公开(公告)号：US5488098A

公开(公告)日：1996-01-30

申请号：US193646

申请日：1994-02-07

Applicant: Masayuki Miki ,  Kingo Akahori ,  Yutaka Kayane ,  Takeshi Washimi

Inventor： Masayuki Miki ,  Kingo Akahori ,  Yutaka Kayane ,  Takeshi Washimi

IPC: C09B62/085 ,  C09B62/44 ,  C09B62/51 ,  D06P1/384

CPC classification number: C09B62/4413 ,  C09B62/51

Abstract: A monoazo compound of the following formula, ##STR1## wherein D is phenylene or naphthylene; X is halogeno, pyridinio or ##STR2## B is --OR.sub.3, --SR.sub.4, ##STR3## in which R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, r is 0 or 1, and E is O, SO, SO.sub.2, CH.sub.2 or NR.sub.8, in which R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl; R, R.sub.1, R.sub.2 and R.sub.7 are each hydrogen or alkyl; A.sub.1, A.sub.2 and A.sub.3 are each phenylene, naphthylene or alkylene; Z.sub.1, Z.sub.2 and Z.sub.3 are each --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a splittable group; and p is 0 or 1; which compound is useful for dyeing or printing fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

Abstract translation: 下式的单偶氮化合物，其中D是亚苯基或亚萘基; X是卤素，吡啶鎓或B是-OR 3，-SR 4，其中R 3，R 4，R 5和R 6各自是氢，烷基，苯基，萘基或苄基，r是0或1，E是 O，SO，SO 2，CH 2或NR 8，其中R 8是氢或C 1 -C 4烷基; R，R 1，R 2和R 7各自为氢或烷基; A1，A2和A3各自为亚苯基，亚萘基或亚烷基; Z 1，Z 2和Z 3各自为-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Y，其中Y为可裂解基团; p为0或1; 该化合物可用于染色或印刷纤维材料以获得染色或印刷成具有优异的各种牢度性能的颜色的产品，具有优异的聚集性能。

公开(公告)号：US5359040A

公开(公告)日：1994-10-25

申请号：US963553

申请日：1992-10-20

Applicant: Kingo Akahori ,  Masayuki Miki ,  Takeshi Washimi ,  Yutaka Kayane

Inventor： Kingo Akahori ,  Masayuki Miki ,  Takeshi Washimi ,  Yutaka Kayane

IPC: C07D251/54 ,  C09B62/085 ,  C09B62/51 ,  D06P1/384

CPC classification number: C09B62/51

Abstract: A monoazo compound represented by the following formula (I) in the free acid form: ##STR1## wherein X is an alkylamino, C.sub.5 -C.sub.7 cycloalkylamino, piperidino, pyrrolidino or morpholino group which is unsubstituted or substituted with a substituent other than sulfo, R is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl, R.sub.1 and R.sub.2 independently of one another are each hydrogen, methoxy, ethoxy, methyl, ethyl, chloro, bromo, nitro, carboxy or sulfo, Z is vinyl or -CH.sub.2 CH.sub.2 Y in which Y is a group which is split by the action of an alkali and p is 0 or 1. This compound is a reactive dye suitable for dyeing or printing fiber materials containing hydroxyl group and/or amide group in red color. This compound is high in dissolvability and can give dyed or printed products excellent in dyeability such as build-up property and various fastnesses.

Abstract translation: 由游离酸形式的下式（I）表示的单偶氮化合物：其中X是未被取代或被取代基以外的取代基取代的烷基氨基，C 5 -C 7环烷基氨基，哌啶子基，吡咯烷子基或吗啉代基 磺基，R为氢或未取代或取代的C 1 -C 4烷基，R 1和R 2各自独立地为氢，甲氧基，乙氧基，甲基，乙基，氯，溴，硝基，羧基或磺基，Z为乙烯基或-CH2CH2Y Y是通过碱的作用而分裂的基团，p是0或1.该化合物是适用于染色或印刷含有红色的羟基和/或酰胺基的纤维材料的活性染料。 该化合物的溶解性高，可以赋予染色性，印染性等优异的染色性，例如聚集性和各种坚牢度。

公开(公告)号：US5266696A

公开(公告)日：1993-11-30

申请号：US836825

申请日：1992-02-19

Applicant: Kingo Akahori ,  Naoki Harada ,  Yutaka Kayane ,  Takashi Omura

Inventor： Kingo Akahori ,  Naoki Harada ,  Yutaka Kayane ,  Takashi Omura

IPC: C09B62/024 ,  C09B62/44 ,  C09B62/505 ,  C07D251/70 ,  C09B62/06 ,  D06P1/382 ,  D06P1/384

CPC classification number: C09B62/024 ,  C09B62/4409 ,  C09B62/505

Abstract: Anthraquinone compounds of the formula, ##STR1## wherein R is hydrogen, alkyl or the like, R.sub.1 and R.sub.2 are each hydrogen, halogen or sulfo, l is 1 or 2, X is sulfo or the like or --V--A--(W).sub.m --Z, and Y is --V.sub.1 --A.sub.1 --U, wherein V and V.sub.1 are each --O-- or --S--, A and A.sub.1 are each a divalent group such as ##STR2## W is --NH-- or the like, Z is hydrogen or a fiber reactive group, and U is hydrogen, a fiber reactive group or a fiber reactive group-containing group, provided that at least one of Z and U is or has a fiber reactive group, which is useful for dyeing or printing fiber materials such as cotton to give a dyed or printed product having excellent fastness properties, particularly those such as light fastness and perspiration-light fastness.

Abstract translation: 下式的蒽醌化合物，其中R是氢，烷基等，R 1和R 2各自为氢，卤素或磺基，l为1或2，X为磺基等或-VA-（W）mZ ，Y为-V1-A1-U，其中V和V1各自为-O-或-S-，A和A1各自为二价基团，例如W为-NH-等，Z为氢 或纤维反应性基团，U为氢，纤维反应性基团或含纤维反应性基团，条件是Z和U中的至少一个为或具有纤维反应性基团，其可用于染色或印刷纤维材料 例如棉，以得到具有优异坚牢性的染色或印刷产品，特别是耐光牢度和耐汗牢度等。

公开(公告)号：US4548612A

公开(公告)日：1985-10-22

申请号：US611889

申请日：1984-05-18

Applicant: Yutaka Kayane ,  Naoki Harada

Inventor： Yutaka Kayane ,  Naoki Harada

IPC: C09B67/26 ,  C09B67/24

CPC classification number: C09B67/0072 ,  Y10S8/918

Abstract: A reactive dye composition comprising (1) a dye having the formula, ##STR1## wherein D is an organic dye residue having at least one sulfo group, R.sub.1 and R.sub.2 are independently a hydrogen atom or an unsubstituted or substituted lower alkyl group, A is an unsubstituted or substituted phenylene or naphthylene group, X is a halogen atom, and Y is a group, --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali, and (2) a buffer, the amount of the buffer being from 3 through 80% by weight based on the weight of the dye, and the pH value of an aqueous solution prepared from the dye composition and water of 20 times as much as the weight of the dye composition being from 3.5 through 7.5, which is superior in storage stability, and useful for dyeing or printing fiber materials to give dyed or printed products having superior fastness with high reproducibility.

Abstract translation: 一种活性染料组合物，其包含（1）具有下式的染料，其中D是具有至少一个磺基的有机染料残基，R 1和R 2独立地是氢原子或未取代或取代的低级烷基，A是 未取代或取代的亚苯基或亚萘基，X为卤素原子，Y为基团-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z为能够通过碱的作用而分裂的基团，和（2） 缓冲液，缓冲液的量基于染料的重量为3-80重量％，由染料组合物和水制备的水溶液的pH值为染料重量的20倍 组合物为3.5至7.5，其储存稳定性优异，并且可用于染色或印花纤维材料，以赋予具有优异牢固性和高再现性的染色或印刷产品。

公开(公告)号：US6136970A

公开(公告)日：2000-10-24

申请号：US967617

申请日：1992-10-29

Applicant: Kazufumi Yokogawa ,  Takahiko Fujisaki ,  Miyao Takahashi ,  Shigeru Kawabata ,  Naoki Harada ,  Kingo Akahori ,  Yutaka Kayane ,  Takashi Omura

Inventor： Kazufumi Yokogawa ,  Takahiko Fujisaki ,  Miyao Takahashi ,  Shigeru Kawabata ,  Naoki Harada ,  Kingo Akahori ,  Yutaka Kayane ,  Takashi Omura

IPC: C07D265/34 ,  C09B19/00 ,  C09B62/002 ,  C09B62/02 ,  C09B62/44 ,  C09B62/503 ,  C07D498/04

CPC classification number: C09B62/5033 ,  C09B62/0025 ,  C09B62/021 ,  C09B62/4405

Abstract: An asymmetric dioxazine compound represented by the following formula (I) in the free acid form: ##STR1## wherein A.sub.1 and A.sub.2 independently of one another are each sulfo, halo, alkyl or alkoxy, X.sub.1 and X.sub.2 independently of one another are each hydrogen, halo, alkyl, alkoxy or phenoxy, R.sub.1 is hydrogen or unsubstituted or substituted alkyl, R.sub.2 and R.sub.3 independently of one another are each hydrogen, alkyl, alkoxy, halo or unsubstituted or substituted amino, Z is a fiber-reactive group, m and n independently of one another are each 0 or 1, provided that m.noteq.n, and L is 1 or 2. This compound is suitable for dyeing and printing cellulose fiber, natural and synthetic polyamide fibers, polyurethane fiber, leather and the like and mixed yarns thereof, to obtain dyed or printed products of a color fast to light, wetness and chlorine with superior build-up and level dyeing properties.

Abstract translation: 由游离酸形式的下式（I）表示的不对称二嗪类化合物：其中A1和A2彼此独立地各自为磺基，卤素，烷基或烷氧基，X 1和X 2彼此独立地为氢，卤素，烷基 ，烷氧基或苯氧基，R 1是氢或未取代或取代的烷基，R 2和R 3彼此独立地各自为氢，烷基，烷氧基，卤素或未取代或取代的氨基，Z为纤维反应性基团，m和n独立地为一个 另外每个都为0或1，条件是m注意n和L为1或2.该化合物适用于将纤维素纤维，天然和合成聚酰胺纤维，聚氨酯纤维，皮革等及其混合纱线染色和印刷到 获得染色或印刷的产品，颜色快速到轻，湿和氯，具有优异的积聚和水平的染色性能。

公开(公告)号：US5235046A

公开(公告)日：1993-08-10

申请号：US793096

申请日：1991-11-18

Applicant: Kingo Akahori ,  Masayuki Miki ,  Yutaka Kayane ,  Takeshi Washimi

Inventor： Kingo Akahori ,  Masayuki Miki ,  Yutaka Kayane ,  Takeshi Washimi

IPC: C09B62/04 ,  C09B62/085 ,  C09B62/503 ,  C09B62/505 ,  C09B62/51 ,  C09B62/513 ,  C09B62/515 ,  D06P1/38 ,  D06P1/384 ,  D06P3/66

CPC classification number: C09B62/503

Abstract: A triazine compound which is useful for dyeing or printing materials containing hydroxyl group and/or amide group, and which has the following formula (I) or salts thereof ##STR1## wherein R represents hydrogen or unsubstituted or substituted alkyl; R.sub.1 represents hydrogen, an alkyl unsubstituted or substituted by carboxy, sulfo, alkoxy, halogeno, sulfato or hydroxy, or --Y--SO.sub.2 Z.sub.3 ; R.sub.2 represents hydrogen or unsubstituted or substituted alkyl; A represents unsubstituted or substituted phenylene or naphthylene; Y represents a divalent group which is C.sub.2 -C.sub.7 alkylene and so on; Z.sub.1, Z.sub.2 and Z.sub.3 independently of one another are each --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 Z' wherein Z' is a group capable of being split by the action of an alkali; and F is any one of the dye residue which is anthraquinone, azo, disazo, trisazo or phthalocyanine nucleus and so on, and a process for dyeing or printing fiber materials which comprises using said triazine compounds or salts thereof.

公开(公告)号：US4937326A

公开(公告)日：1990-06-26

申请号：US714361

申请日：1985-03-22

Applicant: Yutaka Kayane ,  Masaki Sunami ,  Katsumasa Otake ,  Yasuo Tezuka

Inventor： Yutaka Kayane ,  Masaki Sunami ,  Katsumasa Otake ,  Yasuo Tezuka

IPC: C09B62/44

CPC classification number: C09B62/4413

Abstract: A novel reactive monoazo dye, which can give to cellulose fiber materials a deep orange to scarlet color superior in build-up property and chlorine fastness, represented by a free acid of the formula, ##STR1## wherein D is a phenyl group substituted with 1 to 3 substitutes selected from methyl, ethyl, methoxy, ethoxy, halogen, acetylamino, propionylamino, benzoylamino, succinylamino, maleinylamino, nitro, suflonic acid and carboxyl groups; R.sub.1 is a hydrogen atom, or a methyl or ethyl group; R.sub.2 is an alkyl group having 1 to 4 carbon atoms which is unsubstituted or substituted with a hydroxy, cyano, alkoxy, halogen, carboxy, alkoxycarbonyl or sulfonic acid group; Z is a hydrogen atom or a sulfonic acid group; A is a phenylene residue which is unsubstituted or substituted with 1 or 2 substituents selected from methyl, ethyl, methoxy, ethoxy, chlorine, bromine and sulfonic acid groups; or a naphthylene residue which is unsubstituted or substituted with one sulfonic acid group; and X is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y in which Y is a group which is splittable by alkalis.

Abstract translation: 一种新型的反应性单偶氮染料，其可以赋予纤维素纤维材料深层橙色至具有优异的聚集性能和耐氯牢度的猩红色，由下式的游离酸代表：其中D是被1个 至3个选自甲基，乙基，甲氧基，乙氧基，卤素，乙酰氨基，丙酰氨基，苯甲酰基氨基，琥珀酰氨基，马来酰氨基，硝基，磺酰基和羧基的取代基。 R1是氢原子，或甲基或乙基; R2是未取代的或被羟基，氰基，烷氧基，卤素，羧基，烷氧基羰基或磺酸基团取代的具有1至4个碳原子的烷基; Z是氢原子或磺酸基; A是未取代的或被1或2个选自甲基，乙基，甲氧基，乙氧基，氯，溴和磺酸基的取代基取代的亚苯基; 或未被取代或被一个磺酸基团取代的亚萘基残基; X为-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Y，其中Y为可被碱分解的基团。

公开(公告)号：US4751300A

公开(公告)日：1988-06-14

申请号：US8790

申请日：1987-01-30

Applicant: Taira Fujita ,  Yutaka Kayane

Inventor： Taira Fujita ,  Yutaka Kayane

IPC: C07D498/22 ,  C09B19/02

CPC classification number: C07D498/22 ,  C09B19/02

Abstract: Dioxazine compound of the formula (I) mentioned below which is useful for dyes or pigments is prepared by heating a compound of ##STR1## in the presence of inorganic acid with or without an oxidizing agent in an inert organic solvent: ##STR2## wherein R is defined above; X.sub.1 and X.sub.2 are selected from a hydrogen atom and a chlorine atom.

Abstract translation: 下述通式（I）的二恶嗪化合物可用于染料或颜料，是通过在惰性有机溶剂中在有或无氧化剂存在下，在无机酸存在下，在惰性有机溶剂中加热化合物： >（I）其中R定义如上; X1和X2选自氢原子和氯原子。

公开(公告)号：US4511507A

公开(公告)日：1985-04-16

申请号：US563587

申请日：1983-12-20

Applicant: Yutaka Kayane ,  Takashi Omura ,  Katsumasa Otake ,  Akira Takeshita

Inventor： Yutaka Kayane ,  Takashi Omura ,  Katsumasa Otake ,  Akira Takeshita

IPC: C09B33/10 ,  C09B62/44 ,  C09B62/51 ,  D06P1/38 ,  C09B62/08 ,  D06P3/10

CPC classification number: D06P1/38 ,  C09B62/4413 ,  Y10S8/918

Abstract: A monoazo compound which is useful for dyeing or printing fiber materials, particularly cellulose fiber materials in red color, and which is represented by a free acid of the formula, ##STR1## wherein D is a phenyl group substituted with one to three substituents selected from the group consisting of halogen atoms and methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino, sulfo and carboxyl groups, R is a C.sub.1 to C.sub.4 alkyl group unsubstituted or substituted with a halogen atom or a hydroxyl, cyano, alkyl, alkoxy, carboxyl, carbamoyl, alkoxycarbonyl or sulfo group, A is a phenylene group unsubstituted or substituted with one or two substituents selected from the group consisting of methyl, ethyl, methoxy, ethoxy and sulfo groups and chlorine and bromine atoms, or a naphthylene group unsubstituted or substituted with one sulfo group, and X is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y in which Y is a group capable of being split by the action of an alkali.

Abstract translation: 用于染色或印刷纤维材料，特别是红色的纤维素纤维材料的单偶氮化合物，其由下式的游离酸表示，其中D是被一至三个选自以下的取代基取代的苯基： 由卤素原子和甲基，乙基，甲氧基，乙氧基，乙酰氨基，丙酰氨基，磺基和羧基组成的基团，R是未被取代或被卤素原子或羟基，氰基，烷基，烷氧基，羧基取代的C1至C4烷基 ，氨基甲酰基，烷氧基羰基或磺基，A是未被取代或被一个或两个选自甲基，乙基，甲氧基，乙氧基和磺基以及氯和溴原子的取代基取代的亚苯基，或未取代或取代的亚萘基 具有一个磺基，X是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Y，其中Y是能够通过碱的作用而分裂的基团。

公开(公告)号：US06277966B1

公开(公告)日：2001-08-21

申请号：US09736375

申请日：2000-12-15

Applicant: Yutaka Kayane ,  Akihiro Taguma ,  Narutoshi Hayashi

Inventor： Yutaka Kayane ,  Akihiro Taguma ,  Narutoshi Hayashi

IPC: C09B31043

Abstract: An azo-compound, free acid form of which is represented by the following formula (I): wherein A and B represent, independently with each other, a phenyl having one or two groups selected from sulfo and carboxyl or a naphthyl having 1 to 3 sulfos; R1, R2, R3, R4, R5 and R6 represent, independently with each other, hydrogen, lower alkyl or lower alkoxy; and X represents —N═N— or —NHCO—, and a dye polarizing film containing the azo-compound in a polarizing film base, which exhibits a high polarizing performance and is excellent in durability and light fastness, are provided.