公开(公告)号：US09334418B2

公开(公告)日：2016-05-10

申请号：US11321680

申请日：2005-12-29

Applicant: Cheng-Chung Chang ,  Zai-Ming Qiu ,  Naiyong Jing ,  Cheryl L Elsbernd

Inventor： Cheng-Chung Chang ,  Zai-Ming Qiu ,  Naiyong Jing ,  Cheryl L Elsbernd

IPC: C08F214/18 ,  C08F14/06 ,  C09D133/16

CPC classification number: C09D133/16 ,  C08F214/18 ,  C08F214/188 ,  Y10T428/3154 ,  Y10T428/31855

Abstract: The invention features a coating composition that comprises a non-urethane acrylate or methacrylate compound in combination with a fluorochemical. Typically, the non-urethane (meth)acrylate is an aliphatic or aromatic (meth)acrylate compound and the fluorochemical typically comprises a monofunctional (per)fluoropolyether (meth)acrylate compound. The coating compositions can provide a protective topcoat layer to a variety of substrates, including wood and vinyl.

Abstract translation: 本发明的特征在于涂料组合物，其包含与含氟化合物组合的非氨基甲酸酯丙烯酸酯或甲基丙烯酸酯化合物。 通常，非氨基甲酸酯（甲基）丙烯酸酯是脂族或芳族（甲基）丙烯酸酯化合物，并且含氟化合物通常包含单官能（全）氟聚醚（甲基）丙烯酸酯化合物。 涂料组合物可以为各种基材（包括木材和乙烯基材料）提供保护性顶涂层。

公开(公告)号：US09234058B2

公开(公告)日：2016-01-12

申请号：US13885185

申请日：2011-12-09

Applicant: Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

Inventor： Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

IPC: C08F14/16 ,  C08F8/34 ,  C08F114/16 ,  C08F8/44 ,  C08F28/02

Abstract: Described herein is a composition comprising a fluorinated polysulfinic acid or a salt thereof having the following formula (I): wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3, and CH3 and wherein at least one of X1, X2, or X3 is H; R1 is a linking group; Z1 and Z2 are independently selected from Br, Cl, I, F, CF3, and a perfluorinated alkyl group; M is a cation; p is 0 or 1; and n is at least 2. Also described is a method of making the partially fluorinated polysulfinic acid or salt thereof.

公开(公告)号：US09206317B2

公开(公告)日：2015-12-08

申请号：US13504545

申请日：2009-12-14

Applicant: Jayshree Seth ,  Marie A. Boulos ,  Zai-Ming Qiu ,  Janet A. Venne

Inventor： Jayshree Seth ,  Marie A. Boulos ,  Zai-Ming Qiu ,  Janet A. Venne

IPC: C09J7/02 ,  C08L83/08 ,  C09D183/08 ,  C08K5/01 ,  C08K5/05 ,  C08K5/06 ,  C08K5/07 ,  C08G77/24 ,  C08K5/54 ,  C08G77/12 ,  C08G77/20

CPC classification number: C08L83/08 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08K5/01 ,  C08K5/05 ,  C08K5/06 ,  C08K5/07 ,  C08K5/5406 ,  C09D183/08 ,  C09J7/401 ,  C09J2483/005 ,  Y10T428/2839 ,  C08L2666/14 ,  C08L83/00 ,  C08K5/56

Abstract: Release compositions comprising a blend of ethylenically unsaturated fluoroorganopolysiloxane polymers and ethylenically unsaturated non-fluorinated organopolysiloxane polymers are described. The release compositions are dispersed in a solvent system and also contain a catalyst and at least one crosslinker. Both fluoroorganohydrogenpolysiloxane and organohydrogenpolysiloxane are described. Release liners and adhesive articles including cured release compositions are also disclosed.

Abstract translation: 描述了包含烯键式不饱和氟代有机聚硅氧烷聚合物和烯键式不饱和非氟化有机聚硅氧烷聚合物的共混物的释放组合物。 释放组合物分散在溶剂体系中并且还含有催化剂和至少一种交联剂。 描述了氟代有机氢聚硅氧烷和有机氢聚硅氧烷。 还公开了包括固化的剥离组合物的脱模衬垫和粘合制品。

公开(公告)号：US09096712B2

公开(公告)日：2015-08-04

申请号：US13321621

申请日：2010-06-29

Applicant: Zai-Ming Qiu

Inventor： Zai-Ming Qiu

IPC: C08G65/22 ,  C09D183/06 ,  C09D183/08 ,  G03F1/48 ,  G03F7/004 ,  G03F7/038 ,  G03F7/075 ,  H05K3/00 ,  C08G77/14 ,  C08G77/24 ,  C08G77/26 ,  C08G77/28 ,  G03F7/20 ,  H05K3/02

CPC classification number: C08G65/22 ,  C08G77/14 ,  C08G77/24 ,  C08G77/26 ,  C08G77/28 ,  C09D183/06 ,  C09D183/08 ,  G03F1/48 ,  G03F7/0046 ,  G03F7/038 ,  G03F7/0755 ,  G03F7/2014 ,  H05K3/00 ,  H05K3/02 ,  H05K2203/0557

Abstract: A curable composition comprises: an epoxy silane represented by formula X—Si(OR1)(OR2)(OR3) wherein R1-R3 represent C1 to C4 alkyl groups, and X represents an organic group having at least one oxirane ring; a fluorinated silane represented by formula; wherein: Rf represents a perfluoroalkyl group having from 3 to 5 carbon atoms, R4 represents H or a C1 to C4 alkyl group, and R5-R7 represent C1 to C4 alkyl groups; and a photoacid. Use of the curable composition to coat a phototool, thereby providing a protective coating on the phototool is also disclosed.

Abstract translation: 可固化组合物包含：由式X-Si（OR1）（OR2）（OR3）表示的环氧硅烷（OR3），其中R1-R3表示C1至C4烷基，X表示具有至少一个环氧乙烷环的有机基团; 由式表示的氟化硅烷; 其中：Rf表示碳原子数3〜5的全氟烷基，R4表示H或C1〜C4烷基，R5-R7表示C1〜C4烷基。 和光酸。 还公开了使用可固化组合物涂覆光固醇，从而在光固醇上提供保护性涂层。

公开(公告)号：US08715904B2

公开(公告)日：2014-05-06

申请号：US13457657

申请日：2012-04-27

Applicant: Zai-Ming Qiu ,  Douglas C. Fall

Inventor： Zai-Ming Qiu ,  Douglas C. Fall

IPC: G03F7/004

CPC classification number: G03F7/0046 ,  G03F7/027 ,  G03F7/038

Abstract: A low surface energy photoresist composition is described that comprises a silicone-polyether block copolymer, wherein the silicone block comprises 35 wt. % or more of said copolymer. When compounded with a photoresist composition, the composition enables the release of a phototool from the photoresist layer.

Abstract translation: 描述了一种低表面能光致抗蚀剂组合物，其包含硅氧烷 - 聚醚嵌段共聚物，其中硅氧烷嵌段包含35wt。 ％以上的所述共聚物。 当与光致抗蚀剂组合物复合时，组合物能够从光致抗蚀剂层释放光学工具。

公开(公告)号：US08663874B2

公开(公告)日：2014-03-04

申请号：US12922133

申请日：2009-03-11

Applicant: Zai-Ming Qiu ,  John C. Hulteen ,  Douglas C. Fall

Inventor： Zai-Ming Qiu ,  John C. Hulteen ,  Douglas C. Fall

IPC: C09D133/08 ,  G03F1/12

CPC classification number: G03F7/11 ,  G03F1/48 ,  G03F1/54 ,  G03F7/0048 ,  G03F7/0755 ,  G03F7/2014 ,  H05K3/0002

Abstract: A hardcoat composition comprises (a) one or more epoxy silane compounds, (b) one or more epoxy-functionalized perfluoropolyether acrylate oligomers, and (c) photoacid generator.

Abstract translation: 硬涂层组合物包含（a）一种或多种环氧硅烷化合物，（b）一种或多种环氧官能化的全氟聚醚丙烯酸酯低聚物，和（c）光酸产生剂。

公开(公告)号：US08628855B2

公开(公告)日：2014-01-14

申请号：US12740357

申请日：2008-12-10

Applicant: Encai Hao ,  Zai-Ming Qiu ,  Yu Yang ,  Thomas P. Klun

Inventor： Encai Hao ,  Zai-Ming Qiu ,  Yu Yang ,  Thomas P. Klun

IPC: B32B27/30

CPC classification number: G02B1/14 ,  C08G65/007 ,  C08G65/3322 ,  C08G65/33351 ,  C08G2650/48 ,  C08J7/045 ,  C08J7/047 ,  C08J2433/16 ,  C08L71/02 ,  C08L2205/05 ,  C09D133/02 ,  C09D133/16 ,  C09D171/02 ,  G02B1/10 ,  G02B1/105 ,  Y10T428/31511 ,  Y10T428/3154 ,  Y10T428/31544 ,  C08L2666/22 ,  C08L2666/04

Abstract: Presently described are articles, such as optical displays and protective films, comprising a (e.g. light transmissive) substrate having a surface layer comprising the reaction product of a mixture comprising a non-fluorinated binder precursor (e.g. of a hardcoat composition) and at least one polymerizable perfluoropolyether polymer. The resulting cured surface layer can advantageously exhibit low lint attraction in combination with low surface energy. Also described are one-step and two-step methods of synthesizing perfluoropolyether polymers having polymerizable ethylenically unsaturated groups.

Abstract translation: 目前描述的是诸如光学显示器和保护膜的物品，其包括具有表面层（例如透光性）的基材，该表面层包含包含非氟化粘合剂前体（例如硬涂层组合物）的混合物的反应产物和至少一种 可聚合的全氟聚醚聚合物。 所得到的固化表面层可以有利地表现出与低表面能结合的低绒毛吸引力。 还描述了合成具有可聚合烯属不饱和基团的全氟聚醚聚合物的一步和两步法。

公开(公告)号：US20130281648A1

公开(公告)日：2013-10-24

申请号：US13885185

申请日：2011-12-09

Applicant: Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

Inventor： Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

IPC: C08F114/16

CPC classification number: C08F114/16 ,  C08F8/12 ,  C08F8/26 ,  C08F8/34 ,  C08F8/44 ,  C08F14/16 ,  C08F28/02 ,  C08F114/185 ,  C08F214/182 ,  C08F2800/20 ,  C08F2810/50 ,  C08F214/184 ,  C08F228/02

Abstract: Described herein is a composition comprising a fluorinated polysulfinic acid or a salt thereof having the following formula (I): wherein X1, X2, and X3 are independently selected from H, F, CI, Br, I, CF3, and CH3 and wherein at least one of X1, X2, or X3 is H; R1 is a linking group; Z1 and Z2 are independently selected from Br, CI, I, F, CF3, and a perfluorinated alkyl group; M is a cation; p is 0 or 1; and n is at least 2. Also described is a method of making the partially fluorinated polysulfinic acid or salt thereof.

Abstract translation: 本文描述的是包含具有下式（I）的氟化聚亚磺酸或其盐的组合物：其中X 1，X 2和X 3独立地选自H，F，Cl，Br，I，CF 3和CH 3，并且其中 X 1，X 2或X 3中的至少一个为H; R1是连接基团; Z 1和Z 2独立地选自Br，Cl，I，F，CF 3和全氟化烷基; M是阳离子; p为0或1; 并且n至少为2.还描述了制备部分氟化聚亚磺酸或其盐的方法。

公开(公告)号：US08476398B2

公开(公告)日：2013-07-02

申请号：US13396669

申请日：2012-02-15

Applicant: Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, Jr.

Inventor： Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, Jr.

IPC: C08G18/71 ,  C08G18/34

CPC classification number: C07C235/08 ,  C08G18/3802 ,  C08G18/3825 ,  C08G18/672 ,  C08G18/673 ,  C08G18/792 ,  C08G18/8175 ,  C09D175/16 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31551 ,  C08G18/50

Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.

公开(公告)号：US20110027702A1

公开(公告)日：2011-02-03

申请号：US12922133

申请日：2009-03-11

Applicant: Zai-Ming Qiu ,  John C. Hulteen ,  Douglas C. Fall

Inventor： Zai-Ming Qiu ,  John C. Hulteen ,  Douglas C. Fall

IPC: G03F1/00 ,  C08F124/00 ,  G03F7/20 ,  G03F7/004

CPC classification number: G03F7/11 ,  G03F1/48 ,  G03F1/54 ,  G03F7/0048 ,  G03F7/0755 ,  G03F7/2014 ,  H05K3/0002

Abstract: A hardcoat composition comprises (a) one or more epoxy silane compounds, (b) one or more epoxy-functionalized perfluoropolyether acrylate oligomers, and (c) photoacid generator.

Abstract translation: 硬涂层组合物包含（a）一种或多种环氧硅烷化合物，（b）一种或多种环氧官能化的全氟聚醚丙烯酸酯低聚物，和（c）光酸产生剂。