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1.发明申请Benzocyclobutene based polymer formulations and methods for processing such formulations in oxidative environments 有权基于苯并环丁烯的聚合物配方和在氧化环境中处理这些制剂的方法公开(公告)号：US20090275673A1
公开(公告)日：2009-11-05
申请号：US11665245
申请日：2005-10-12
Applicant: Ying Hung So , Edmund J. Stark , Jack E. Hetzner , Shellene K. Thurston
Inventor： Ying Hung So , Edmund J. Stark , Jack E. Hetzner , Shellene K. Thurston
IPC: C08K5/13 , C08K5/3435 , C08K5/3492 , C08K5/53 , C08K5/053
CPC classification number: G03F7/0233 , C08K5/13 , G03F7/0085 , G03F7/0125 , G03F7/038 , C08L65/00
Abstract: The use of hindered phenol containing anti-oxidants enable arylcyclobutene-based formulations to be cured in oxygen containing environments such as air without unacceptable degradation in key properties of dielectric constant, water uptake, or transmittance.
Abstract translation: 使用含有受阻酚的抗氧化剂使得基于芳基环丁烷的制剂能够在含氧环境例如空气中固化，而在介电常数，吸水率或透射率的关键性能方面不会有不可接受的降解。
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公开(公告)号：US5965679A
公开(公告)日：1999-10-12
申请号：US834677
申请日：1997-04-01
Applicant: James P. Godschalx , Duane R. Romer , Ying Hung So , Zenon Lysenko , Michael E. Mills , Gary R. Buske , Paul H. Townsend, III , Dennis W. Smith, Jr. , Steven J. Martin , Robert A. DeVries
Inventor： James P. Godschalx , Duane R. Romer , Ying Hung So , Zenon Lysenko , Michael E. Mills , Gary R. Buske , Paul H. Townsend, III , Dennis W. Smith, Jr. , Steven J. Martin , Robert A. DeVries
CPC classification number: C08G61/10 , C08G2261/312
Abstract: An oligomer, uncured polymer or cured polymer comprising the reaction product of one or more polyfunctional compounds containing two or more cyclopentadienone groups and at least one polyfunctional compound containing two or more aromatic acetylene groups wherein at least some of the polyfunctional compounds contain three or more reactive groups. Such oligomers and uncured polymers may be cured to form cured polymers which are useful as dielectrics in the microelectronics industry, especially for dielectrics in integrated circuits.
Abstract translation: 包含含有两个或多个环戊二烯酮基团的一种或多种多官能化合物与至少一种含有两个或多个芳族乙炔基团的多官能化合物的反应产物的低聚物，未固化聚合物或固化聚合物，其中至少一些多官能化合物含有三个或更多个反应性 团体 这种低聚物和未固化的聚合物可以固化以形成固化聚合物，其可用作微电子工业中的电介质，特别是用于集成电路中的电介质。
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3.发明授权Aqueous developable, photosensitive benzocyclobutene-based oligomers and polymers with high moisture resistance 有权水性可显影，光敏苯并环丁烯低聚物和具有高耐湿性的聚合物公开(公告)号：US07198878B2
公开(公告)日：2007-04-03
申请号：US11146818
申请日：2005-06-07
Applicant: Ying Hung So , Scott J. Bis , Keith J. Watson
Inventor： Ying Hung So , Scott J. Bis , Keith J. Watson
Abstract: The invention is a photoswitchable benzocyclobutene-based polymer that while remaining aqueous developable, avoids the problem of significant moisture uptake. The oligomer or polymer comprises a polymeric backbone, benzocyclobutene reactive groups, and photoswitchable pendant groups. The pendant groups are bonded to the polymeric backbone and are characterized by the presence of a moiety that converts to carboxylic acid upon exposure to activating wavelengths of radiation a carboxylic acid. When the oligomer or polymer is subsequently heated to cause cure of the oligomer or polymer, carbon dioxide is emitted and the group forms a substantially non-polar moiety. The invention is also a method of making such a polymer and a method of forming a patterned film using such a polymer.
Abstract translation: 本发明是一种可光切换的基于苯并环丁烯的聚合物，其在保持水可显影的同时，避免了显着吸湿的问题。 低聚物或聚合物包含聚合物主链，苯并环丁烯反应性基团和可照照开关的侧基。 侧基键合到聚合物骨架上，其特征在于存在一个部分，当暴露于活化的辐射波长的羧酸时，该部分转变成羧酸。 当低聚物或聚合物随后被加热以使低聚物或聚合物固化时，发出二氧化碳，并且该基团形成基本上非极性部分。 本发明也是制造这种聚合物的方法和使用这种聚合物形成图案化膜的方法。
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4.发明授权Aqueous developable, photosensitive benzocyclobutene-based oligomers and polymers with high moisture resistance 有权水性可显影，光敏苯并环丁烯低聚物和具有高耐湿性的聚合物公开(公告)号：US07019093B2
公开(公告)日：2006-03-28
申请号：US10273540
申请日：2002-10-18
Applicant: Ying Hung So , Keith J. Watson , Scott J. Bis
Inventor： Ying Hung So , Keith J. Watson , Scott J. Bis
Abstract: The invention is a photoswitchable benzocyclobutene-based polymer that while remaining aqueous developable, avoids the problem of significant moisture uptake. The oligomer or polymer comprises a polymeric backbone, benzocyclobutene reactive groups, and photoswitchable pendant groups. The pendant groups are bonded to the polymeric backbone and are characterized by the presence of a moiety that converts to carboxylic acid upon exposure to activating wavelengths of radiation a carboxylic acid. When the oligomer or polymer is subsequently heated to cause cure of the oligomer or polymer, carbon dioxide is emitted and the group forms a substantially non-polar moiety. The invention is also a method of making such a polymer and a method of forming a patterned film using such a polymer.
Abstract translation: 本发明是一种可光切换的基于苯并环丁烯的聚合物，其在保持水可显影的同时，避免了显着吸湿的问题。 低聚物或聚合物包含聚合物主链，苯并环丁烯反应性基团和可照照开关的侧基。 侧基键合到聚合物骨架上，其特征在于存在一个部分，当暴露于活化的辐射波长的羧酸时，该部分转变成羧酸。 当低聚物或聚合物随后被加热以使低聚物或聚合物固化时，发出二氧化碳，并且该基团形成基本上非极性部分。 本发明也是制造这种聚合物的方法和使用这种聚合物形成图案化膜的方法。
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5.发明授权Toughened benzocyclobutene based polymers and their use in building-up printed wiring boards 失效增韧的苯并环丁烯聚合物及其在建立印刷电路板中的应用公开(公告)号：US06420093B1
公开(公告)日：2002-07-16
申请号：US09496495
申请日：2000-02-02
Applicant: Kaoru Ohba , Brian Martin , Hideki Akimoto , Albert Charles Marie Achen , Philip E. Garrou , Britton Lee Kaliszewski , Ying-Hung So
Inventor： Kaoru Ohba , Brian Martin , Hideki Akimoto , Albert Charles Marie Achen , Philip E. Garrou , Britton Lee Kaliszewski , Ying-Hung So
IPC: G03F700
CPC classification number: H05K3/4655 , C08G61/02 , H05K3/4652 , H05K2201/0158 , H05K2201/0358
Abstract: The invention is a process for building-up printed wiring boards using metal foil coated with toughened benzocyclobutene-based dielectric polymers. The invention is also a toughened dielectric polymer comprising benzocyclobutene-based monomers or oligomers, ethylenically unsaturated polymer additive, and, optionally, a photoactive compound.
Abstract translation: 本发明是使用镀有苯乙烯类韧性介电聚合物的金属箔来构建印刷线路板的方法。 本发明还是包含苯并环丁烯类单体或低聚物，烯属不饱和聚合物添加剂和任选的光活性化合物的增韧介电聚合物。
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Patent Agency Ranking
公开(公告)号：US4495036A
公开(公告)日：1985-01-22
申请号：US512263
申请日：1983-07-11
Applicant: Ying-Hung So
Inventor： Ying-Hung So
CPC classification number: C25B3/06
Abstract: Electrolytically prepare para-chloroalkyl aromatic compounds, such as para-chlorotoluene, using a potential of less than 1.5 volts, as measured against a Ag/Ag.sup.+ reference electrode, and an anode which is free of cyclodextrin.
Abstract translation: 使用相对于Ag / Ag +参比电极测量的电压低于1.5伏的电极，以及不含环糊精的阳极，电解制备对氯烷基芳族化合物，如对氯甲苯。
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7.发明授权Benzocyclobutene based polymer formulations and methods for processing such formulations in oxidative environments 有权基于苯并环丁烯的聚合物配方和在氧化环境中处理这些制剂的方法公开(公告)号：US08143324B2
公开(公告)日：2012-03-27
申请号：US11665245
申请日：2005-10-12
Applicant: Ying Hung So , Edmund J. Stark , Jack E. Hetzner , Shellene K. Thurston
Inventor： Ying Hung So , Edmund J. Stark , Jack E. Hetzner , Shellene K. Thurston
CPC classification number: G03F7/0233 , C08K5/13 , G03F7/0085 , G03F7/0125 , G03F7/038 , C08L65/00
Abstract: The use of hindered phenol containing anti-oxidants enable arylcyclobutene-based formulations to be cured in oxygen containing environments such as air without unacceptable degradation in key properties of dielectric constant, water uptake, or transmittance.
Abstract translation: 使用含有受阻酚的抗氧化剂使得基于芳基环丁烷的制剂能够在含氧环境例如空气中固化，而在介电常数，吸水率或透光率的关键性质方面不会有不可接受的降解。
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8.发明申请Aqueous developable benzocyclobutene-based polymer composition and method of use of such compositions 有权水性可显影的苯并环丁烯类聚合物组合物及其组合物的使用方法公开(公告)号：US20090075205A1
公开(公告)日：2009-03-19
申请号：US11665246
申请日：2005-10-12
Applicant: Ying Hung So , Edmund J. Stark , Shellene K. Thurston , Kayla J. Gallant (nee Baranck) , Yongfu Li
Inventor： Ying Hung So , Edmund J. Stark , Shellene K. Thurston , Kayla J. Gallant (nee Baranck) , Yongfu Li
CPC classification number: C08K5/23 , C08K5/42 , G03F7/0226 , G03F7/0233 , G03F7/075 , G03F7/40 , C08L45/00
Abstract: The invention is a composition comprising a curable arylcyclobutene based oligomer or polymer and a dissolution inhibitor which comprises a compound comprising at least two diazonaphthoquinone (DNQ) moieties each of which is pendant from different phenyl groups.
Abstract translation: 本发明是一种包含可固化的芳族环烯基低聚物或聚合物和一种溶解抑制剂的组合物，其包含包含至少两个重氮萘醌（DNQ）部分的化合物，每个重氮萘醌（DNQ）部分是不同苯基的侧链。
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公开(公告)号：US06727038B1
公开(公告)日：2004-04-27
申请号：US09910130
申请日：2001-07-20
Applicant: Ying Hung So , Cheryl L. Murlick , Daniel M. Scheck , Gregory S. Becker , Eric S. Moyer
Inventor： Ying Hung So , Cheryl L. Murlick , Daniel M. Scheck , Gregory S. Becker , Eric S. Moyer
IPC: G03C176
CPC classification number: G03F7/008 , G03F7/0755 , Y10S430/12 , Y10S430/124
Abstract: A photodefineable mixture comprising oligomeric divinyltetramethyldisiloxane bisbenzocyclobutene as its major resin component dissolved in mesitylene and at least 2,6-bis(4-azidobenzylidene)-4-ethylcyclohexanone as a photosensitive agent in an amount sufficient to convert the mixture to an organic-insoluble solid upon exposing the mixture to photon radiation is disclosed. These polymer compositions are useful as thin film dielectrics in electronic applications such as multichip modules, integrated circuits and printed circuit boards.
Abstract translation: 一种光可定义的混合物，其包含低聚二乙烯基四甲基二硅氧烷双苯并环丁烯作为其主要的树脂组分溶解在均三甲苯中，至少2,6-双（4-叠氮基亚苄基）-4-乙基环己酮作为感光剂，其用量足以将混合物转化为有机不溶性固体 公开了将混合物暴露于光子辐射时。 这些聚合物组合物可用作诸如多芯片模块，集成电路和印刷电路板的电子应用中的薄膜电介质。
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10.发明授权公开(公告)号：US06670101B2
公开(公告)日：2003-12-30
申请号：US10043839
申请日：2002-01-10
Applicant: Kaoru Ohba , Hideki Akimoto , Philip E. Garrou , Ying-Hung So , Britton Lee Kaliszewski
Inventor： Kaoru Ohba , Hideki Akimoto , Philip E. Garrou , Ying-Hung So , Britton Lee Kaliszewski
IPC: G03C500
CPC classification number: H05K3/4655 , C08G61/02 , H05K3/4652 , H05K2201/0158 , H05K2201/0358
Abstract: The invention is a process for building-up printed wiring boards using metal foil coated with toughened benzocyclobutene-based dielectric polymers. The invention is also a toughened dielectric polymer comprising benzocyclobutene-based monomers or oligomers, ethylenically unsaturated polymer additive, and, optionally, a photoactive compound.
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