Antistatic sol/gel compositions and optical articles coated therewith
    1.
    发明授权
    Antistatic sol/gel compositions and optical articles coated therewith 有权
    抗静电溶胶/凝胶组合物和涂覆的光学制品

    公开(公告)号:US09133348B2

    公开(公告)日:2015-09-15

    申请号:US13266712

    申请日:2010-05-07

    摘要: The invention relates to an antistatic coating composition comprising a hydrolyzate resulting from the at least partial hydrolysis of: a component A consisting of one or more compounds containing at least one polyalkylene oxide segment and at least one —Si(X)n hydrolyzable group, in which n is an integer ranging from 1 to 3 and the X groups are precursors of OH groups; at least one inorganic metal salt; and optionally, at least one component B, consisting of one or more compounds of formula Rn,Si(Z)4-n′ or formula R1n1Ym1Si(Z1)4-n1-m1, in which the R groups are monovalent alkyl groups, the Z and Z1 groups are hydrolyzable groups or hydrogen atoms, the R1 groups are monovalent organic groups linked to the silicon atom through a carbon atom, the Y groups are monovalent organic groups linked to the silicon atom and containing at least one epoxy function, n′ is an integer equal to O, 1 or 2, m1 and n1 are integers such that m1 is equal to 1 or 2 and n1+m1=1 or 2, component A and optional component B being chosen such that a cross-linked structure is generated upon polymerization of said composition, the dry extract of said composition containing less than 5% by weight of free polyalkylene oxide polymers.

    摘要翻译: 本发明涉及一种抗静电涂料组合物,其包含由至少部分水解产生的水解产物:由一种或多种含有至少一个聚环氧烷链段和至少一个-Si(X)n可水解基团的化合物组成的组分A, n为1〜3的整数,X基为OH基的前体; 至少一种无机金属盐; 和任选的至少一种由一种或多种式Rn,Si(Z)4-n'或式R1n1Ym1Si(Z1)4-n1-m1化合物组成的组分B,其中R基团是一价烷基, Z和Z1基团是可水解基团或氢原子,R1基团是通过碳原子与硅原子连接的一价有机基团,Y基团是与硅原子连接的含有至少一个环氧官能团的单价有机基团,n' 是等于O,1或2的整数,m1和n1是整数,使得m1等于1或2,n1 + m1 = 1或2,选择组分A和任选的组分B,使得交联结构为 在所述组合物聚合时产生,所述组合物的干提取物含有少于5重量%的游离聚环氧烷聚合物。

    Antistatic Sol/Gel Compositions and Optical Articles Coated Therewith
    2.
    发明申请
    Antistatic Sol/Gel Compositions and Optical Articles Coated Therewith 有权
    抗静电溶胶/凝胶组合物及其制品

    公开(公告)号:US20120045577A1

    公开(公告)日:2012-02-23

    申请号:US13266712

    申请日:2010-05-07

    摘要: The invention relates to an antistatic coating composition comprising a hydrolyzate resulting from the at least partial hydrolysis of: a component A consisting of one or more compounds containing at least one polyalkylene oxide segment and at least one —Si(X)n hydrolyzable group, in which n is an integer ranging from 1 to 3 and the X groups are precursors of OH groups; at least one inorganic metal salt; and optionally, at least one component B, consisting of one or more compounds of formula Rn,Si(Z)4-n′ or formula R1n1Ym1Si(Z1)4-n1-m1, in which the R groups are monovalent alkyl groups, the Z and Z1 groups are hydrolyzable groups or hydrogen atoms, the R1 groups are monovalent organic groups linked to the silicon atom through a carbon atom, the Y groups are monovalent organic groups linked to the silicon atom and containing at least one epoxy function, n′ is an integer equal to O, 1 or 2, m1 and n1 are integers such that m1 is equal to 1 or 2 and n1+m1=1 or 2, component A and optional compo nent B being chosen such that a cross-linked structure is generated upon polymerization of said composition, the dry extract of said composition containing less than 5% by weight of free polyalkylene oxide polymers.

    摘要翻译: 本发明涉及一种抗静电涂料组合物,其包含由至少部分水解产生的水解产物:由一种或多种含有至少一个聚环氧烷链段和至少一个-Si(X)n可水解基团的化合物组成的组分A, n为1〜3的整数,X基为OH基的前体; 至少一种无机金属盐; 和任选的至少一种由一种或多种式Rn,Si(Z)4-n'或式R1n1Ym1Si(Z1)4-n1-m1化合物组成的组分B,其中R基团是一价烷基, Z和Z1基团是可水解基团或氢原子,R1基团是通过碳原子与硅原子连接的一价有机基团,Y基团是与硅原子连接的含有至少一个环氧官能团的单价有机基团,n' 是等于O,1或2的整数,m1和n1是整数,使得m1等于1或2,n1 + m1 = 1或2,组分A和任选的组分B被选择为使得交联结构 在所述组合物聚合时产生,所述组合物的干提取物含有小于5重量%的游离聚环氧烷聚合物。