知搜-全球专利检索

  1. Login
  2. Sign Up

Search Results

31 records (took 0.023 seconds)

    Viscous conjugated diene block copolymers
    3.
    发明授权
    Viscous conjugated diene block copolymers 失效
    粘性共轭二烯嵌段共聚物

    公开(公告)号：US5686535A

    公开(公告)日：1997-11-11

    申请号：US770915

    申请日：1996-12-20

    Applicant: James Robert Erickson ,  David John St. Clair

    Inventor： James Robert Erickson ,  David John St. Clair

    IPC: C08F8/00 ,  C08G59/34 ,  C08L63/08 ,  C08F297/02

    CPC classification number: C08G59/027 ,  C08F8/04 ,  C08F8/08 ,  C08L63/08 ,  C08F2800/20 ,  C08F2810/20

    Abstract: A viscous block copolymer of the formula (A-B-A.sub.p).sub.n -Y.sub.r -(A.sub.q -B).sub.m wherein Y is a coupling agent or coupling monomers, and wherein A and B are polymer blocks which may be homopolymer blocks of conjugated diolefin monomers, copolymer blocks of conjugated diolefin monomers or copolymer blocks of conjugated diolefin monomers and monoalkenyl aromatic hydrocarbon monomers, and wherein the A blocks have a higher number of more highly substituted aliphatic double bonds per unit of block mass than do the B blocks, and wherein the A blocks have a molecular weight from about 100 to about 3000 and the B blocks have a molecular weight from about 1000 to about 15,000, and wherein p and q are 0 or 1 and n>0, r is 0 or 1, m.gtoreq.0 and n+m ranges from 1 to 100. This block copolymer is preferably partially hydrogenated, epoxidized and crosslinked through at least some of the epoxy functionality to form an adhesive, coating or sealant composition.

    Abstract translation: 式（AB-Ap）n-Yr-（Aq-B）m的粘性嵌段共聚物，其中Y是偶联剂或偶联单体，其中A和B是可以是共轭二烯烃单体的均聚物嵌段的聚合物嵌段， 共轭二烯单体的共聚物嵌段或共轭二烯烃单体和单链烯基芳族烃单体的共聚物嵌段，并且其中所述A嵌段与B嵌段相比，每单位嵌段质量具有更高数目的更高取代的脂族双键，并且其中A 嵌段的分子量为约100至约3000，并且B嵌段的分子量为约1000至约15,000，并且其中p和q为0或1且n> 0，r为0或1，m> 0和n + m的范围为1至100.该嵌段共聚物优选部分氢化，环氧化并通过至少一些环氧官能团交联以形成粘合剂，涂料或密封剂组合物。

    Telechelic polymers and heterotelechelic polydiene block polymers with dual curing systems
    4.
    发明授权
    Telechelic polymers and heterotelechelic polydiene block polymers with dual curing systems 失效
    具有双重固化体系的远端聚合物和异丙烯基聚二烯嵌段聚合物

    公开(公告)号：US5948863A

    公开(公告)日：1999-09-07

    申请号：US932970

    申请日：1997-09-18

    Applicant: David John St. Clair ,  James Robert Erickson

    Inventor： David John St. Clair ,  James Robert Erickson

    IPC: C09K3/10 ,  C08G18/62 ,  C08G18/69 ,  C08G59/18 ,  C08G59/34 ,  C08J3/24 ,  C08L53/00 ,  C09J4/06 ,  C09J119/00 ,  C09J153/00 ,  C09J161/34 ,  C09J163/00 ,  C09J163/08 ,  C09J175/04 ,  C09J201/02 ,  C08L53/02 ,  C08L33/08 ,  C08L67/02

    CPC classification number: C08G59/027 ,  C08G18/6208 ,  C08G18/69 ,  C08G18/698 ,  C08G59/18 ,  C08J3/243 ,  C09J119/006 ,  C09J163/00 ,  C09J163/08 ,  C09J175/04 ,  C09J4/06 ,  C08G2170/40 ,  C08G2190/00

    Abstract: A pressure structural or sealant composition comprises (a) from 15 to 95% by weight of a telechelic polymer such as a glycidyl ether-functional telechelic polymer and from 5 to 85% by weight of a heterotelechelic polydiene block polymer wherein at least one of the functonalities is the same as the functionality of the telechelic polymer, such as a heterotelechelic polydiene block polymer with glycidyl ether and another functionality such as olefinic unsaturation or epoxidized olefin; and (b) a dual curing system wherein one curing agent cures the teolechelic polymer and the common functionality on the heterotelechelic polydiene block polymer such as an aliphatic polyamine, and the other curing agent cures the other functionality on the heterotelechelic polydiene block polymer but does not cure under conditions required to cure the telechelic polymer, such as a sulfur-based curing agent when the functionality is olefinic unsaturation or an amino resin when the functionality is epoxidized olefin.

    Abstract translation: 压力结构或密封剂组合物包含（a）15至95重量％的遥爪聚合物，例如缩水甘油醚官能遥爪聚合物和5至85重量％的异炔基聚二烯嵌段聚合物，其中至少一个 功能与遥爪聚合物的功能相同，例如具有缩水甘油醚和另一官能团如烯属不饱和键或环氧化烯烃的杂多炔类聚二烯嵌段聚合物; 和（b）双重固化体系，其中一种固化剂固化脱氧缩醛聚合物和杂多烯聚二烯嵌段聚合物如脂肪族多胺的共同官能团，而另一种固化剂固化在异金属聚二烯嵌段聚合物上的其它官能团，但不 在官能度为烯属不饱和度时固化遥爪聚合物（例如硫基固化剂）或官能度为环氧化烯烃时的氨基树脂所需的条件下固化。

    Pressure sensitive structural adhesives and sealants based on telechelic/heterotelechelic polymers with dual cure systems
    5.
    发明授权
    Pressure sensitive structural adhesives and sealants based on telechelic/heterotelechelic polymers with dual cure systems 失效
    基于具有双重固化系统的遥爪/异金属螯合聚合物的压敏结构粘合剂和密封剂

    公开(公告)号：US5721318A

    公开(公告)日：1998-02-24

    申请号：US631759

    申请日：1996-04-12

    Applicant: David John St. Clair ,  James Robert Erickson

    Inventor： David John St. Clair ,  James Robert Erickson

    IPC: C09K3/10 ,  C08G18/62 ,  C08G18/69 ,  C08G59/18 ,  C08G59/34 ,  C08J3/24 ,  C08L53/00 ,  C09J4/06 ,  C09J119/00 ,  C09J153/00 ,  C09J161/34 ,  C09J163/00 ,  C09J163/08 ,  C09J175/04 ,  C09J201/02 ,  C08L53/02 ,  C08L33/08 ,  C08L67/02

    CPC classification number: C08G59/027 ,  C08G18/6208 ,  C08G18/69 ,  C08G18/698 ,  C08G59/18 ,  C08J3/243 ,  C09J119/006 ,  C09J163/00 ,  C09J163/08 ,  C09J175/04 ,  C09J4/06 ,  C08G2170/40 ,  C08G2190/00

    Abstract: Pressure sensitive structural adhesive and sealant compositions comprising: (a) a polymer system comprising from 95 to 15 percent by weight of a telechelic polymer and from 5 to 85 percent by weight of a heterotelechelic polymer wherein at least one of the functionalities thereon is the same as the functionality on the telechelic polymer, and (b) a dual curing system wherein one element of the curing system cures the telechelic polymer and the common functionality on the heterotelechelic polymer and the other element cures the functionality on the heterotelechelic polymer but does not cure under the conditions required to cure the telechelic polymer to form a structural adhesive or sealant composition. In a preferred embodiment, the polymer system is comprised of a hydroxyl functional telechelic diol or polyol polymer and the heterotelechelic polymer is a monohydroxylated polydiene polymer which also has epoxidized olefin functionality. The dual curing system preferably is comprised of an isocyanate curing agent to cure through the hydroxyl groups at ambient temperatures to form a pressure sensitive adhesive or sealant and an amino resin to cure through the epoxy functionality upon baking to form a structural adhesive or sealant.

    Abstract translation: 压敏结构粘合剂和密封剂组合物，其包含：（a）包含95至15重量％的遥爪聚合物和5至85重量％的异丙炔基聚合物的聚合物体系，其中至少一个其上的官能团相同 作为遥爪聚合物上的功能，和（b）双重固化系统，其中固化体系的一个元素固化遥爪聚合物，并且杂多聚乙烯聚合物上的共同官能团固化，而另一个元素固化在异极性聚合物上的功能，但不固化 在固化遥爪聚合物以形成结构粘合剂或密封剂组合物所需的条件下。 在一个优选的实施方案中，聚合物体系由羟基官能的遥爪二醇或多元醇聚合物组成，并且所述聚异戊烯聚合物是也具有环氧化烯烃官能团的单羟基化聚二烯烃聚合物。 双重固化体系优选由异氰酸酯固化剂组成，以在环境温度下固化通过羟基，以形成压敏粘合剂或密封剂和氨基树脂，以在烘烤时通过环氧官能团固化以形成结构粘合剂或密封剂。

    Crosslinkable waterborne dispersions of epoxidized polydiene block copolymers and amino resins
    6.
    发明授权
    Crosslinkable waterborne dispersions of epoxidized polydiene block copolymers and amino resins 失效
    环氧化聚二烯嵌段共聚物和氨基树脂的交联水性分散体

    公开(公告)号：US06255364B1

    公开(公告)日：2001-07-03

    申请号：US08389521

    申请日：1995-02-16

    Applicant: David John St. Clair ,  James Robert Erickson

    Inventor： David John St. Clair ,  James Robert Erickson

    IPC: C08K0320

    CPC classification number: C08G59/027 ,  C08L63/08 ,  C08L61/20

    Abstract: A crosslinkable waterborne dispersion of an epoxidized polydiene block polymer composition which comprises: (a) 10 to 65% w of a polydiene block polymer containing at least five olefinic epoxy groups per molecule which are sterically hindered, (b) 0.2 to 25% w of a compatible aminoplast, (c) 0.1 to 10% w of a surfactant which is nonionic or anionic and has a volatile cation, and (d) the balance water. The invention also describes a water-continuous process and an inversion processes for making such dispersions.

    Abstract translation: 环氧化聚二烯嵌段聚合物组合物的可交联的水性分散体，其包含：（a）每分子含有至少五个烯属环氧基的空间位阻含10至65重量％的聚二烯嵌段聚合物，（b）0.2至25重量％ 相容的氨基塑料，（c）0.1至10％w的非离子或阴离子表面活性剂并具有挥发性阳离子，和（d）余量的水。 本发明还描述了制造这种分散体的水连续方法和反转方法。

    Monohydroxylated diene polymers and epoxidized derivatives thereof
    9.
    发明授权
    Monohydroxylated diene polymers and epoxidized derivatives thereof 失效

    公开(公告)号：US06525142B1

    公开(公告)日：2003-02-25

    申请号：US08399864

    申请日：1995-03-07

    Applicant: James Robert Erickson ,  David John St. Clair ,  Michael Alan Masse

    Inventor： James Robert Erickson ,  David John St. Clair ,  Michael Alan Masse

    IPC: C08F21016

    CPC classification number: C08L53/02 ,  C08L2666/02 ,  C09J153/02

    Abstract: The invention herein relates to unsaturated monohydroxylated polydiene polymers which are comprised of at least two polymerizable ethenically unsaturated hydrocarbon monomers wherein at least one is a diene monomer which yields unsaturation suitable for epoxidation. The invention also encompasses partially hydrogenated and/or epoxidized derivatives of these novel monohydroxylated polydiene polymers. The preferred monohydroxylated polydiene polymer of the present invention has a structural formula (HO)x—A—Sz—B—(OH)y wherein A and B are polymer blocks which may be homopolymer blocks of conjugated diolefin monomers, copolymer blocks of conjugated diolefin monomers, or copolymer blocks of diolefin monomers and monoalkenyl aromatic hydrocarbon monomers. These polymers may contain up to 60% by weight of at least one vinyl aromatic hydrocarbon, preferably styrene. Generally, it is preferred that the A blocks should have a greater concentration of more highly substituted aliphatic double bonds than the B blocks have. Thus, the A blocks have a greater concentration of di-, tri-, or tetra-substituted unsaturation sites (aliphatic double bonds) per unit of block mass than do the B blocks. This produces a polymer wherein the most facile epoxidation occurs in the A blocks. The A blocks have a molecular weight of from 100 to 6000, preferably 500 to 4,000, and most preferably 1000 to 3000, and the B blocks have a molecular weight of from 1000 to 15,000, preferably 2000 to 10,000, and most preferably 3000 to 6000. S is a vinyl aromatic hydrocarbon block which may have a molecular weight of from 100 to 10,000. x and y are 0 or 1. Either x or y must be 1, but only one at a time can be 1. z is 0 or 1. Either the A or the B block may be capped with a miniblock of polymer, 50 to 1000 molecular weight, of a different composition, to compensate for any initiation, tapering due to unfavorable copolymerization rates, or capping difficulties. These polymers may be epoxidized such that they contain from 0.1 to 7.0 milliequivalents (meq) of epoxy per gram of polymer.

    Waterborne dispersions of epoxidized polydiene block copolymers and amino resins
    10.
    发明授权
    Waterborne dispersions of epoxidized polydiene block copolymers and amino resins 失效
    环氧化聚二烯嵌段共聚物和氨基树脂的水分散体

    公开(公告)号：US06248810B1

    公开(公告)日：2001-06-19

    申请号：US08389520

    申请日：1995-02-16

    Applicant: David John St. Clair ,  James Robert Erickson

    Inventor： David John St. Clair ,  James Robert Erickson

    IPC: C08L5302

    CPC classification number: C08G59/027 ,  C08L63/08 ,  C08L61/20

    Abstract: A crosslinkble waterborne dispersion useful as a coating on metal substrates of an epoxidized polydiene block polymer composition which comprises: (a) 10 to 65% by weight of a polydiene block polymer containing at least five olefinic epoxy groups per molecule which are sterically hindered, (b) 0.2 to 25% by weight of a compatible aminoplast, (c) 0.1 to 10% by weight of a surfactant which is nonionic or anionic and has a volatile cation, and (d) the balance water. A water-continuous process and an inversion process for making a dispersion are also described.

    Abstract translation: 一种用作环氧化聚二烯嵌段聚合物组合物的金属基材上的涂层的交联水性分散体，其包含：（a）10至65重量％的含空间位阻的每分子至少有5个烯属环氧基团的聚二烯嵌段聚合物，（ b）0.2至25重量％的相容氨基塑料，（c）0.1至10重量％的非离子或阴离子表面活性剂并具有挥发性阳离子，和（d）余量的水。 还描述了用于制造分散体的水连续方法和反转方法。

Patent Agency Ranking