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公开(公告)号：US20200216590A1
公开(公告)日：2020-07-09
申请号：US16648142
申请日：2018-09-25
发明人： Kenneth Laughlin , Alfred K. Schultz , John Reffner , Oscar David Redwine , Robert L. Sammler , Andrew M. Savo
IPC分类号： C08F212/08 , B01J39/20 , C08L25/06
摘要： A polymeric bead having radius R wherein the polymer comprises 0.3% to 20% by weight, based on the weight of the polymer, of polymerized units of one or more multifunctional vinyl monomer and 80% to 99.7% by weight, based on the weight of the polymer, of polymerized units of one or more monofunctional vinyl monomer, (a) wherein the polymerized units of multifunctional vinyl monomer have radial distribution factor MR of 0.9 to 1.1, and (b) wherein some of the vinyl groups in the polymerized units of multivinyl monomer are unreacted, and the unreacted vinyl groups have a radial distribution factor VR of 2.5 or higher.
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公开(公告)号：US20190070600A1
公开(公告)日：2019-03-07
申请号：US15757045
申请日：2016-09-14
发明人： J. Marcus Slagt , Alfred K. Schultz
摘要： Provided is a method of regenerating an acrylic resin (B2), comprising (A) providing a collection of particles of acrylic resin (B2) that has calculated Hansch parameter of −1.0 to 2.5, wherein one or more humic acid, one or more fulvic acid, or a mixture thereof, is adsorbed onto said acrylic resin (B2), and (B) bringing said collection of particles of acrylic resin (B2) into contact with an aqueous solution (RA) having pH of 4 or lower, to form a mixture B2RA, (C) then separating acrylic resin (B3) from said mixture B2RA.
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公开(公告)号：US20190314806A1
公开(公告)日：2019-10-17
申请号：US15757050
申请日：2016-09-14
发明人： J. Marcus Slagt , Alfred K. Schultz
摘要： Provided is a method of regenerating an acrylic resin (B2), comprising (A) providing a collection of particles of acrylic resin (B2) that has calculated Hansch parameter of −1.0 to 2.5, wherein one or more humic acid, one or more fulvic acid, or a mixture thereof, is adsorbed onto said acrylic resin (B2), and (B) bringing said collection of particles of acrylic resin (B2) into contact with an aqueous solution (RB) having pH of 10 or higher, to form a mixture B2RB, (C) then separating acrylic resin (B4) from said mixture B2RB.
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公开(公告)号：US20190291096A1
公开(公告)日：2019-09-26
申请号：US16302335
申请日：2017-06-19
发明人： William Carlin , Patricia Crawford , Martin Deetz , John C. Rohanna , Alfred K. Schultz , Lauren Versagli
IPC分类号： B01J49/09 , B01J41/05 , B01J41/14 , B01J39/05 , B01J39/20 , B01J47/04 , B01J49/53 , B01J49/57 , C02F1/28
摘要： Provided is a method of treating a vinyl aromatic resin (I) comprising (a) bringing the vinyl aromatic resin (I) into contact with an alcohol, and maintaining the contact between the vinyl aromatic resin (I) and the alcohol for 10 minutes or more, and (b) bringing the vinyl aromatic resin into contact with a base. wherein the vinyl aromatic resin (I), prior to steps (a) and (b), has benzyl chloride groups, benzyl alcohol groups, and methylene bridge groups.
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公开(公告)号：US20180244544A1
公开(公告)日：2018-08-30
申请号：US15757052
申请日：2016-09-14
发明人： J. Marcus Slagt , Alfred K. Schultz
IPC分类号： C02F1/42 , B01J41/05 , B01J41/14 , B01J39/05 , B01J39/20 , B01J47/028 , B01J49/08 , B01J49/57
CPC分类号： C02F1/42 , B01J39/05 , B01J39/20 , B01J41/05 , B01J41/14 , B01J47/028 , B01J49/08 , B01J49/57 , C02F2001/422 , C02F2101/30 , C02F2303/16
摘要： Provided is a method of purifying water comprising (a) providing an aqueous solution (A) that has pH of 5.5 or lower and that comprises (i) one or more dissolved organic compounds in an amount of 5 mg/L or more, measured as dissolved organic carbon, and (ii) 95% or more water by weight based on the weight of the aqueous solution (A), and (b) bringing the aqueous solution (A) into contact with a collection of particles of acrylic resin (B) that has calculated Hansch parameter of −1.0 to 2.5, and (c) then separating an aqueous solution (C) from the collection of particles of acrylic resin (B).
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6.发明申请METHOD FOR MAKING ANION EXCHANGE AND CHELANT RESINS INCLUDING ALIPHATIC AMINO FUNCTIONAL GROUPS 有权用于制备阴离子交换和粘合剂的方法，包括氨基甲酰基官能团公开(公告)号：US20160236187A1
公开(公告)日：2016-08-18
申请号：US14384101
申请日：2014-06-09
CPC分类号： B01J41/14 , B01J41/05 , B01J41/07 , B01J41/13 , B01J45/00 , C08F8/04 , C08F8/30 , C08F212/36 , C08F212/08
摘要： A method for making an anion exchange or chelant resin comprising a vinyl aromatic polymer including a repeating unit comprising an aromatic ring substituted with an aliphatic amino group, wherein the method comprises the step of reacting a vinyl aromatic polymer with a nitro compound comprising from 1 to 12 carbon atoms with the proviso that the a carbon includes at least one hydrogen.
摘要翻译： 一种阴离子交换剂或螯合树脂的制造方法，其包含乙烯基芳族聚合物，所述乙烯基芳族聚合物包括由脂肪族氨基取代的芳香环的重复单元，其中所述方法包括使乙烯基芳族聚合物与硝基化合物反应的步骤，所述硝基化合物包含1〜 12个碳原子，条件是一个碳包括至少一个氢。
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公开(公告)号：US20150259456A1
公开(公告)日：2015-09-17
申请号：US14426636
申请日：2013-10-07
发明人： Alfred K. Schultz , Gregoire Cardoen , William I. Harris , William J. Harris , Charles R. Marston , David J. Moll
IPC分类号： C08F224/00 , B01J41/14 , B01J39/20
CPC分类号： C08F224/00 , B01J39/20 , B01J41/14 , C08F2/18 , C08F8/30 , C08F8/34 , C08F12/22 , C08F212/08 , C08F212/14 , C08F212/36
摘要： A water-insoluble copolymer including an epoxide containing structural unit represented by Formula (I), wherein: the epoxide containing group is positioned meta, ortho or para on the ring relative to the bond linkage with the polymer backbone; L is an optional linking group; and R1, R2 and R3 are independently selected from: hydrogen, or a substituted or unsubstituted hydrocarbyl group.
摘要翻译： 一种包含由式（I）表示的含环氧化物的结构单元的水不溶性共聚物，其中：所述环氧化物基团相对于与聚合物主链的键键在环上位于环上，邻位或对位; L是可选的连接基团; 并且R 1，R 2和R 3独立地选自：氢或取代或未取代的烃基。
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公开(公告)号：US09920139B2
公开(公告)日：2018-03-20
申请号：US15536735
申请日：2015-12-15
发明人： Matthew D. Reichert , Alfred K. Schultz , Andrew M. Savo , Steven Rosenberg , Ralph C. Even , Lester H. Mcintosh, III , Robert Johnson , John David Finch , Decai Yu
IPC分类号： C08F2/20 , C08F12/08 , C08F212/08 , C08F212/36 , C08J3/07 , C08F2/18
CPC分类号： C08F2/20 , C08F2/18 , C08F12/08 , C08F212/08 , C08F212/36 , C08J3/07
摘要： Provided is a suspension comprising liquid droplets dispersed in an aqueous medium, wherein said droplets comprise (a) one or more water-insoluble compounds, and (b) a vinyl polyelectrolyte (PED) having a polarity, and wherein said aqueous medium comprises a polyelectrolyte (PEW) having a polarity that is opposite to the polarity of said polyelectrolyte (PED). Also provided are a method of making such a suspension and a method using such a suspension in a process of suspension polymerization.
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公开(公告)号：US20180002465A1
公开(公告)日：2018-01-04
申请号：US15537441
申请日：2015-12-15
发明人： Matthew D. Reichert , Alfred K. Schultz , Andrew M. Savo , Steven Rosenberg , Ralph C. Even , Lester H. Mcintosh, III , Robert Johnson , John David Finch , Decai Yu
IPC分类号： C08F212/08
CPC分类号： C08F212/08 , C08F2/18 , C08F2/20 , C08F12/08 , C08F212/36
摘要： Provided is a method of suspension polymerization comprising (i) providing a suspension of liquid droplets in an aqueous medium, wherein said droplets comprise (a) one or more water-insoluble vinyl monomers, and (b) a polyelectrolyte (PED) having a polarity, (c) one or more initiators, and wherein said aqueous medium comprises a polyelectrolyte (PEW) having a polarity that is opposite to the polarity of said polyelectrolyte (PED), (ii) polymerizing said vinyl monomer or allowing said vinyl monomer to polymerize.
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10.发明授权Method for making anion exchange and chelant resins including aliphatic amino functional groups 有权阴离子交换方法和螯合树脂，包括脂族氨基官能团公开(公告)号：US09486798B2
公开(公告)日：2016-11-08
申请号：US14384101
申请日：2014-06-09
CPC分类号： B01J41/14 , B01J41/05 , B01J41/07 , B01J41/13 , B01J45/00 , C08F8/04 , C08F8/30 , C08F212/36 , C08F212/08
摘要： A method for making an anion exchange or chelant resin comprising a vinyl aromatic polymer including a repeating unit comprising an aromatic ring substituted with an aliphatic amino group, wherein the method comprises the step of reacting a vinyl aromatic polymer with a nitro compound comprising from 1 to 12 carbon atoms with the proviso that the α carbon includes at least one hydrogen.
摘要翻译： 一种阴离子交换剂或螯合树脂的制造方法，其包含乙烯基芳族聚合物，所述乙烯基芳族聚合物包括由脂肪族氨基取代的芳香环的重复单元，其中所述方法包括使乙烯基芳族聚合物与硝基化合物反应的步骤，所述硝基化合物包含1〜 12个碳原子，条件是α碳包括至少一个氢。
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