摘要:
An electric conductive polymer suspension is produced by performing chemical oxidative polymerization of a monomer for providing an electric conductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant to form an electric conductive polymer, recovering the electric conductive polymer, allowing an oxidant to act on the electric conductive polymer in an aqueous solvent containing a polyacid, and further mixing a dispersant with a branched structure and then pulverizing the electric conductive polymer. According to the electric conductive polymer suspension, an organic material high in conductivity, and excellent in adhesiveness to a substrate and water resistance, and a method for producing the material, as well as an electrolytic capacitor and a method for producing the capacitor can be provided.
摘要:
An electric conductive polymer suspension is produced by performing chemical oxidative polymerization of a monomer for providing an electric conductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant to form an electric conductive polymer, recovering the electric conductive polymer, allowing an oxidant to act on the electric conductive polymer in an aqueous solvent containing a polyacid, and further mixing a dispersant with a branched structure and then pulverizing the electric conductive polymer. According to the electric conductive polymer suspension, an organic material high in conductivity, and excellent in adhesiveness to a substrate and water resistance, and a method for producing the material, as well as an electrolytic capacitor and a method for producing the capacitor can be provided.
摘要:
An electric conductive polymer aqueous suspension is prepared by dispersing an electric conductive polymer powder whose surface is doped with a polyacid in which the number of anion groups is 50% or more and 99% or less with respect to the number of repeating units of the polyacid. By using the electric conductive polymer aqueous suspension, an organic material excellent in adhesiveness to a substrate and humidity resistance, and high in conductivity, as well as a solid electrolytic capacitor low in ESR and excellent in reliability in a high humidity atmosphere, and a method for producing the same can be provided.
摘要:
A conductive polymer composition with excellent water resistance and conductivity, and a solid electrolytic capacitor with low ESR, excellent reliability, and especially moisture resistance. The conductive polymer composition includes a conductive polymer, a polyanion that includes a hydrophilic group, where the polyanion functioning as a dopant of the conductive polymer. At least a part of the hydrophilic group of the polyanion is condensed with an epoxy group in a compound with one epoxy group. A solid electrolytic capacitor of the present invention includes the conductive polymer composition.
摘要:
Provided are an electroconductive polymer suspension solution and a method for producing the same, which has excellent adhesion to a substrate and excellent liquid resistance and which can provide an organic material having high electroconductivity. An electroconductive polymer suspension solution of an exemplary embodiment of the invention contains an electroconductive polymer, at least one kind of a water-soluble polyhydric alcohol, and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol. The electroconductive polymer suspension solution can be produced by collecting an electroconductive polymer which is obtained by chemical oxidative polymerization of a monomer giving the electroconductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant, by contacting the electroconductive polymer with an oxidant in an aqueous solvent containing a polyacid, and further by mixing at least one kind of a water-soluble polyhydric alcohol and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol.
摘要:
A method for manufacturing a solid electrolytic capacitor has the steps of: mixing valve metal powders with organic binder for granulation, press-molding granulated powders embedded with a valve metal lead, sintering a press-molded compact in vacuum to produce a sintered body, and anodizing the sintered body to form a dielectric oxide film layer. The method further has a step of performing a cathode electrolytic cleaning to the sintered body before the step of forming the dielectric oxide film layer. The cathode electrolytic cleaning is performed in an acid solution, which is a mixed acid solution of hydrofluoric acid, nitric acid, and sulfuric acid.
摘要:
A conductive polymer having high conductivity and a solid electrolytic capacitor having low ESR are provided. A conductive polymer is synthesized using as a monomer a compound of a dimer to a decamer in which 3-alkyl five-membered heterocyclic rings are bonded at positions 2 and 5, being sterically controlled. Further, this conductive polymer is used as the solid electrolyte of a solid electrolytic capacitor.
摘要:
The present invention provides a conductive polymer suspension for providing a conductive polymer material having high conductivity and a method for producing the same, and particularly provides a solid electrolytic capacitor having low ESR and a method for producing the same. In an emulsion comprising a dopant of a low molecular organic acid or a salt thereof, obtained by emulsifying a monomer providing a conductive polymer, using a nonionic surfactant, in a water, the monomer is subjected to chemical oxidative polymerization, using an oxidant, to synthesize a conductive polymer. The obtained conductive polymer is purified, and then, the purified conductive polymer and an oxidant are mixed in an aqueous solvent containing a polyacid component to produce a conductive polymer suspension.
摘要:
The present invention provides a conductive polymer suspension for providing a conductive polymer material having high conductivity and a method for producing the same, and particularly provides a solid electrolytic capacitor having low ESR and a method for producing the same. In an emulsion comprising a dopant of a low molecular organic acid or a salt thereof, obtained by emulsifying a monomer providing a conductive polymer, using a nonionic surfactant, in a water, the monomer is subjected to chemical oxidative polymerization, using an oxidant, to synthesize a conductive polymer. The obtained conductive polymer is purified, and then, the purified conductive polymer and an oxidant are mixed in an aqueous solvent containing a polyacid component to produce a conductive polymer suspension.
摘要:
Provided are a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension is produced as follows: a conductive polymer is synthesized by chemical oxidative polymerization of a monomer giving a conductive polymer by using an oxidant in a solvent containing a dopant consisting of polysulfonic acid or a salt thereof; the conductive polymer is purified; and the purified conductive polymer is mixed with an oxidant in an aqueous solvent containing a polyacid component.