715° C. is between 5 and 240 seconds. Following this method of thermal treatment can achieve alloy formation at the contact surface between metal foam body and metal-containing powder, but simultaneously leave unalloyed regions within the metal foam. The present invention further comprises processes comprising the treatment of the alloyed metal foam bodies with basic solution. The present invention further comprises the metal foam bodies obtainable by these processes, which find use, for example, as support and structure components and in catalyst technology.
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公开(公告)号:US12006279B2
公开(公告)日:2024-06-11
申请号:US18113319
申请日:2023-02-23
发明人: Robert Franke , Meike Roos , Horst-Werner Zanthoff , Julia Bauer , Christoph Weber , Andrea Heinroth , Jan Benedikt Metternich
IPC分类号: C07C29/141 , B01J21/02 , B01J23/652
CPC分类号: C07C29/141 , B01J21/02 , B01J23/6525
摘要: The present invention relates to a process for producing alcohols by hydrogenation of C13 aldehydes. The process according to the invention is performed in two consecutive hydrogenation stages, wherein the first hydrogenation stage employs an activated metal catalyst based on a nickel metal foam and the second stage employs a supported catalyst containing a catalytically active component from the group consisting of nickel, copper, chromium and mixtures thereof.
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