公开(公告)号：US11549417B2

公开(公告)日：2023-01-10

申请号：US17045332

申请日：2019-04-23

申请人： BASF Corporation

发明人： Marcus Hilgendorff ,  Karifala Dumbuya ,  Matthias Peter ,  Andreas Sundermann

IPC分类号： F01N3/20 ,  B01J6/00 ,  B01J23/22 ,  B01J29/072 ,  B01J37/00 ,  B01J37/02

摘要： The present invention relates to a selective catalytic reduction catalyst for the treatment of an exhaust gas of a diesel engine comprising: a flow-through substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the flow through substrate extending therethrough; a coating disposed on the surface of the internal walls of the substrate, wherein the coating comprises a non-zeolitic oxidic material comprising manganese and one or more of the metals of the groups 4 to 11 and 13 of the periodic table, and further comprises one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron.

公开(公告)号：US11213789B2

公开(公告)日：2022-01-04

申请号：US15757384

申请日：2016-08-29

申请人： BASF Corporation

发明人： Marcus Hilgendorff ,  Karifala Dumbuya ,  Claudia Zabel ,  Susanne Stiebels

IPC分类号： B01J37/02 ,  B01J35/00 ,  B01D53/94 ,  B01J29/76 ,  F01N3/20

摘要： A catalyst containing a washcoat including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms physically mixed with platinum and rhodium on a refractory metal oxide support including alumina, silica, zirconia, titania, and a physical mixture or a chemical combination or an atomically doped combination thereof is described. A catalyst containing a first washcoat zone substantially free of platinum group metal and including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms; and a second washcoat zone including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms physically mixed with platinum or platinum and rhodium on a refractory metal oxide support including alumina, silica, zirconia, titania, and a physical mixture or a chemical combination or an atomically doped combination thereof is provided. A method and a system for treating emissions using the catalyst are also described.

公开(公告)号：US10724411B2

公开(公告)日：2020-07-28

申请号：US16484874

申请日：2018-03-13

申请人： BASF Corporation

发明人： Karifala Dumbuya ,  Claudia Zabel ,  Shiang Sung

IPC分类号： F01N3/10 ,  B01J23/00 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J37/00 ,  B01J37/02

摘要： A diesel oxidation catalyst, containing a washcoat containing four layers, the washcoat being disposed on a substrate, wherein the washcoat contains: a first layer containing a first platinum group metal supported on a first metal oxide support material, wherein the first layer is disposed on the substrate; a second layer containing a second platinum group metal supported on a second metal oxide support material, and containing a fifth platinum group metal, wherein the second layer is disposed on the first layer; a third layer containing a third platinum group metal supported on a third metal oxide support material and containing a zeolitic material containing Fe and containing a sixth platinum group metal; and a fourth layer containing a fourth platinum group metal and a fourth metal oxide.

公开(公告)号：US20240189771A1

公开(公告)日：2024-06-13

申请号：US18556735

申请日：2022-04-21

申请人： BASF Corporation

发明人： Karifala Dumbuya ,  Thomas Schmitz ,  Chunxin Ji ,  Florian Waltz ,  Stephan Siemund

IPC分类号： B01D53/94 ,  B01J21/04 ,  B01J23/10 ,  B01J23/44 ,  B01J23/46 ,  B01J35/00 ,  F01N3/10 ,  F01N3/28

CPC分类号： B01D53/945 ,  B01J21/04 ,  B01J23/10 ,  B01J23/44 ,  B01J23/464 ,  B01J35/19 ,  F01N3/101 ,  F01N3/2803 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/702 ,  B01D2258/012 ,  B01D2258/014 ,  F01N2370/02

摘要： The present invention relates to three-way conversion catalysts (TWC) for the treatment of an exhaust gas stream comprising nitrogen oxides (NOx), carbon monoxide (CO), and hydrocarbons (HC), comprising platinum group metal (PGM), a refractory metal oxide support, and a carrier characterized in that the platinum group metal (PGM) comprises platinum, palladium and rhodium, as well as methods and uses thereof.

公开(公告)号：US11896962B2

公开(公告)日：2024-02-13

申请号：US16953533

申请日：2020-11-20

申请人： BASF Corporation

发明人： Shiang Sung ,  Stanley A. Roth ,  Karifala Dumbuya ,  Susanne Stiebels ,  Claudia Zabel ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01D53/94 ,  B01J29/076 ,  B01J37/02 ,  B01J35/00 ,  B01J23/63 ,  B01J23/40 ,  B01J23/656

CPC分类号： B01J29/076 ,  B01D53/944 ,  B01D53/945 ,  B01J35/0006 ,  B01J37/0244 ,  B01J37/0246 ,  B01D53/9418 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/2073 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9025 ,  B01J23/40 ,  B01J23/63 ,  B01J23/6562 ,  Y02T10/12

摘要： An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat comprising a zeolite, Pt, and first refractory metal oxide support containing manganese, a second washcoat comprising a second refractory metal oxide support, a Pt component and a Pd component, and a third washcoat comprising palladium and a rare earth oxide component is described.

公开(公告)号：US20230321635A1

公开(公告)日：2023-10-12

申请号：US18043964

申请日：2021-09-23

申请人： BASF Corporation ,  BASF SE

发明人： Yuejin Li ,  Andreas Sundermann ,  Xiaolai Zheng ,  Yipeng Sun ,  Karifala Dumbuya ,  Pascaline Tran

IPC分类号： B01J23/42 ,  B01J23/46 ,  B01J23/10 ,  B01J21/04 ,  B01J21/06 ,  B01J37/02 ,  B01J37/04 ,  B01D53/86 ,  F01N3/10

CPC分类号： B01J23/42 ,  B01J23/464 ,  B01J23/10 ,  B01J21/04 ,  B01J21/066 ,  B01J37/0201 ,  B01J37/04 ,  B01D53/865 ,  F01N3/101 ,  F01N2570/14 ,  F01N2570/10 ,  F01N2570/12 ,  F01N2330/18

摘要： The present invention provides a catalyst composition comprising a) platinum; b) rhodium; and c) a ceria-alumina composite, a zirconia composite or a mixture thereof, wherein platinum is supported on the ceria-alumina composite, zirconia composite or mixture thereof, wherein rhodium is supported on the ceria-alumina composite, zirconia composite or mixture thereof, wherein CeO2 in the ceria alumina composite is 1.0 to 50 wt. %, based on the total weight of the ceria-alumina composite, wherein the amount of ZrO2 in the zirconia composite is 50 to 99 wt. %, based on the total weight of the zirconia composite. The present invention also provides a catalytic article comprising the catalyst composition and its preparation.

公开(公告)号：US11192066B2

公开(公告)日：2021-12-07

申请号：US16308730

申请日：2017-06-07

申请人： BASF Corporation

发明人： Natalia Trukhan ,  Michaela Maltry ,  Ulrich Mueller ,  Stefan Marx ,  Karifala Dumbuya ,  Mathias Feyen

IPC分类号： B01J29/04 ,  B01J29/03 ,  B01D53/94 ,  B01J37/02 ,  B01J37/08 ,  B01J37/10 ,  B01D53/86 ,  B01J29/76 ,  B01J35/04 ,  B01J35/10 ,  C01B39/48 ,  B01J37/00 ,  F01N3/20 ,  F01N3/28 ,  B01J31/16 ,  B01J31/22

摘要： The present invention relates to a process for the preparation of a catalyst for selective catalytic reduction comprising • (i) preparing a mixture comprising a metal-organic framework material comprising an ion of a metal or metalloid selected from groups 2-5, groups 7-9, and groups 11-14 of the Periodic Table of the Elements, and at least one at least monodentate organic compound, a zeolitic material containing a metal as a non-framework element, optionally a solvent system, and optionally a pasting agent, • (ii) calcining of the mixture obtained in (i); and further relates to a catalyst per se comprising a composite material containing an amorphous mesoporous metal and/or metalloid oxide and a zeolitic material, wherein the zeolitic material contains a metal as non-framework element, as well as to the use of said catalyst.

公开(公告)号：US20210069684A1

公开(公告)日：2021-03-11

申请号：US16953533

申请日：2020-11-20

申请人： BASF Corporation

发明人： Shiang Sung ,  Stanley A. Roth ,  Karifala Dumbuya ,  Susanne Stiebels ,  Claudia Zabel ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01J29/076 ,  B01D53/94 ,  B01J37/02 ,  B01J35/00

摘要： An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat comprising a zeolite, Pt, and first refractory metal oxide support containing manganese, a second washcoat comprising a second refractory metal oxide support, a Pt component and a Pd component, and a third washcoat comprising palladium and a rare earth oxide component is described.

公开(公告)号：US20150165423A1

公开(公告)日：2015-06-18

申请号：US14107781

申请日：2013-12-16

申请人： BASF Corporation

发明人： Shiang Sung ,  Stanley A. Roth ,  Karifala Dumbuya ,  Susanne Stiebels ,  Claudia Zabel ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01J29/076 ,  B01D53/94

CPC分类号： B01J29/076 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/945 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/2073 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9025 ,  B01J23/40 ,  B01J23/63 ,  B01J23/6562 ,  B01J35/0006 ,  B01J37/0244 ,  B01J37/0246 ,  Y02T10/24

摘要： An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat comprising a zeolite, Pt, and first refractory metal oxide support containing manganese, a second washcoat comprising a second refractory metal oxide support, a Pt component and a Pd component, and a third washcoat comprising palladium and a rare earth oxide component is described.

摘要翻译： 描述了用于处理来自柴油发动机的废气排放物的氧化催化剂复合材料，方法和系统。 更具体地说，一种氧化催化剂复合材料，包括包含沸石，Pt和含有锰的第一难熔金属氧化物载体的第一修补基面涂料，包含第二难熔金属氧化物载体的第二修补基面涂料，Pt组分和Pd组分，以及第三修补基面涂料， 描述了钯和稀土氧化物组分。

公开(公告)号：US12005426B2

公开(公告)日：2024-06-11

申请号：US17250794

申请日：2019-09-12

申请人： BASF Corporation

发明人： Karifala Dumbuya ,  Thomas Schmitz ,  Florian Waltz ,  Stephan Siemund

IPC分类号： B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/12 ,  B01J23/10 ,  B01J23/34 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J23/63 ,  B01J23/656 ,  B01J37/02 ,  F01N3/035 ,  F01N3/10 ,  F01N3/08

CPC分类号： B01J23/6562 ,  B01J21/04 ,  B01J37/0244 ,  F01N3/035 ,  F01N3/101 ,  F01N3/0835 ,  F01N3/0842 ,  F01N3/0857

摘要： The disclosure relates to a three-way conversion catalyst for the treatment of an exhaust gas comprising nitrogen monoxide, carbon monoxide, and hydrocarbon, wherein the catalyst comprises: (i) a substrate; (ii) a first coating comprising rhodium supported on a first oxidic component; (iii) a second coating comprising palladium supported on a non-zeolitic oxidic material, wherein the non-zeolitic oxidic material comprises manganese and a second oxidic component, wherein the second coating consists of 0 weight-% to 0.001 weight-% of platinum; wherein the first coating is disposed on the substrate over x % of the axial length, with x ranging from 80 to 100; wherein the second coating extends over y % of the axial length from the inlet end to the outlet end and is disposed on the first coating, with y ranging from 20 to x.