摘要:
The invention concerns a method of hydrosilylation between a siloxane compound (A) comprising at least one hydrogen atom bonded to a silicon atom and an unsaturated compound (B) comprising at least one alkene function and/or at least one alkyne function, the method being characterized in that it is catalysed by a photocatalyst selected from among the polyoxometalates.
摘要:
The present invention concerns an organopolysiloxane (A) able to be obtained by the reaction, at a temperature of between 10° C. and 75° C., between—at least one compound (C) chosen from the organic compounds comprising at least one alkene or alkyne functional group, at least one of the substituents of which is an acid functional group and the organic compounds comprising at least one acid functional group and at least one alkene or alkyne functional group, at least one of the substituents of which is an electron-withdrawing group; and—at least one organopolysiloxane (B) chosen from the organopolysiloxanes comprising siloxyl units (I.1) and (I.2) of the following formulae: (I) The present invention also concerns compositions comprising said organopolysiloxanes (A) and the uses thereof. ( I ) Y a Z b 1 SiO 4 - ( a + b ) 2 ; ( I .1 ) Z c 2 SiO 4 - c 2 ( I .2 )
摘要:
The present invention relates to a hardenable silicone composition including an irradiation-activated system for temporarily inhibiting the hydrosilylation reaction. Said system includes at least one inhibitor selected from among α-acetylenic alcohols, α-α′-acetylenic diesters, conjugated ene-yne compounds, α-acetylenic ketones, acrylonitriles, maleates, fumarates, the mixture thereof, at least one photoinitiator, and tris(trimethylsilyl)silane (TTMSS). The invention also relates to a method for preparing a silicone coating and hard elastomer materials provided comprising said silicone composition.