公开(公告)号：US07419718B2

公开(公告)日：2008-09-02

申请号：US10481739

申请日：2003-02-25

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: B32B5/16 ,  C09K3/18 ,  B05D3/02

CPC classification number: C08K3/22 ,  B01J21/063 ,  B01J21/066 ,  B01J31/0202 ,  B01J31/0204 ,  B01J35/004 ,  B01J37/0018 ,  C03C17/007 ,  C03C2217/477 ,  C03C2217/71 ,  C08K2003/2237 ,  C09D5/00 ,  C09D7/61 ,  Y10T428/25 ,  Y10T428/256

Abstract: A coating film forming liquid containing a saccharide, and titanium oxide fine particles having peroxy groups or titanium oxide fine particles not having peroxy groups is applied onto a surface of a substrate such as glass, metal or a tile, and then heating is carried out at a high temperature, thus forming on the substrate a super-hydrophilic photocatalytic coating film that contains titanium oxide fine particles and has a water contact angle in a state in which the photocatalyst is not excited of less than 10°.

Abstract translation: 将含有糖的涂膜形成液和具有过氧基的氧化钛微粒或不具有过氧基的氧化钛微粒施加到诸如玻璃，金属或瓷砖的基材的表面上，然后在 高温，从而在基板上形成含有氧化钛微粒的超亲水性光催化剂涂膜，并且在光催化剂未被激发的状态下具有小于10°的水接触角。

公开(公告)号：US08518174B2

公开(公告)日：2013-08-27

申请号：US13216389

申请日：2011-08-24

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: C09C1/36

CPC classification number: C09C1/36 ,  B01J21/063 ,  B01J23/002 ,  B01J23/06 ,  B01J23/70 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/03 ,  B01J2523/00 ,  C01G23/047 ,  C01G23/0536 ,  C01P2002/54 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/3607 ,  C09C1/3653 ,  Y10T428/12611 ,  Y10T428/12771 ,  B01J2523/27 ,  B01J2523/47 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/847

Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having titania-metal composite having peroxy groups, and not having a photocatalytic activity fine particles dispersed therein, wherein the titania-metal composite includes particles of at least one of elemental copper, manganese, nickel, cobalt, iron, zinc and compounds thereof; using this to form a coating film, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.

Abstract translation: 在铜，锰，镍，钴，铁，锌及其化合物中存在至少一种的情况下，四价钛盐溶液和碱性溶液一起反应形成钛和上述金属的氢氧化物，然后 氢氧化钛用氧化剂过氧化以制造具有二氧化钛 - 金属复合材料的具有过氧基并且不具有分散在其中的光催化活性细颗粒的水性液体或分散体，其中所述二氧化钛 - 金属复合材料包括至少一种元素的颗粒 铜，锰，镍，钴，铁，锌及其化合物; 使用它来形成涂膜时，可以防止由于涂料，印刷制品，建筑材料，纤维，有机聚合物树脂产品等的褪色或变色引起的颜色的装饰性下降，此外，表面 可以实现防污染和亲水性。

公开(公告)号：US20120048144A1

公开(公告)日：2012-03-01

申请号：US13216389

申请日：2011-08-24

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: C09D1/00

CPC classification number: C09C1/36 ,  B01J21/063 ,  B01J23/002 ,  B01J23/06 ,  B01J23/70 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/03 ,  B01J2523/00 ,  C01G23/047 ,  C01G23/0536 ,  C01P2002/54 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/3607 ,  C09C1/3653 ,  Y10T428/12611 ,  Y10T428/12771 ,  B01J2523/27 ,  B01J2523/47 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/847

Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having therein titanium oxide fine particles having peroxy groups; by using this alone to form a coating film adjacent to a coating film of an organic dye or pigment, or using this to form a coating film together with an organic dye or pigment, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.

公开(公告)号：US06235401B1

公开(公告)日：2001-05-22

申请号：US09051237

申请日：1999-04-19

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: C01G2304

CPC classification number: C23C26/02 ,  B01J21/063 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0244 ,  C01B15/047 ,  C03C17/007 ,  C03C17/256 ,  C03C2217/212 ,  C03C2217/42 ,  C03C2217/71 ,  C03C2218/11 ,  C03C2218/113 ,  C04B41/009 ,  C04B41/5041 ,  C04B41/52 ,  C04B41/87 ,  C04B41/89 ,  C04B2111/00827 ,  C08J7/06 ,  C09D1/00 ,  C23C2/04 ,  C23C4/123 ,  C23C18/1216 ,  C23C18/1295 ,  C23C26/00 ,  Y10T428/24917 ,  C04B41/4537 ,  C04B41/4535 ,  C04B41/4545 ,  C04B41/5025 ,  C04B33/00 ,  C04B35/00

Abstract: A hydrophilic treatment by the use of a surface active agent and the like is not required for a base even the surface of which is water-repellent or thermoplastic when a viscous amorphous type titanium peroxide is used for fixing a base as a binder. In addition, a thin layer of a photocatalyst semiconductor, a dielectrical ceramics or an electrical ceraincs can be easily formed by adhering particles of a photocatalyst semiconductor, a dielectrical ceramics or an electrical ceramics to the layer of a viscous amorphous type titanium peroxide, which is a layer as a binder, in a homogeneously floating state gas. Furthermore, a layer of a titanium oxide having a photocatalyst function can be formed when a base is fixed with a viscous amorphous type titanium peroxide.

Abstract translation: 当使用粘性无定形型过氧化钛作为粘合剂固定基材时，即使表面具有防水性或热塑性，也不需要通过使用表面活性剂等的亲水处理。 此外，通过将光催化剂半导体，介电陶瓷或电陶瓷的颗粒粘附到粘性无定形型二氧化钛的层上，可以容易地形成光催化剂半导体，电介质陶瓷或电子陶瓷的薄层，其为 作为粘合剂的层，在均匀漂浮状态的气体中。 此外，当用粘性无定形型过氧化钛固定基材时，可以形成具有光催化剂功能的氧化钛层。

公开(公告)号：US08158270B2

公开(公告)日：2012-04-17

申请号：US13216568

申请日：2011-08-24

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: C01G23/04 ,  C09D1/00 ,  C09D5/16 ,  C09C1/36 ,  B05D1/00

CPC classification number: C09C1/36 ,  B01J21/063 ,  B01J23/002 ,  B01J23/06 ,  B01J23/70 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/03 ,  B01J2523/00 ,  C01G23/047 ,  C01G23/0536 ,  C01P2002/54 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/3607 ,  C09C1/3653 ,  Y10T428/12611 ,  Y10T428/12771 ,  B01J2523/27 ,  B01J2523/47 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/847

Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having therein titanium oxide fine particles having peroxy groups; by using this alone to form a coating film adjacent to a coating film of an organic dye or pigment, or using this to form a coating film together with an organic dye or pigment, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.

Abstract translation: 在铜，锰，镍，钴，铁，锌及其化合物中存在至少一种的情况下，四价钛盐溶液和碱性溶液一起反应形成钛和上述金属的氢氧化物，然后 用氧化剂过氧化氢氧化钛，制造其中具有过氧基团的氧化钛微粒的水性液体或分散体; 通过单独使用它们来形成与有机染料或颜料的涂膜相邻的涂膜，或者使用它与有机染料或颜料一起形成涂膜，由于褪色或变色引起的颜色的装饰性下降 可以防止涂料，印刷品，建筑材料，纤维，有机聚合物树脂产品等，并且还可以实现表面防污和亲水性。

公开(公告)号：US20120045655A1

公开(公告)日：2012-02-23

申请号：US13216568

申请日：2011-08-24

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: B32B15/04 ,  B05D1/36

CPC classification number: C09C1/36 ,  B01J21/063 ,  B01J23/002 ,  B01J23/06 ,  B01J23/70 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/03 ,  B01J2523/00 ,  C01G23/047 ,  C01G23/0536 ,  C01P2002/54 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/3607 ,  C09C1/3653 ,  Y10T428/12611 ,  Y10T428/12771 ,  B01J2523/27 ,  B01J2523/47 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/847

Abstract: Under the presence of at least one out of copper, manganese, nickel, cobalt, iron, zinc, and compounds thereof, a tetravalent titanium salt solution and a basic solution are reacted together to form a hydroxide of titanium and the above metal, and then the titanium hydroxide is peroxidated with an oxidizing agent to manufacture an aqueous liquid or dispersion having therein titanium oxide fine particles having peroxy groups; by using this alone to form a coating film adjacent to a coating film of an organic dye or pigment, or using this to form a coating film together with an organic dye or pigment, a drop in decorativeness of color due to fading or discoloration of a coating material, a printed article, a building material, a fiber, an organic polymer resin product or the like can be prevented, and moreover surface anti-soiling and hydrophilic properties can be realized.

公开(公告)号：US20110121634A1

公开(公告)日：2011-05-26

申请号：US12736418

申请日：2009-04-10

Applicant: Keiji Koike ,  Masayuki Iwasaki ,  Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Keiji Koike ,  Masayuki Iwasaki ,  Shiro Ogata ,  Yoshimitsu Matsui

IPC: B60B19/00 ,  B32B27/36 ,  H05K13/00

CPC classification number: B32B7/02 ,  Y10T29/49002 ,  Y10T428/31507

Abstract: The present invention relates to a method for preventing or reducing contamination of a surface of a substrate, or protecting a surface of a substrate by making a surface of a substrate hydrophilic, by means of arranging, successively in relation to the substrate, a first layer containing a negatively-charged substance, and a second layer containing a positively-charged substance or containing a positively-charged substance and a negatively-charged substance on the surface of the substrate or in a surface layer of the substrate. In accordance with the present invention, a novel method for preventing or reducing adhesion of contaminants, and color degradation or color change of a substrate over time, can be provided.

Abstract translation: 本发明涉及一种用于防止或减少基材表面的污染或通过使基材的表面亲水化来保护基材表面的方法，该方法通过相继地相对于基底排列第一层 含有带负电荷的物质，以及含有带正电物质或含有带正电荷物质和带负电荷物质的第二层在基材表面或基材表面层。 根据本发明，可以提供一种用于防止或降低污染物的粘附性，以及基板随时间的颜色劣化或颜色变化的新方法。

公开(公告)号：US06379811B2

公开(公告)日：2002-04-30

申请号：US09810252

申请日：2001-03-19

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: B01J2300

CPC classification number: C23C26/02 ,  B01J21/063 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0244 ,  C01B15/047 ,  C03C17/007 ,  C03C17/256 ,  C03C2217/212 ,  C03C2217/42 ,  C03C2217/71 ,  C03C2218/11 ,  C03C2218/113 ,  C04B41/009 ,  C04B41/5041 ,  C04B41/52 ,  C04B41/87 ,  C04B41/89 ,  C04B2111/00827 ,  C08J7/06 ,  C09D1/00 ,  C23C2/04 ,  C23C4/123 ,  C23C18/1216 ,  C23C18/1295 ,  C23C26/00 ,  Y10T428/24917 ,  C04B41/4537 ,  C04B41/4535 ,  C04B41/4545 ,  C04B41/5025 ,  C04B33/00 ,  C04B35/00

Abstract: A hydrophilic treatment by the use of a surface active agent and the like is not required for a base even the surface of which is water-repellent or thermoplastic when a viscous amorphous type titanium peroxide is used for fixing a base as a binder. In addition, a thin layer of a photocatalyst semiconductor, a dielectrical ceramics or an electrical ceramics can be easily formed by adhering particles of a photocatalyst semiconductor, a dielectrical ceramics or an electrical ceramics to the layer of a viscous amorphous type titanium peroxide, which is a layer as a binder, in a homogeneously floating state gas. Furthermore, a layer of a titanium oxide having a photocatalyst function can be formed when a base is fixed with a viscous amorphous type titanium peroxide.

Abstract translation: 当使用粘性无定形型过氧化钛作为粘合剂固定基材时，即使表面具有防水性或热塑性，也不需要通过使用表面活性剂等的亲水处理。 此外，光催化剂半导体，介电陶瓷或电陶瓷的薄层可以通过将光催化剂半导体，介电陶瓷或电陶瓷的颗粒粘附到粘性无定形型过氧化钛的层上而容易地形成，其是 作为粘合剂的层，在均匀漂浮状态的气体中。 此外，当用粘性无定形型过氧化钛固定基材时，可以形成具有光催化剂功能的氧化钛层。

公开(公告)号：US06344277B1

公开(公告)日：2002-02-05

申请号：US09663710

申请日：2000-09-18

Applicant: Shiro Ogata ,  Yoshimitsu Matsui

Inventor： Shiro Ogata ,  Yoshimitsu Matsui

IPC: B32B900

CPC classification number: C23C26/02 ,  B01J21/063 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0244 ,  C01B15/047 ,  C03C17/007 ,  C03C17/256 ,  C03C2217/212 ,  C03C2217/42 ,  C03C2217/71 ,  C03C2218/11 ,  C03C2218/113 ,  C04B41/009 ,  C04B41/5041 ,  C04B41/52 ,  C04B41/87 ,  C04B41/89 ,  C04B2111/00827 ,  C08J7/06 ,  C09D1/00 ,  C23C2/04 ,  C23C4/123 ,  C23C18/1216 ,  C23C18/1295 ,  C23C26/00 ,  Y10T428/24917 ,  C04B41/4537 ,  C04B41/4535 ,  C04B41/4545 ,  C04B41/5025 ,  C04B33/00 ,  C04B35/00

Abstract: A hydrophilic treatment by the use of a surface active agent and the like is not required for a base even the surface of which is water-repellent or thermoplastic when a viscous amorphous type titanium peroxide is used for fixing a base as a binder. In addition, a thin layer of a photocatalyst semiconductor, a dielectrical ceramics or an electrical ceramics can be easily formed by adhering particles of a photocatalyst semiconductor, a dielectrical ceramics or an electrical ceramics to the layer of a viscous amorphous type titanium peroxide, which is a layer as a binder, in a homogeneously floating state gas. Furthermore, a layer of a titanium oxide having a photocatalyst function can be formed when a base is fixed with a viscous amorphous type titanium peroxide.

公开(公告)号：USRE36832E

公开(公告)日：2000-08-22

申请号：US100241

申请日：1998-06-19

Applicant: Masashi Nagamine ,  Kenji Yamamoto ,  Yoshimitsu Matsui ,  Kenji Horiuchi ,  Masanori Yoshida

Inventor： Masashi Nagamine ,  Kenji Yamamoto ,  Yoshimitsu Matsui ,  Kenji Horiuchi ,  Masanori Yoshida

IPC: A61K31/34 ,  A61K31/343 ,  A61K31/38 ,  A61K31/381 ,  A61K31/40 ,  A61K31/403 ,  A61K31/404 ,  A61P3/06 ,  A61P9/10 ,  A61P43/00 ,  C07D209/40 ,  C07D307/77 ,  C07D307/82 ,  C07D307/92 ,  C07D307/935 ,  C07D333/66 ,  C07D333/74 ,  C07D333/78 ,  C12N9/99

CPC classification number: C07D307/82 ,  C07D209/40 ,  C07D307/92 ,  C07D333/66 ,  C07D333/74 ,  C07D333/78

Abstract: An N-heteroaryl-N'-phenylurea derivative represented by the general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are as defined in the description of the specification which is useful as a prophylactic and therapeutic agent for hypercholesterolemia, atherosclerosis and diseases caused by them.

Abstract translation: 由通式（I）表示的N-杂芳基-N'-苯基脲衍生物：其中R1，R2，R3，R4，R5，R6和R7如说明书的描述中所定义，其可用作预防和治疗 高胆固醇血症药物，动脉粥样硬化及其引起的疾病。