公开(公告)号：US09388118B2

公开(公告)日：2016-07-12

申请号：US14038972

申请日：2013-09-27

Applicant: BASF SE

Inventor： Ulrich Jaeger ,  Volker Schliephake ,  Ortmund Lang ,  Jochen Petzoldt ,  Tobias Johannes Korn ,  Virginie Bette ,  Claus Hechler

IPC: C07C67/03 ,  C07C67/08 ,  C07C67/54 ,  C07C69/52 ,  C07C67/62

CPC classification number: C07C67/62 ,  C07C67/08 ,  C07C67/54 ,  C07C69/52 ,  C07C69/54

Abstract: A continuous process for preparing (meth)acrylates of C10-alcohol mixtures by reaction of glacial (meth)acrylic acid with an isomer mixture of C10-alcohols composed of 2-propylheptanol as the main isomer and at least one of the C10-alcohols 2-propyl-4-methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4-methylhexanol, 2-isopropyl-5-methylhexanol and/or 2-propyl-4,4-dimethylpentanol, and the use of a diester of dicarboxylic acids which have been esterified with N-oxyl-containing compounds as polymerization inhibitors in such a process.

Abstract translation: 通过冰（甲基）丙烯酸与由2-丙基庚醇组成的C 10醇作为主要异构体的异构体混合物和至少一种C 10醇2来制备C10-醇混合物的（甲基）丙烯酸酯的连续方法 丙基-4-甲基己醇，2-丙基-5-甲基己醇，2-异丙基庚醇，2-异丙基-4-甲基己醇，2-异丙基-5-甲基己醇和/或2-丙基-4,4-二甲基戊醇， 的二羧酸二酯在这种方法中被N-氧基化合物酯化作为聚合抑制剂。

公开(公告)号：US09353043B2

公开(公告)日：2016-05-31

申请号：US14620579

申请日：2015-02-12

Applicant: BASF SE

Inventor： Andrea Misske ,  Uwe Meisenburg ,  Jochen Petzoldt ,  Virginie Bette ,  Bolette Urtel ,  Jean-Marc Ballin

IPC: C07C67/08 ,  C08G65/332

CPC classification number: C07C67/08 ,  C08G65/3322

Abstract: In a process for preparing (meth)acrylic esters (E) of polyalkoxy-containing alcohols which comprises reacting polyalkoxy-containing alcohols (P) of formula (I) where R1 is hydrogen, a hydroxyl group or a straight-chain or branched, saturated or unsaturated alcohol of 1 to 30 carbon atoms, R2 and R3 are each independently H or methyl, and m and n are each independently an integer between 0 and 100, with the proviso that m and n cannot both be 0, with a (meth)acrylic anhydride (A) in the presence of at least one basic catalyst (K) having a pKB value of not more than 7.0 and of at least one sterically hindered polymerization inhibitor, the reaction mixture is quenched with a C1-C6 alkanol after the reaction has ended.

Abstract translation: 在制备含有聚烷氧基的醇的（甲基）丙烯酸酯（E）的方法中，其包括使式（I）的含有聚烷氧基的醇（P），其中R 1为氢，羟基或直链或支链饱和 或1〜30个碳原子的不饱和醇，R2和R3各自独立地为H或甲基，m和n各自独立地为0〜100的整数，条件是m和n不能均为0，与（甲基） ）丙烯酸酐（A）在至少一种pKB值不大于7.0的碱性催化剂（K）和至少一种空间位阻聚合抑制剂存在下，将反应混合物用C 1 -C 6烷醇淬灭后 反应已经结束。

公开(公告)号：US20150232409A1

公开(公告)日：2015-08-20

申请号：US14620579

申请日：2015-02-12

Applicant: BASF SE

Inventor： Andrea MISSKE ,  Uwe Meisenburg ,  Jochen Petzoldt ,  Virginie Bette ,  Bolette Urtel

IPC: C07C67/08

CPC classification number: C07C67/08 ,  C08G65/3322

Abstract: In a process for preparing (meth)acrylic esters (E) of polyalkoxy-containing alcohols which comprises reacting polyalkoxy-containing alcohols (P) of formula (I) where R1 is hydrogen, a hydroxyl group or a straight-chain or branched, saturated or unsaturated alcohol of 1 to 30 carbon atoms, R2 and R3 are each independently H or methyl, and m and n are each independently an integer between 0 and 100, with the proviso that m and n cannot both be 0, with a (meth)acrylic anhydride (A) in the presence of at least one basic catalyst (K) having a pKB value of not more than 7.0 and of at least one sterically hindered polymerization inhibitor, the reaction mixture is quenched with a C1-C6 alkanol after the reaction has ended.

Abstract translation: 在制备含有聚烷氧基的醇的（甲基）丙烯酸酯（E）的方法中，其包括使式（I）的含有聚烷氧基的醇（P），其中R 1为氢，羟基或直链或支链饱和 或1〜30个碳原子的不饱和醇，R2和R3各自独立地为H或甲基，m和n各自独立地为0〜100的整数，条件是m和n不能均为0，与（甲基） ）丙烯酸酐（A）在至少一种pKB值不大于7.0的碱性催化剂（K）和至少一种空间位阻聚合抑制剂存在下，将反应混合物用C 1 -C 6烷醇淬灭后 反应已经结束。