公开(公告)号：US11545697B2

公开(公告)日：2023-01-03

申请号：US16645601

申请日：2018-09-12

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Takayoshi Morinaka ,  Keita Nakahara ,  Susumu Iwasaki ,  Wataru Kawabata ,  Mikihiro Takahashi

IPC: H01M10/0567 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/054

Abstract: An additive for a non-aqueous electrolyte solution that can suppress the initial gas generation amount when used in a non-aqueous electrolyte solution battery. The additive for a non-aqueous electrolyte solution is represented by any one of formulae [1] to [4]: wherein R1, R2, R3, R4, X1, X2 and Y are as defined in the specification.

公开(公告)号：US11502335B2

公开(公告)日：2022-11-15

申请号：US16769499

申请日：2018-12-05

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Mikihiro Takahashi ,  Takayoshi Morinaka ,  Wataru Kawabata ,  Makoto Kubo ,  Katsumasa Mori

IPC: H01M10/0567 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/058 ,  H01M4/02

Abstract: Provided are an electrolyte for a non-aqueous electrolyte battery using a positive electrode including nickel, where the battery generates a small amount of gas during a durability test even if the cell potential reaches 4.1 V or more, as well as a non-aqueous electrolyte battery using the electrolyte. In the electrolyte for a non-aqueous electrolyte battery including a positive electrode including at least one selected from the group consisting of oxides containing nickel and phosphates containing nickel as a positive electrode active material, the electrolyte comprises (I) a non-aqueous organic solvent, (II) a fluorine-containing solute being an ionic salt, (III) at least one additive selected from the group consisting of compounds represented by formulae (1) and (2), and (IV) hydrogen fluoride in an amount of 5 mass ppm or more and less than 200 mass ppm based on the total amount of the components (I), (II), and (III).

公开(公告)号：US10287165B2

公开(公告)日：2019-05-14

申请号：US15529638

申请日：2015-12-01

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Takayoshi Morinaka ,  Makoto Kubo ,  Wataru Kawabata ,  Kenta Yamamoto ,  Takashi Mori ,  Masutaka Shinmen ,  Hiroki Matsuzaki ,  Ryosuke Kondo ,  Mikihiro Takahashi

IPC: C01B21/086 ,  C01B21/097 ,  H01M10/0567 ,  B01J27/24 ,  B01J31/02 ,  C07C211/63 ,  C07F9/26 ,  C09K3/16 ,  H01M10/0568 ,  C01B25/455 ,  H01G11/62 ,  H01M10/052 ,  H01M10/054 ,  H01M6/16

Abstract: Provided is a novel imidic acid compound having a divalent anion useful as a pharmaceutical intermediate, an agrochemical intermediate, an acid catalyst, a battery electrolyte or an antistatic agent. The imidic acid compound is a divalent imidic acid compound represented by the following general formula (1) or (2). [In formulae (1) and (2), R1 to R3 represent a fluorine atom or an organic groups selected from a linear or branched C1-10 alkoxy group, a C2-10 alkenyloxy group, a C2-10 alkynyloxy group, a C3-10 cycloalkoxy group, a C3-10 cycloalkenyloxy group and a C6-10 aryloxy group, and wherein a fluorine atom, an oxygen atom or an unsaturated bond may also be present in the organic group. M1 and M2 represent protons, metal cations or onium cations.]

公开(公告)号：US20150147643A1

公开(公告)日：2015-05-28

申请号：US14404271

申请日：2013-05-29

Applicant: Central Glass Co., Ltd.

Inventor： Takayoshi Morinaka ,  Satoshi Muramoto ,  Yoshinori Tateishi ,  Keiji Sato

IPC: H01M10/0568 ,  H01M4/38 ,  H01M10/05 ,  C07F5/02 ,  C07F9/6574

CPC classification number: H01M10/0568 ,  C07B63/02 ,  C07F5/022 ,  C07F9/65742 ,  C07F9/65744 ,  H01G11/54 ,  H01G11/58 ,  H01M4/382 ,  H01M10/05 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/13

Abstract: The present invention provides a purified metal complex having oxalic acid as a ligand and a method for industrially producing a purified non-aqueous solvent solution of the metal complex at low cost. In the method of the present invention, oxalic acid contained in a non-aqueous solvent solution of a metal complex having oxalic acid as a ligand is decomposed by a reaction with a thionyl halide in a non-aqueous solvent, and the decomposition product of the reaction and the unreacted thionyl halide are removed by deaeration.

Abstract translation: 本发明提供了一种具有草酸作为配体的纯化金属络合物和低成本地工业生产金属络合物的非水溶剂溶液的方法。 在本发明的方法中，通过与非水溶剂中的亚硫酰卤反应，在具有草酸作为配位体的金属络合物的非水溶剂溶液中含有的草酸被分解， 通过脱气除去未反应的亚硫酰卤。

公开(公告)号：US11424486B2

公开(公告)日：2022-08-23

申请号：US17064930

申请日：2020-10-07

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Takayoshi Morinaka ,  Makoto Kubo ,  Wataru Kawabata ,  Masutaka Shinmen ,  Hiroki Matsuzaki ,  Mikihiro Takahashi

IPC: H01M10/0569 ,  H01M10/0525 ,  H01M10/0567 ,  H01M4/505 ,  H01M4/525 ,  H01M4/36 ,  H01M10/052 ,  H01M10/0568 ,  H01M6/16 ,  H01M4/02

Abstract: Provided is an electrolyte for a non-aqueous electrolyte battery, which can provide, when used in a non-aqueous electrolyte battery, in a good balance, an effect to suppress an increase in an internal resistance at a low temperature and an effect to suppress an increase in an amount of gas generated at a high temperature, as well as a non-aqueous electrolyte battery containing such an % electrolyte. The non-aqueous electrolyte comprises a non-aqueous solvent and at least a hexafluorophosphate and/or tetrafluoroborate as a solute, and further comprises at least one imide anion-containing salt represented by the following general formula [1] but does not contain a silane compound represented by the following general formula [2] or an ionic complex represented by, for example, the following general formula [3].

公开(公告)号：US11171361B2

公开(公告)日：2021-11-09

申请号：US16717000

申请日：2019-12-17

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Makoto Kubo ,  Takayoshi Morinaka ,  Mikihiro Takahashi ,  Masutaka Shinmen ,  Wataru Kawabata ,  Hiroki Matsuzaki

IPC: H01M10/0567 ,  H01M10/0568 ,  C07F9/28 ,  C07C317/24 ,  C07F9/02 ,  C07C307/02 ,  C07F7/08 ,  C07F7/12 ,  C07F9/26 ,  H01M10/0569 ,  H01M10/0525 ,  H01M10/054

Abstract: The present invention provides an electrolyte solution for a non-aqueous electrolyte battery capable of an exerting high average discharge voltage and an excellent low-temperature output characteristic at −30° C. or lower and an excellent cycle characteristic and an excellent storage characteristic at high temperatures of 50° C. or higher, as well as a non-aqueous electrolyte battery containing the same. The present electrolyte solution comprises a non-aqueous solvent, a solute, at least one silane compound represented by the following general formula (1) as a first compound, and a fluorine-containing compound represented by the following general formula (3), for example, as a second compound. Si(R1)a(R2)4-a  (1)

公开(公告)号：US10553904B2

公开(公告)日：2020-02-04

申请号：US15549210

申请日：2016-02-18

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Makoto Kubo ,  Takayoshi Morinaka ,  Mikihiro Takahashi ,  Masutaka Shinmen ,  Wataru Kawabata ,  Hiroki Matsuzaki

IPC: H01M10/0567 ,  H01M10/0568 ,  C07F9/28 ,  C07C317/24 ,  C07F9/02 ,  H01M10/0569 ,  H01M10/0525 ,  H01M10/054

Abstract: The present invention provides an electrolyte solution for a non-aqueous electrolyte battery capable of an exerting high average discharge voltage and an excellent low-temperature output characteristic at −30° C. or lower and an excellent cycle characteristic and an excellent storage characteristic at high temperatures of 50° C. or higher, as well as a non-aqueous electrolyte battery containing the same. The present electrolyte solution comprises a non-aqueous solvent, a solute, at least one silane compound represented by the following general formula (1) as a first compound, and a fluorine-containing compound represented by the following general formula (3), for example, as a second compound.

公开(公告)号：US10211480B2

公开(公告)日：2019-02-19

申请号：US15529738

申请日：2015-12-01

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Takayoshi Morinaka ,  Makoto Kubo ,  Wataru Kawabata ,  Kenta Yamamoto ,  Mikihiro Takahashi

IPC: H01M10/0567 ,  H01M10/052 ,  H01M10/054 ,  H01M10/0563 ,  H01M10/0568 ,  H01M10/0569

Abstract: An electrolytic solution for a non-aqueous electrolyte battery is provided, which is capable of providing an excellent low-temperature output characteristic at −30° C. or lower and an excellent cycle characteristic at high temperatures of 45° C. or higher. For example, the electrolytic solution contains the following salt having a divalent imide anion. wherein R1 to R3 represent a fluorine atom or an alkoxy group, for example, and M1 and M2 represent protons or metal cations, for example.

公开(公告)号：US20150111098A1

公开(公告)日：2015-04-23

申请号：US14403349

申请日：2013-05-29

Applicant: Central Glass Co., Ltd.

Inventor： Makoto Kubo ,  Takayoshi Morinaka ,  Keita Nakahara ,  Satoshi Muramoto

IPC: H01M10/0567

CPC classification number: H01M10/0567 ,  C07F9/65742 ,  H01M10/0525 ,  H01M10/0568 ,  H01M2300/0025

Abstract: The present invention provides a method of safely producing a solution containing a tetrafluoro(oxalate)phosphate in which the amounts of chlorine compounds and free acids are low such that crystallization refinement is not required in a post-process. The method produces a tetrafluoro(oxalate)phosphate solution by mixing a tetrafluoro(oxalate)phosphate with oxalic acid in a non-aqueous solvent and then adding silicon tetrachloride to the resulting mixture solution for reaction. In the reaction, the addition ratio of the hexafluorophosphate, oxalic acid, and silicon tetrachloride is controlled such that the amount of the hexafluorophosphate is 1.90 moles or more and the amount of the oxalic acid is 1.90 to 2.10 moles, based on 1 mole of the silicon tetrachloride.

Abstract translation: 本发明提供一种安全地生产含有四氯（草酸）磷酸酯的溶液的方法，其中氯化合物和游离酸的量低，使得在后期处理中不需要结晶精制。 该方法通过在无水溶剂中将四氟（草酸）磷酸酯与草酸混合，然后向得到的混合溶液中加入四氯化硅反应生成四氟（草酸）磷酸盐溶液。 在该反应中，控制六氟磷酸盐，草酸和四氯化硅的添加比例，使得六氟磷酸盐的量为1.90摩尔以上，草酸的量为1.90〜2.10摩尔，以1摩尔 四氯化硅。

公开(公告)号：US12206073B2

公开(公告)日：2025-01-21

申请号：US17629085

申请日：2020-07-22

Applicant: CENTRAL GLASS CO., LTD.

Inventor： Ryosuke Terada ,  Mikihiro Takahashi ,  Takayoshi Morinaka ,  Ryota Esaki ,  Susumu Iwasaki ,  Miyuki Yamauchi ,  Wataru Kawabata ,  Masahiro Miura

IPC: H01M10/0568 ,  H01M10/0525 ,  H01M10/0569

Abstract: The present invention provides: a nonaqueous electrolyte solution which is used in a nonaqueous electrolyte battery having a low initial resistance value; and a compound which is contained in this nonaqueous electrolyte solution. A nonaqueous electrolyte solution according to the present invention contains a compound represented by formula (1), a solute and a nonaqueous organic solvent. In general formula (1), each of R1 and R2 represents PO(Rf)2 or SO2Rf, and Rf represents, for example, a fluorine atom; each of R3 and R4 represents, for example, a lithium ion, or alternatively R3 and R4 may form a ring structure together with a nitrogen atom to which the moieties are bonded, and in this case, R3 and R4 form an alkylene group in combination with each other; an oxygen atom may be contained between carbon atom-carbon atom bonds in the alkylene group; a side chain thereof may have an alkyl group; and an arbitrary hydrogen atom in the alkyl group and the alkylene group may be substituted by a fluorine atom.