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    Protein hydrolyzate compositions for fire fighting containing perfluoroalkyl sulfide terminated oligomers
    2.
    发明授权
    Protein hydrolyzate compositions for fire fighting containing perfluoroalkyl sulfide terminated oligomers 失效
    用于消防的蛋白质水解物组合物，其含有全氟烷基硫化物封端的低聚物

    公开(公告)号：US4460480A

    公开(公告)日：1984-07-17

    申请号：US129872

    申请日：1980-03-13

    Applicant: Eduard K. Kleiner ,  Thomas W. Cooke ,  Robert A. Falk

    Inventor： Eduard K. Kleiner ,  Thomas W. Cooke ,  Robert A. Falk

    IPC: A62D1/02 ,  B01F17/00 ,  C08F2/38 ,  C11D1/00 ,  A62D1/00 ,  C07D211/70 ,  C07D211/82 ,  C07D213/56

    CPC classification number: C11D1/004 ,  A62D1/0085 ,  B01F17/0057 ,  C08F2/38

    Abstract: The present invention relates to novel oligomers of the formula R.sub.f --E--S--M.sub.1 ].sub.x [M.sub.2 ].sub.y H, and mixutes thereof, wherein R.sub.f is a perfluoroalkyl group, E is a linkage group, --M.sub.1 -- represents a hydrophilic monomer unit, --M.sub.2 -- represents a hydrophobic monomer unit, x and y represent the number of monomer units present in the novel oligomers. The sum of x and y is between 4 and 500 and x/(x+y) is between 1 and 0.5. The novel oligomers are useful as additives in protein foam type fire fighting compositions improving foam expansion, foam drainage and extinguishing times and reducing flammability of hydrocarbon contaminated protein foams. The novel oligomers are further useful as surface tension depressants providing improved wetting, spreading and leveling properties in aqueous systems.

    Abstract translation: 本发明涉及式Rf-ES-M1] x [M2] yH的新型低聚物及其混合物，其中Rf为全氟烷基，E为连接基，-M1-表示亲水性单体单元， M2-表示疏水单体单元，x和y表示存在于新型低聚物中的单体单元的数目。 x和y之和在4和500之间，x /（x + y）在1和0.5之间。 新型低聚物可用作蛋白质泡沫型消防组合物中的添加剂，其改善泡沫膨胀，泡沫排放和灭火时间并降低碳氢化合物污染的蛋白质泡沫的可燃性。 新型低聚物还可用作表面张力抑制剂，其在水性体系中提供改善的润湿，铺展和流平性能。

    Perfluoroalkyl phenols and naphthols
    3.
    发明授权
    Perfluoroalkyl phenols and naphthols 失效
    全氟烷基酚和萘酚

    公开(公告)号：US4429162A

    公开(公告)日：1984-01-31

    申请号：US344681

    申请日：1982-02-01

    Applicant: Thomas W. Cooke ,  Robert A. Falk

    Inventor： Thomas W. Cooke ,  Robert A. Falk

    IPC: C09K3/18 ,  B01F17/00 ,  C07C67/00 ,  C07C209/00 ,  C07C211/62 ,  C07C211/63 ,  C07C211/64 ,  C07C213/00 ,  C07C215/40 ,  C07C313/00 ,  C07C315/02 ,  C07C317/00 ,  C07C317/22 ,  C07C323/16 ,  D06M13/156 ,  D06M13/248 ,  D06M13/265 ,  D21H17/09 ,  D21H17/11 ,  C07C149/36 ,  C07C149/42

    CPC classification number: D21H17/11 ,  B01F17/0057 ,  C07C317/00 ,  C07C323/00 ,  D06M13/265 ,  D21H17/09

    Abstract: The instant invention relates to compounds of the formula ##STR1## wherein each R.sub.f is independently straight or branched chain perfluoroalkyl of 2 to 18 carbon atoms or perfluoroalkoxy-perfluoroalkyl of 4 to 18 carbon atoms;each R.sub.1 is independently straight or branched chain alkylene of 1 to 12 carbon atoms, alkylenethioalkylene of 2 to 12 carbon atoms, alkyleneoxyalkylene of 2 to 12 carbon atoms, or alkyleneiminoalkylene of 2 to 12 carbon atoms where the imino nitrogen atom contains as a third substituent, hydrogen or alkyl of 1 to 6 carbon atoms;R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, chloro, bromo, alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, hydroxyalkyl of 1 to 6 carbon atoms or alkoxy of 1 to 6 carbon atoms, and R.sub.2 and R.sub.3 additionally may, together with the carbon atoms to which they are attached, form a fused benzo ring;R.sub.5 is hydrogen, or alkyl of 1 to 6 carbon atoms which is unsubstituted or substituted by hydroxy, alkoxy of 1 to 6 carbon atoms or phenyl;x is 0, 1 or 2; and the alkali metal, alkaline earth metal, ammonium or amine salt thereof. These compounds are useful as surfactants, water repellents and intermediates.

    Abstract translation: 本发明涉及下式化合物：其中每个Rf独立地为2至18个碳原子的直链或支链全氟烷基或4至18个碳原子的全氟烷氧基 - 全氟烷基; 每个R 1独立地为具有1至12个碳原子的直链或支链亚烷基，2至12个碳原子的亚烷基亚硫酰基亚烷基，2至12个碳原子的亚烷基亚烷基氧基或2至12个碳原子的亚烷基亚氨基亚烷基，其中亚氨基氮原子含有第三个取代基 ，氢或1至6个碳原子的烷基; R2，R3和R4独立地是氢，氯，溴，1-6个碳原子的烷基，2-6个碳原子的烯基，1-6个碳原子的羟基烷基或1-6个碳原子的烷氧基，R2和R3另外 可以与它们所连接的碳原子一起形成稠合的苯并环; R5是氢或未取代或被羟基，1至6个碳原子的烷氧基或苯基取代的1至6个碳原子的烷基; x是0,1或2; 及其碱金属，碱土金属，铵或胺盐。 这些化合物可用作表面活性剂，防水剂和中间体。

    Fluoroaliphatic-thio,-sulfinyl, or sulfonyl substituted bicycloaliphatic amic acid amine salts, and compositions and use thereof
    5.
    发明授权
    Fluoroaliphatic-thio,-sulfinyl, or sulfonyl substituted bicycloaliphatic amic acid amine salts, and compositions and use thereof 失效
    氟脂族硫代，亚磺酰基或磺酰基取代的双环脂肪族酰胺胺盐，及其组合物和用途

    公开(公告)号：US4515640A

    公开(公告)日：1985-05-07

    申请号：US503435

    申请日：1983-06-13

    Applicant: Jurgen Kaschig ,  Eduard K. Kleiner ,  Karl F. Mueller ,  Thomas W. Cooke

    Inventor： Jurgen Kaschig ,  Eduard K. Kleiner ,  Karl F. Mueller ,  Thomas W. Cooke

    IPC: C07C67/00 ,  C07C209/00 ,  C07C211/63 ,  C07C213/00 ,  C07C215/40 ,  C07C313/00 ,  C07C317/44 ,  C07C323/61 ,  C07D307/77 ,  C07D307/93 ,  D21H17/14 ,  C09K3/00 ,  C08K5/35

    CPC classification number: C07D307/77 ,  C07D307/93

    Abstract: Fluoroaliphatic-thio,-sulfinyl and -sulfonyl substituted bicycloaliphatic amic acid amine salts of the formula: ##STR1## where R.sub.f is perfluoroalkyl, R' is alkylene optionally interrupted by --O--, --S-- or ##STR2## where R.sub.a is hydrogen or alkyl, Y is lower alkylene or --O--, n is 0-2, R.sub.1 and R.sub.2 are independently hydrogen, lower alkyl, hydroxy lower alkyl or together with the nitrogen to which they are attached, represented morpholino, R.sub.3, R.sub.4 and R.sub.5 are independently hydrogen, lower alkyl, or hydroxy lower alkyl, R.sub.6 is lower alkyl, carboxy lower alkyl, sulfo lower alkyl, hydroxy lower alkyl, benzyl or together with R.sub.5 and the nitrogen to which they are attached represent morpholino, and R is hydrogen or methyl are provided. These salts applied in the form of aqueous solutions, dispersions or emulsions are useful in rendering cellulosic and natural and synthetic polyamide materials oil and water repellent.

    Abstract translation: 氟化脂肪族 - 硫代 - 亚磺酰基和 - 磺酰基取代的双环脂肪族酰胺酸胺，其结构式如下：其中Rf是全氟烷基，R'是任选地被-O-，-S-或者其中R a 是氢或烷基，Y是低级亚烷基或-O-，n是0-2，R1和R2独立地是氢，低级烷基，羟基低级烷基或与它们相连的氮一起代表吗啉代，R3，R4 R 5为低级烷基，羧基低级烷基，磺基低级烷基，羟基低级烷基，苄基或与R 5一起并且与它们相连的氮表示吗啉代，R为 提供氢或甲基。 以水溶液，分散体或乳液的形式施用的这些盐可用于使纤维素和天然和合成的聚酰胺材料具有防油和防水性能。

    Method of processing textile products utilizing decomposable emulsifiers
    6.
    发明授权
    Method of processing textile products utilizing decomposable emulsifiers 失效
    使用可分解乳化剂处理纺织品的方法

    公开(公告)号：US6110231A

    公开(公告)日：2000-08-29

    申请号：US88254

    申请日：1998-06-01

    Applicant: Thomas W. Cooke

    Inventor： Thomas W. Cooke

    IPC: D06M13/02 ,  D06M13/402 ,  D06M13/46 ,  D06M15/227 ,  D06M15/643 ,  D06M13/137 ,  D06P5/00

    CPC classification number: D06M15/643 ,  D06M13/02 ,  D06M13/402 ,  D06M13/46 ,  D06M15/227 ,  D06M7/00 ,  D06M2200/40

    Abstract: A method of applying a surface coating to an intermediate textile product to enhance the performance of the textile product in a downstream manufacturing process. The method includes the steps of preparing an application composition having a process-enhancing material, an acid-decomposable emulsifier and an acid; emulsifying the application composition in a water bath to improve the surface activity of the process-enhancing material; exposing the intermediate textile product to the water bath containing the application composition; and decomposing the emulsifier into non-surface active substances simultaneously with the step of applying the application composition to the intermediate textile product to thereby permit the process-enhancing material to exhaust onto the textile product.

    Abstract translation: 将表面涂层施加到中间纺织品以提高下游制造工艺中纺织品的性能的方法。 该方法包括制备具有加工增强材料，酸分解乳化剂和酸的应用组合物的步骤; 在水浴中乳化施用组合物以改善加工增强材料的表面活性; 将中间纺织产品暴露于含有施用组合物的水浴中; 并且将施用组合物施用于中间纺织品的步骤同时将乳化剂分解为非表面活性物质，从而允许加工增强材料排出到纺织品上。

    Use of alkyl glycosides for dust suppression
    7.
    发明授权
    Use of alkyl glycosides for dust suppression 失效
    使用烷基糖苷进行粉尘抑制

    公开(公告)号：US5223165A

    公开(公告)日：1993-06-29

    申请号：US965987

    申请日：1992-10-22

    Applicant: Richard A. Winstanley ,  Michael W. Swartzlander ,  Thomas W. Cooke

    Inventor： Richard A. Winstanley ,  Michael W. Swartzlander ,  Thomas W. Cooke

    IPC: C07H15/04 ,  C09K3/22

    CPC classification number: C07H15/04 ,  C09K3/22

    Abstract: A method of suppressing the generation or persistence of dust is provided. An aqueous composition of a higher alkyl glycoside is placed in contact with a friable solid material (e.g. coal) to suppress the generation of dust thereform. The alkyl glycoside is generally present in the aqueous composition at a level of from about 0.001% by weight to about 1% by weight of the aqueous composition. Because of the nature of this particular use, highly colored compositions can be employed in the method. A composition used as a dust suppressant comprised of a higher alkyl glycoside and a hydrophilic binder material is also provided.

    Abstract translation: 提供了抑制灰尘的产生或持续的方法。 将高级烷基糖苷的水性组合物与易碎的固体材料（例如煤）接触以抑制灰尘的产生。 烷基糖苷通常以含水组合物的约0.001重量％至约1重量％的含量存在于水性组合物中。 由于这种特殊用途的性质，可以在该方法中使用高度着色的组合物。 还提供了用作由高级烷基糖苷和亲水性粘合剂材料构成的抑尘剂的组合物。

    Fluorochemical non-ionic surfactants
    9.
    发明授权
    Fluorochemical non-ionic surfactants 失效
    含氟化学非离子表面活性剂

    公开(公告)号：US4310698A

    公开(公告)日：1982-01-12

    申请号：US166275

    申请日：1980-07-07

    Applicant: Thomas W. Cooke

    Inventor： Thomas W. Cooke

    IPC: B01F17/00 ,  C11D1/00 ,  C11D1/722 ,  C07C149/18

    CPC classification number: C11D1/004 ,  B01F17/0057 ,  C07C323/00 ,  Y10S516/02

    Abstract: Fluorochemical surfactants of the formula ##STR1## wherein R.sub.f is perfluoroalkyl of 4-20 carbon atoms or perfluoroalkoxyperfluoroalkyl of 4-20 carbon atoms;A is straight or branched chain alkylene of 1-10 carbon atoms which is unsubstituted or substituted by halo;n is 1 to 50;R.sub.1 is hydrogen or alkyl of 1-4 carbon atoms and R.sub.2 is hydrogen or alkyl of 1-4 carbon atoms.

    Abstract translation: 其中R f为4-20个碳原子的全氟烷基或4-20个碳原子的全氟烷氧基全氟烷基; A是未被取代或被卤素取代的1-10个碳原子的直链或支链亚烷基; n为1〜50; R1是氢或1-4个碳原子的烷基，R2是氢或1-4个碳原子的烷基。

    UV light absorber composition and method of improving the lightfastness of dyed textiles
    10.
    发明授权
    UV light absorber composition and method of improving the lightfastness of dyed textiles 失效
    UV光吸收剂组合物和改善染色纺织品耐光性的方法

    公开(公告)号：US06391065B1

    公开(公告)日：2002-05-21

    申请号：US08553072

    申请日：1995-11-03

    Applicant: Thomas W. Cooke

    Inventor： Thomas W. Cooke

    IPC: D06P502

    CPC classification number: D06P5/06 ,  D06P1/0024 ,  D06P1/16 ,  D06P1/6133 ,  D06P1/6426 ,  D06P1/645 ,  D06P1/65112 ,  D06P1/928 ,  D06P3/54

    Abstract: A water-dilutable UV light absorber composition and method for improving the lightfastness of dyed textiles is provided. The composition includes from about 5-75% by weight of an ultraviolet light absorbing agent selected from the group consisting of benzotriazole, benzophenone, and phenol substituted triazine; and from about 25-95% by weight of an organic solvent suitable for dissolving the ultraviolet light absorbing agent. The ultraviolet light absorbing agent is applied to the textiles in a concentration sufficient to result in an add-on in the range of between 0.4-4.0% by weight of the textiles when dry.

    Abstract translation: 提供了一种水可稀释紫外光吸收剂组合物和改善染色纺织品耐光性的方法。 所述组合物包含约5-75重量％的选自苯并三唑，二苯甲酮和苯酚取代的三嗪的紫外光吸收剂; 和约25-95重量％的适用于溶解紫外光吸收剂的有机溶剂。 将紫外光吸收剂以足以导致在干燥时纺织品的重量的0.4-4.0％的范围内的添加剂施加到织物上。

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