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    Process for producing carboxylic acids
    1.
    发明授权
    Process for producing carboxylic acids 失效
    制备羧酸的方法

    公开(公告)号：US06784313B2

    公开(公告)日：2004-08-31

    申请号：US10263643

    申请日：2002-10-04

    申请人： Chia Jung Tsai ,  Yao Lung Liu ,  Hsi Chin Tsai

    发明人： Chia Jung Tsai ,  Yao Lung Liu ,  Hsi Chin Tsai

    IPC分类号： C07C5110

    CPC分类号： C07C51/12 ,  C07C53/08

    摘要： A process for producing a carboxylic acid having (n+1) carbon atoms, which includes carbonylating an alcohol having n carbon atoms, and/or an ester of the alcohol and the carboxylic acid in each alkyl group with carbon monoxide in the presence of a catalytic system containing a rhodium catalyst. The process uses a reaction medium for the carbonylation that includes: (1) a rhodium catalyst, (2) an organic halide corresponding to said alcohol, (3) an ester of the alcohol and the carboxylic acid, (4) the carboxylic acid, optionally (5) water, a haloid acid, an inorganic halogen salt or an acetate, and (6) a cocatalyst selected from arginine, N-acetyl alanine, or nitrogen- and oxygen-containing organic compounds.

    摘要翻译： 一种具有（n + 1）个碳原子的羧酸的方法，该方法包括在每个烷基中羰基化具有n个碳原子的醇，和/或每个烷基中的醇和羧酸的酯与一氧化碳在一种 含有铑催化剂的催化体系。 该方法使用羰基化反应介质，其包括：（1）铑催化剂，（2）对应于所述醇的有机卤化物，（3）醇和羧酸的酯，（4）羧酸， 任选的（5）水，卤代酸，无机卤素盐或乙酸盐，和（6）选自精氨酸，N-乙酰丙氨酸或含氮和氧的有机化合物的助催化剂。

    PROCESS FOR PRODUCING CARBOXYLIC ACID ANHYDRIDES
    4.
    发明申请
    PROCESS FOR PRODUCING CARBOXYLIC ACID ANHYDRIDES 失效
    生产羧酸类抗坏血酸的方法

    公开(公告)号：US20100145098A1

    公开(公告)日：2010-06-10

    申请号：US12370268

    申请日：2009-02-12

    申请人： Ching Liang Tu ,  Chia Hui Shen ,  Chia Jung Tsai ,  Chi He Chen

    发明人： Ching Liang Tu ,  Chia Hui Shen ,  Chia Jung Tsai ,  Chi He Chen

    IPC分类号： C07C51/56

    CPC分类号： C07C51/56 ,  C07C53/08

    摘要： A process for producing carboxylic acid anhydrides by the carbonylation reaction of a carboxylic acid ester, derived from an alcohol and a carboxylic acid, with carbon monoxide containing a small amount of hydrogen in a liquid reaction medium in the presence of a Group VIII B catalyst to produce a carboxylic acid anhydride. The reaction medium comprises the Group VIII B catalyst, an organic halide, the carboxylic acid ester, an alkali metal salt, the carboxylic acid anhydride, the carboxylic acid, and at least one ionic liquid consisting of a cation and an anion where the cation of the ionic liquid has a nitrogen-containing heterocyclic structure. The ionic liquid has at least one of the following structural forms: The reaction rate of the carbonylation reaction is increased by the use of the specified ionic liquid promoters.

    摘要翻译： 通过在醇和羧酸中衍生的羧酸酯与含有少量氢的一氧化碳在液体反应介质中在VIII VIII族催化剂存在下羰基化反应制备羧酸酐的方法， 产生羧酸酐。 反应介质包括VIII族B催化剂，有机卤化物，羧酸酯，碱金属盐，羧酸酐，羧酸和至少一种由阳离子和阴离子组成的离子液体，其中阳离子 离子液体具有含氮杂环结构。 离子液体具有以下结构形式中的至少一种：羰基化反应的反应速率通过使用指定的离子液体促进剂而增加。

    Process for producing diaryl carbonates
    5.
    发明授权
    Process for producing diaryl carbonates 有权
    生产碳酸二芳酯的方法

    公开(公告)号：US08212066B2

    公开(公告)日：2012-07-03

    申请号：US12813185

    申请日：2010-06-10

    申请人： Zhen Wei Huang ,  Chih Wei Chang ,  Chia Jung Tsai

    发明人： Zhen Wei Huang ,  Chih Wei Chang ,  Chia Jung Tsai

    IPC分类号： C07C68/00

    CPC分类号： C07C68/005 ,  C07C69/96

    摘要： The present invention relates to a process for producing diaryl carbonates, which is to synthesize diaryl carbonates by oxidative carbonylation of phenols with carbon monoxide and oxygen, and in particular, to synthesize diphenyl carbonate from phenol. The present invention is characterized in that a catalytic system comprising a metal halide catalyst and one or more cocatalysts of nitrogenous heterocyclic compounds is used to increase the convertibility, selectivity and yield of this catalytic reaction.

    摘要翻译： 本发明涉及一种碳酸二芳基酯的制备方法，该方法是通过苯酚与一氧化碳和氧的氧化羰基化合成碳酸二芳基酯，特别是合成苯酚碳酸二苯酯。 本发明的特征在于，使用包含金属卤化物催化剂和一种或多种含氮杂环化合物的助催化剂的催化体系来提高该催化反应的可转换性，选择性和产率。

    PROCESS FOR PRODUCING ORGANIC CARBOXYLIC ACID ESTERS
    6.
    发明申请
    PROCESS FOR PRODUCING ORGANIC CARBOXYLIC ACID ESTERS 审中-公开
    生产有机羧酸酯的方法

    公开(公告)号：US20100160669A1

    公开(公告)日：2010-06-24

    申请号：US12372334

    申请日：2009-02-17

    申请人： Yu Chiao Liu ,  Chin Yi Lee ,  Chia Jung Tsai

    发明人： Yu Chiao Liu ,  Chin Yi Lee ,  Chia Jung Tsai

    IPC分类号： C07C69/66

    CPC分类号： C07C67/20 ,  C07C69/675

    摘要： The present invention relates to a process for producing organic carboxylic acid esters, in which an amino-ester exchange reaction of an organic carboxylic acid amide with an ester compound, or with an alcohol compound under a CO pressure, is carried out at a specific temperature in the presence of a catalyst and a promoter, so as to produce an organic carboxylic acid ester.

    摘要翻译： 本发明涉及一种有机羧酸酯的制备方法，其中有机羧酸酰胺与酯化合物的氨基酯交换反应或在CO压力下与醇化合物的氨基酯交换反应在特定温度下进行 在催化剂和助催化剂的存在下，制备有机羧酸酯。

    Process for producing carboxylic acid anhydrides
    7.
    发明授权
    Process for producing carboxylic acid anhydrides 有权
    制备羧酸酐的方法

    公开(公告)号：US08450524B2

    公开(公告)日：2013-05-28

    申请号：US13010865

    申请日：2011-01-21

    申请人： Hui Ting Wang ,  Chia Jung Tsai ,  Chia Hui Shen

    发明人： Hui Ting Wang ,  Chia Jung Tsai ,  Chia Hui Shen

    IPC分类号： C07C51/56

    CPC分类号： C07C51/56 ,  C07C53/12

    摘要： The present invention relates to a process for producing carboxylic acid anhydrides by the carbonylation reaction of a carboxylic acid ester, derived from an alcohol and a carboxylic acid, with carbon monoxide containing a small amount of hydrogen in a liquid reaction medium in the presence of a Group VIII B catalyst to produce a carboxylic acid anhydride. The liquid reaction medium comprises the Group VIII B catalyst, an organic halide, the carboxylic acid ester, an alkali metal salt, the carboxylic acid anhydride, the carboxylic acid, N-acetylimidazole as a protecting agent, and ethylidene diacetate (EDA) as an organic promoter. By making use of the protecting agent of N-acetylimidazole, metal ions in the reactor can be prevented from reacting with EDA so as to reduce the formation of hardly-soluble tars during the reaction. Also, the EDA organic promoter is kept at a certain content in the system to promote the overall carbonylation reaction rate.

    摘要翻译： 本发明涉及一种通过在醇和羧酸中衍生的羧酸酯与含有少量氢的一氧化碳在液体反应介质中的存在下，通过羰基化反应制备羧酸酐的方法 VIII族B族催化剂生成羧酸酐。 液体反应介质包括VIII族B催化剂，有机卤化物，羧酸酯，碱金属盐，羧酸酐，羧酸，作为保护剂的N-乙酰基咪唑，以及亚乙基二乙酸酯（EDA） 有机促进剂。 通过利用N-乙酰基咪唑的保护剂，可以防止反应器中的金属离子与EDA反应，从而减少反应期间几乎不溶的焦油的形成。 此外，EDA有机促进剂在系统中保持一定含量以促进总的羰基化反应速率。

    Process for Producing Carboxylic Acid Anhydrides
    8.
    发明申请
    Process for Producing Carboxylic Acid Anhydrides 有权
    生产羧酸酐的方法

    公开(公告)号：US20120053366A1

    公开(公告)日：2012-03-01

    申请号：US13010865

    申请日：2011-01-21

    申请人： Hui Ting Wang ,  Chia Jung Tsai ,  Chia Hui Shen

    发明人： Hui Ting Wang ,  Chia Jung Tsai ,  Chia Hui Shen

    IPC分类号： C07C51/56

    CPC分类号： C07C51/56 ,  C07C53/12

    摘要： The present invention relates to a process for producing carboxylic acid anhydrides by the carbonylation reaction of a carboxylic acid ester, derived from an alcohol and a carboxylic acid, with carbon monoxide containing a small amount of hydrogen in a liquid reaction medium in the presence of a Group VIII B catalyst to produce a carboxylic acid anhydride. The liquid reaction medium comprises the Group VIII B catalyst, an organic halide, the carboxylic acid ester, an alkali metal salt, the carboxylic acid anhydride, the carboxylic acid, N-acetylimidazole as a protecting agent, and ethylidene diacetate (EDA) as an organic promoter. By making use of the protecting agent of N-acetylimidazole, metal ions in the reactor can be prevented from reacting with EDA so as to reduce the formation of hardly-soluble tars during the reaction. Also, the EDA organic promoter is kept at a certain content in the system to promote the overall carbonylation reaction rate.

    摘要翻译： 本发明涉及一种通过在醇和羧酸中衍生的羧酸酯与含有少量氢的一氧化碳在液体反应介质中的存在下，通过羰基化反应制备羧酸酐的方法 VIII族B族催化剂生成羧酸酐。 液体反应介质包括VIII族B催化剂，有机卤化物，羧酸酯，碱金属盐，羧酸酐，羧酸，作为保护剂的N-乙酰基咪唑，以及亚乙基二乙酸酯（EDA） 有机促进剂。 通过利用N-乙酰基咪唑的保护剂，可以防止反应器中的金属离子与EDA反应，从而减少反应期间几乎不溶的焦油的形成。 此外，EDA有机促进剂在系统中保持一定含量以促进总的羰基化反应速率。

    Process for producing carboxylic acid anhydrides
    9.
    发明授权
    Process for producing carboxylic acid anhydrides 失效
    制备羧酸酐的方法

    公开(公告)号：US08097756B2

    公开(公告)日：2012-01-17

    申请号：US12370268

    申请日：2009-02-12

    申请人： Ching Liang Tu ,  Chia Hui Shen ,  Chia Jung Tsai ,  Chi He Chen

    发明人： Ching Liang Tu ,  Chia Hui Shen ,  Chia Jung Tsai ,  Chi He Chen

    IPC分类号： C07C51/54

    CPC分类号： C07C51/56 ,  C07C53/08

    摘要： A process for producing carboxylic acid anhydrides by the carbonylation reaction of a carboxylic acid ester, derived from an alcohol and a carboxylic acid, with carbon monoxide containing a small amount of hydrogen in a liquid reaction medium in the presence of a Group VIII B catalyst to produce a carboxylic acid anhydride. The reaction medium comprises the Group VIII B catalyst, an organic halide, the carboxylic acid ester, an alkali metal salt, the carboxylic acid anhydride, the carboxylic acid, and at least one ionic liquid consisting of a cation and an anion where the cation of the ionic liquid has a nitrogen-containing heterocyclic structure. The ionic liquid has at least one of the following structural forms: The reaction rate of the carbonylation reaction is increased by the use of the specified ionic liquid promoters.

    摘要翻译： 通过在醇和羧酸中衍生的羧酸酯与含有少量氢的一氧化碳在液体反应介质中在VIII VIII族催化剂存在下羰基化反应制备羧酸酐的方法， 产生羧酸酐。 反应介质包括VIII族B催化剂，有机卤化物，羧酸酯，碱金属盐，羧酸酐，羧酸和至少一种由阳离子和阴离子组成的离子液体，其中阳离子 离子液体具有含氮杂环结构。 离子液体具有以下结构形式中的至少一种：羰基化反应的反应速率通过使用指定的离子液体促进剂而增加。