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公开(公告)号：US20170275307A1
公开(公告)日：2017-09-28
申请号：US15506322
申请日：2015-08-14
申请人： Arkema Inc.
摘要： Methods of synthesizing fluorosilanes containing cyano-substituted alkyl groups are provided. For example, 3-cyano-propyldimethylfluorosilane may be produced by reacting tetramethyldisiloxane and boron trifluoride to obtain fluorodimethylsilane and then reacting the fluorodimethylsilane with allyl cyanide, in the presence of a hydrosilylation catalyst
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公开(公告)号：US08722915B2
公开(公告)日：2014-05-13
申请号：US13637446
申请日：2011-04-06
申请人： Aswini K. Dash , Charles Alan Hall , Dimitris Katsoulis , Robert Thomas Larsen , Matthew J. McLaughlin , Jonathan David Wineland
发明人： Aswini K. Dash , Charles Alan Hall , Dimitris Katsoulis , Robert Thomas Larsen , Matthew J. McLaughlin , Jonathan David Wineland
IPC分类号： C07F7/18
摘要： A process for preparing organohalosilanes comprising combining hydrogen, a halosilane having the formula HaSiX4-a (I) and an organohalide having the formula RX (II), wherein R is C1-C10 alkyl or C4-C10 cycloalkyl, each X is independently halo, and the subscript a is 0, 1, or 2, in the presence of a sufficient amount of a catalyst effective in enabling the replacement of one or more of the halo groups of the halosilane with the R group from the organohalide, at a temperature from 200 to 800° C., to form an organohalosilane and a hydrogen halide, wherein the volumetric ratio of hydrogen to halosilane is from 1:3 to 1:0.001 and the volumetric ratio of hydrogen to organohalide is from 1:1 to 1:0.001, and wherein the catalyst is optionally treated with the hydrogen or the halosilane prior to the combining.
摘要翻译： 一种制备有机卤代硅烷的方法，包括将氢，具有式IIaSiX4-a（Ⅰ）的卤代硅烷与式RX（Ⅱ）的有机卤化物混合，其中R是C 1 -C 10烷基或C 4 -C 10环烷基，每个X独立地是卤素， 并且下标a为0,1或2，在足够量的催化剂存在下，有效地能够在有机卤化物的温度下从卤代硅烷替代卤代硅烷中的一个或多个卤代基与R基团 形成有机卤代硅烷和卤化氢，其中氢与卤代硅烷的体积比为1:3至1:0.001，氢与有机卤化物的体积比为1:1至1:0.001 ，并且其中所述催化剂任选地在组合之前用氢或卤代硅烷处理。
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3.发明申请Grignard processes with improved yields of diphenylchlorosilanes as products 失效Grignard工艺具有提高的二苯基氯硅烷的产率作为产品公开(公告)号：US20070066826A1
公开(公告)日：2007-03-22
申请号：US10585154
申请日：2004-12-17
申请人： Binh Nguyen , Curtis Bedbury , Roger Humburg , Susan Jacob , Sarah Ratcliff , John Waterman
发明人： Binh Nguyen , Curtis Bedbury , Roger Humburg , Susan Jacob , Sarah Ratcliff , John Waterman
摘要： A Grignard process for preparing phenyl-containing chlorosilane products, in particular diphenylchlorosilanes, is carried out in three embodiments. In the first embodiment, the reactants of the Grignard process are a phenyl Grignard reagent, an ether solvent, a trichlorosilane, and an aromatic hydrocarbon coupling solvent. In the second embodiment, the reactants of the Grignard process are a phenyl Grignard reagent, an ether solvent, a phenylchlorosilane, and an aromatic hydrocarbon coupling solvent. In the third embodiment, the reactants of the Grignard process are a phenyl Grignard reagent, an ether solvent, a trichlorosilane, a phenylchlorosilane, and an aromatic hydrocarbon coupling solvent. In each embodiment, the reactants are present in a particular mole ratio.
摘要翻译： 用于制备含苯基氯硅烷产物，特别是二苯基氯硅烷的格氏法是在三个实施方案中进行的。 在第一实施方案中，格氏法的反应物是苯基格氏试剂，醚溶剂，三氯硅烷和芳族烃偶合溶剂。 在第二实施方案中，格氏法的反应物是苯基格氏试剂，醚溶剂，苯基氯硅烷和芳族烃偶联溶剂。 在第三实施方案中，格氏法的反应物是苯基格氏试剂，醚溶剂，三氯硅烷，苯基氯硅烷和芳烃耦合溶剂。 在每个实施方案中，反应物以特定的摩尔比存在。
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公开(公告)号：US20030191238A1
公开(公告)日：2003-10-09
申请号：US10117259
申请日：2002-04-04
IPC分类号： C08L083/00
CPC分类号： C07F7/122
摘要： A method for preparing phenyl-containing organosilicon intermediates using a aromatic halogenated solvent during the coupling reaction involving a phenyl Grignard reagent and a precursor silane. The process comprises contacting a phenyl halide with magnesium in a solvent such as ether, or an aromatic halogenated/ether solvent mixture to form a Grignard reagent, and contacting the Grignard reagent with a precursor chlorosilane in aromatic halogenated solvent to form the desired organosilicon intermediates, and then filtering and distilling to acquire the organosilicon intermediate reaction product.
摘要翻译： 在涉及苯基格氏试剂和前体硅烷的偶联反应期间使用芳族卤代溶剂制备含苯基的有机硅中间体的方法。 该方法包括将苯基卤化物与镁在溶剂如醚或芳族卤代/醚溶剂混合物中接触以形成格氏试剂，并使格利雅试剂与前体氯硅烷在芳族卤代溶剂中接触以形成所需的有机硅中间体， 然后过滤蒸馏得到有机硅中间体反应产物。
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公开(公告)号：US06429327B1
公开(公告)日：2002-08-06
申请号：US09487420
申请日：2000-01-20
IPC分类号： C07F708
CPC分类号： C07F7/122
摘要： Processes for the synthesis of substituted silanes from alkyl magnesium compounds using a mixture of catalysts. The catalyst systems include both a copper halide and a salt of a Group IA, IIA, IIA, or IVA element or a transition metal.
摘要翻译： 使用催化剂的混合物从烷基镁化合物合成取代的硅烷的方法。 催化剂体系包括卤化铜和IA，IIA，IIA或IVA族元素或过渡金属的盐。
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公开(公告)号：US20020082438A1
公开(公告)日：2002-06-27
申请号：US09918446
申请日：2001-08-01
发明人： Il-Nam Jung , Bok-Ryul Yoo , Joon-Soo Han , Seung-Hyun Kang
IPC分类号： C07F007/08
CPC分类号： C07F7/122
摘要： The present invention relates to a process for preparing organochlorosilanes and more particularly, to the process for preparing organochlorosilanes of formula I by a dehydrohalogenative coupling of hydrochlorosilanes of formula II with organic halides of formula III in the presence of quaternary phosphonium salt as a catalyst to provide better economical matter and yield compared with conventional methods, because only catalytic amount of phosphonium chloride is required and the catalyst can be separated from the reaction mixture and recycled easily, 1 wherein R1 represents hydrogen, chloro, or methyl; X represents chloro or bromo; R2 is selected from the group consisting of C1-17 alkyl, C1-10 fluorinated alkyl with partial or full fluorination, C2-5 alkenyl, silyl containing alkyl group represented by (CH2)nSiMe3-mClm wherein n is an integer of 0 to 2 and m is an integer of 0 to 3, aromatic group represented by Ar(Rnull)q wherein Ar is C6-14 aromatic hydrocarbon, Rnull is C1-4 alkyl, halogen, alkoxy, or vinyl, and q is an integer of 0 to 5, haloalkyl group represented by (CH2)pX wherein p is an integer of 1 to 9 and X is chloro or bromo, and aromatic hydrocarbon represented by ArCH2X wherein Ar is C6-14 aromatic hydrocarbons and X is a chloro or bromo; R3 is hydrogen, C1-6 alkyl, aromatic group represented by Ar(Rnull)q wherein Ar is C6-14 aromatic hydrocarbon, Rnull is C1-4 alkyl, halogen, alkoxy, or vinyl, and q is an integer of 0 to 5; and R4 in formula I is the same as R2 in formula III and further, R4 can also be (CH2)pSiR1Cl2 or ArCH2SiR1Cl2, when R2 in formula III is (CH2)pX or ArCH2X, which is formed from the coupling reaction of Xnull(CH2)pnull1nullX or XCH2ArCH2X with the compounds of formula II; or when R2 and R3 are covalently bonded to each other to form a cyclic compounds of cyclopentyl or cyclohexyl group, R3 and R4 are also covalently bonded to each other in the same fashion.
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7.发明授权公开(公告)号：US06271407B1
公开(公告)日：2001-08-07
申请号：US09647996
申请日：2001-01-25
申请人： Pascale Colin , Claude De Bellefon , Christina Garcia-Escomel , Pierre Grenouillet , Philippe Morel
发明人： Pascale Colin , Claude De Bellefon , Christina Garcia-Escomel , Pierre Grenouillet , Philippe Morel
IPC分类号： C07F708
摘要： The invention concerns a method for preparing hydrogenated alkylmonosilanes, by catalytic hydrogenolysis, under hydrogen pressure, of halogenoorganopolysilanes, improving known methods, in particular by facilitating implementation, and in terms of cost-effectiveness and performance which are shown by the efficiency of the resulting hydrogenated monosilanes. In said method the starting polysilanes are of the type: (CH3)Cl2Si—SiCl(CH3)2; (CH3)Cl2Si—SiCl2(CH3); (CH3)Cl2Si—Si(CH3)3; (CH3)2ClSi—SiCl(CH3)2; (CH3)Cl2Si—SiCl(Ch3)—SiCl2(CH3); (CH3)Cl2Si—Si(CH3)(SiCH3Cl2)—SiCl2CH3. The hydrogenated monosilanes CH3H2ClSi; (CH3)2HClSi; CH3HCl2Si are obtained by contacting said polysilanes with gaseous hydrogen under pressure, in the presence of a catalytic system AB comprising a hydrogenation catalyst precursor A and an auxiliary B for dissolving precursor A in the reaction medium. Said catalytic system is further characterized in that it is reductant-free.
摘要翻译： 本发明涉及通过催化氢解在氢气压力下制备氢化烷基单硅烷的方法，通过改进已知方法，特别是通过促进实施，以及在成本效益和性能方面，通过所得氢化物的效率 单硅烷 在所述方法中，起始聚硅烷类型为：（CH 3）Cl 2 Si-SiCl（CH 3）2; （CH3）Cl2Si-SiCl2（CH3）; （CH3）Cl2Si-Si（CH3）3; （CH 3）2 ClSi-SiCl（CH 3）2; （CH 3）Cl 2 Si-SiCl（Ch 3）-SiCl 2（CH 3）; （CH 3）Cl 2 Si-Si（CH 3）（SiCH 3 Cl 2）-SiCl 2 CH 3。 氢化单硅烷CH3H2ClSi; （CH3）2HClSi; 在包含氢化催化剂前体A和辅助剂B的催化剂体系AB存在下，将所述聚硅烷与气态氢气在压力下接触，以将前体A溶解在反应介质中，得到CH 3 HCl 2 Si。 所述催化体系的特征还在于其不含还原剂。
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公开(公告)号：US5332853A
公开(公告)日：1994-07-26
申请号：US92319
申请日：1993-07-14
CPC分类号： C07F1/02 , C07F1/00 , C07F7/0896 , C07F7/122
摘要： This application concerns a process for alkylating, in a hydrocarbon solvent reaction medium, metalloidal substrates such as alkylating a chlorosilane with an alkyllithium containing 3 to 8 carbon atoms by conducting these reactions in the presence of a catalyst selected from primary and secondary alcohols, and their respective metal alkoxides, cyclic ethers, hydrocarbyl ethers, hydrocarbyl silyl ethers, and tertiary amines.
摘要翻译： 本申请涉及一种在烃溶剂反应介质中烷基化的方法，例如通过在选自伯醇和仲醇的催化剂存在下进行这些反应而将含有3-8个碳原子的烷基锂烷基化氯代硅烷的金属基底， 各自的金属醇盐，环醚，烃基醚，烃基甲硅烷基醚和叔胺。
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9.发明授权
公开(公告)号：US5286862A
公开(公告)日：1994-02-15
申请号：US398058
申请日：1989-08-24
申请人： Hans H. Schubert
发明人： Hans H. Schubert
CPC分类号： A01N55/00 , C07F7/0827 , C07F7/122
摘要： The present invention relates to a process for the preparation of compounds of the formula I ##STR1## where X is CH.dbd.CH, N.dbd.CH, CH.dbd.N or S,R.sup.1 and R.sup.2 independently of one another are H, halogen, alkyl, alkoxy, alkylthio, haloalkyl, haloalkoxy, haloalkylthio or the bivalent methylenedioxy group,R.sup.3 is a radical of the formulae (A), (B) or (C) ##STR2## where R.sup.4 and R.sup.5 independently of one another are H, halogen, alkyl, alkoxy or a radical of the formula (D) ##STR3## in which R.sup.6 is H or halogen andY is CH.sub.2, O or S, andm, n, o, p and q are 0, 1, or 2, which comprises reacting a compound of the formula IIH.sub.2 C.dbd.CH--CH.sub.2 --R.sup.3 (II) where R.sup.3 is as defined in formula I, with dichloromethylsilane in the presence of a catalyst suitable for hydrosilylation reactions, and reacting the resulting intermediate of the formula III ##STR4## where R.sup.3 is as defined in formula I, in succession and without isolation of the resulting intermediate, with a methylmagnesium halide and an arylmagnesium halide of the general formula IV ##STR5## where R.sup.1, R.sup.2, m, n and X are as defined in formula I and Hal is halogen.The invention furthermore relates to the compounds of the formula III.
摘要翻译： 本发明涉及制备式Ⅰ“化合物”的方法，其中X表示CH = CH，N = CH，CH = N或S，R 1和R 2彼此独立地 表示H，卤素，烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基或二价基亚甲二氧基，R 3表示式（A），（B），（C） R 4和R 5彼此独立地表示H，卤素，烷基，烷氧基或式（D）的基团，其中R 6表示H或卤素，Y表示CH 2，O或S，以及 m，n，o，p和q表示0,1或2，其特征在于式II化合物H 2 C = CH-CH 2 -R 3（II）其中R 3具有如式 I在与适用于氢化硅烷化反应的催化剂存在下与二氯甲基硅烷反应，得到的式III化合物（其中R 3具有式I的含义）的中间体连续反应，而不分离 得到的中间体，与 其中R 1，R 2，m，n和X具有式I中的含义，Hal表示卤素，通式为“IMAGE”的甲基卤化镁和芳基镁卤化物。 本发明还涉及式III的化合物。
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公开(公告)号：US5068386A
公开(公告)日：1991-11-26
申请号：US531617
申请日：1990-06-01
申请人： Akihiko Shirahata
发明人： Akihiko Shirahata
CPC分类号： C07F7/0827 , C07F7/122
摘要： The present invention relates to a method for the preparation of tertiary-hydrocarbylsilyl compounds through a Grignard reaction. A Grignard reagent of formula RMgX, in which R is a tertiary-hydrocarbyl group and X is a halogen atom, is reacted with a silicon compound of formula R.sup.1.sub.a SiX.sub.4-a ; where R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group and a is an integer with a value of zero to three. The process is ran in the presence of a catalytic quantity of a cyano compound or a thiocyanate compound.
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