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公开(公告)号：US11242422B2
公开(公告)日：2022-02-08
申请号：US16689657
申请日：2019-11-20
发明人： Philip P. Fontaine , Jerzy Klosin , Endre Szuromi , Carl N. Iverson , Zach T. Rickaway , Andrew J. Young , Susan G. Brown , Ruth Figueroa , Mehmet Demirors , Mridula Kapur
摘要： The invention provides a process to form an olefin-based polymer, said process comprising polymerizing at least one olefin in the presence of at least one catalyst system comprising the reaction product of the following: A) at least one cocatalyst; and B) a procatalyst comprising a metal-ligand complex of Formula (I), as described herein:
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2.发明申请公开(公告)号：US20200277412A1
公开(公告)日：2020-09-03
申请号：US16646209
申请日：2018-09-19
发明人： Arkady L. Krasovskiy , David R. Wilson , Tulaza Vaidya , Edmund M. Carnahan , Philip P. Fontaine , Carl N. Iverson
IPC分类号： C08F4/64 , C08F10/02 , C08F210/16
摘要： Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: where X is selected from the group consisting of —ORX or NRX2.
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公开(公告)号：US20130102789A1
公开(公告)日：2013-04-25
申请号：US13685232
申请日：2012-11-26
IPC分类号： C07D233/64
CPC分类号： C07D307/82 , C07D233/64 , C07D405/04 , C07F7/00 , C08F10/00 , C08F110/06 , C08F4/64044 , C08F2500/15 , C08F2500/03
摘要： Hafnium complexes of heterocyclic organic ligands having improved solubility in aliphatic hydrocarbon solvents and their use as components of olefin polymerization catalysts as well as novel syntheses of component parts thereof are disclosed.
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公开(公告)号：US20240199775A1
公开(公告)日：2024-06-20
申请号：US18553266
申请日：2022-03-28
IPC分类号： C08F210/06
CPC分类号： C08F210/06
摘要： Methods of propylene polymerization incorporate bis biphenyl-phenoxy procatalysts favoring polypropylene isotacticity at elevated reactor temperatures. The methods include polymerizing propylene in the presence of a catalyst system to produce a propylene-based polymer. The catalyst system includes a metal-ligand complex selected from bis-biphenyl-phenoxy procatalysts. Polymerization reactions result in polypropylenes having greater than 90% isotacticity, as measured by percentages of isotactic triads, at reaction temperatures from 110° C. to 190 ° C. or from 160 ° C. to 190 ° C.
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公开(公告)号：US20240084050A1
公开(公告)日：2024-03-14
申请号：US18472617
申请日：2023-10-10
发明人： Ruth Figueroa , Robert D. Grigg , Jerzy Klosin , Tulaza Vaidya , Carl N. Iverson
IPC分类号： C08F4/659 , C08F4/64 , C08F210/16
CPC分类号： C08F4/65908 , C08F4/64193 , C08F210/16
摘要： Embodiments of this disclosure are directed to catalyst systems comprising a metal-ligand complex according to formula (I):
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公开(公告)号：US20210309768A1
公开(公告)日：2021-10-07
申请号：US17267587
申请日：2019-08-30
发明人： Ruth Figueroa , Robert D. Grigg , Jerzy Klosin , Tulaza Vaidya , Carl N. Iverson
IPC分类号： C08F4/659 , C08F210/16 , C08F4/64
摘要： Embodiments of this disclosure are directed to catalyst systems comprising a metal-ligand complex according to formula (I).
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公开(公告)号：US20170101494A1
公开(公告)日：2017-04-13
申请号：US15311299
申请日：2015-06-29
发明人： Philip P. Fontaine , Jerzy Klosin , Endre Szuromi , Carl N. Iverson , Zach T. Rickaway , Andrew J. Young , Susan G. Brown , Ruth Figueroa , Mehmet Demirors , Mridula Babli Kapur
IPC分类号： C08F210/16
摘要： The invention provides a process to form an olefin-based polymer, said process comprising polymerizing at least one olefin in the presence of at least one catalyst system comprising the reaction product of the following: A) at least one cocatalyst; and B) a procatalyst comprising a metal-ligand complex of Formula (I), as described herein: (Formula I).
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公开(公告)号：US11242415B2
公开(公告)日：2022-02-08
申请号：US16646209
申请日：2018-09-19
发明人： Arkady L. Krasovskiy , David R. Wilson , Tulaza Vaidya , Edmund M. Carnahan , Philip P. Fontaine , Carl N. Iverson
IPC分类号： C07F7/00 , C08F4/76 , C08F4/64 , C08F10/02 , C08F210/16
摘要： Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: where X is selected from the group consisting of —ORX or NRX2.
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公开(公告)号：US10519260B2
公开(公告)日：2019-12-31
申请号：US15311299
申请日：2015-06-29
发明人： Philip P. Fontaine , Jerzy Klosin , Endre Szuromi , Carl N. Iverson , Zach T. Rickaway , Andrew J. Young , Susan G. Brown , Ruth Figueroa , Mehmet Demirors , Mridula Kapur
IPC分类号： C08F4/76 , C08F4/64 , C08F210/16 , C08F4/659
摘要： The invention provides a process to form an olefin-based polymer, said process comprising polymerizing at least one olefin in the presence of at least one catalyst system comprising the reaction product of the following: A) at least one cocatalyst; and B) a procatalyst comprising a metal-ligand complex of Formula (I), as described herein: (Formula I).
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公开(公告)号：US20190276573A1
公开(公告)日：2019-09-12
申请号：US16318568
申请日：2017-07-25
发明人： Edmund M. Carnahan , Philip P. Fontaine , Carl N. Iverson , Jeffrey C. Munro , David M. Pearson , Kim Walton
IPC分类号： C08F210/16 , C08L23/16 , C08L23/12 , C08F4/6592 , C08F4/659 , C08F4/64
摘要： Embodiments of the present disclosure are directed to multimodal elastomers produced by olefin polymerization with a mixed catalyst system, specifically, a constrained geometry catalyst and a biphenyl phenol catalyst. The multimodal elastomers may be incorporated as impact modifiers in thermoplastic olefins.
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