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公开(公告)号:US3746732A
公开(公告)日:1973-07-17
申请号:US3746732D
申请日:1971-12-15
申请人: DOW CORNING
发明人: ATWELL W , BOKERMAN G
CPC分类号: B01J31/2404 , B01J31/1608 , B01J31/24 , B01J2231/4277 , B01J2231/641 , B01J2531/824 , C07F7/02 , C07F7/12
摘要: SILYL COMPLEXES OF PLATINUM AND PALLADIUM ARE PREPARED BY REACTING BELOW 150* C. DISILANES OR HYDROSILANES WITH PHOSPHINE COMPLEXES OF THE FORMULA M(PR''3)2Y2. SPECIFICALLY HEXACHLORODISILANE IS REACTED WITH
PD(PPHME2)2CL2
TO GIVE PD(PPHME2)2(SICL3)CL AND/OR
PD(PPHME2)2(SICL3)2.-
公开(公告)号:US3772347A
公开(公告)日:1973-11-13
申请号:US3772347D
申请日:1971-12-15
申请人: DOW CORNING
发明人: ATWELL W , BOKERMAN G
CPC分类号: C07F7/123 , B01J21/18 , B01J31/1608 , B01J31/1616 , B01J31/24 , B01J31/2404 , B01J2231/4277 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07F7/0827 , C07F7/122
摘要: OR M''(PR''3)2SI(RAC13-A)MX2-M. SPECIFICALLY, HEXACHLORODISILANE IS REACTED WITH ALLYL CHLORIDE IN THE PRESENCE OF PD(P(CH3)2C6H5)2C12 TO GIVE ALLYL TRICHLOROSILANE.
THE REACTION BETWEEN DISILANES AND HYDROCARBON CHLORIDES TO PRODUCE R''NSIC14-N IS CATALYZED WITH M'',
M(PR"3)2X2
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