公开(公告)号：US10829631B2

公开(公告)日：2020-11-10

申请号：US16458464

申请日：2019-07-01

Applicant: Takao Hiraoka ,  Mitsunobu Morita ,  Takashi Okada ,  Soh Noguchi ,  Tatsuki Yamaguchi ,  Masahide Kobayashi ,  Takenori Suenaga

Inventor： Takao Hiraoka ,  Mitsunobu Morita ,  Takashi Okada ,  Soh Noguchi ,  Tatsuki Yamaguchi ,  Masahide Kobayashi ,  Takenori Suenaga

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08L33/26 ,  C08K5/00 ,  C09D11/38 ,  C08K5/3462 ,  B41J11/00

Abstract: A composition contains an acrylamide compound A1 having an ester structure and a polymerization initiator B1 having a molecular weight of 800 or more.

公开(公告)号：US10829575B2

公开(公告)日：2020-11-10

申请号：US15311231

申请日：2015-06-01

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: C08F220/18 ,  C09D11/101 ,  C09D11/30 ,  C08F2/48 ,  C08F265/06 ,  C08F257/02 ,  C09D4/00

Abstract: A photopolymerizable composition, which contains: a monofunctional monomer having a viscosity of 5 mPa·s or less at 25° C.; one or more polyfunctional monomers including glycerol dimethacrylate; and a polymer free from a hydrophilic functional group, wherein a mass ratio (A/B) of an amount (A) of the polymer free from a hydrophilic functional group to an amount (B) of the polyfunctional monomer is greater than 0.80 but 3 or less.

公开(公告)号：US09777095B2

公开(公告)日：2017-10-03

申请号：US15186003

申请日：2016-06-17

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: C09D11/101 ,  C08F222/10 ,  C09D11/30 ,  C09D11/322 ,  C09D133/14

CPC classification number: C08F222/1006 ,  C08F2222/1013 ,  C09D11/101 ,  C09D11/30 ,  C09D11/322 ,  C09D133/14

Abstract: A photopolymerizable composition, which includes a photoradical polymerization initiator and photopolymerizable monomers containing glycerol dimethacrylate, where an amount of the glycerol dimethacrylate in the photopolymerizable monomers is 25% by mass or greater, and pencil hardness of a cured product is F or harder, where the cured product is formed by curing a coating film through irradiation with light of a wavelength region corresponding to a UVA region, with a light to dose of 800 mJ/cm2, where the coating film is formed by coating the photopolymerizable composition on a base so as to have an average thickness of 30 μm.

公开(公告)号：US09644104B2

公开(公告)日：2017-05-09

申请号：US14492208

申请日：2014-09-22

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: C09D11/101 ,  C08F2/50 ,  C09D11/38

CPC classification number: C09D11/101 ,  C08F2/50 ,  C09D11/38

Abstract: A photopolymerizable composition contains diethylene glycol dimethacrylate, b1, b2, and b3, wherein the content of b2 is less than 2.5% by weight, the content of b3 is less than 3% by weight. b1 is 1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propane-1-on, b2 is 2-hydroxy-1-{4-[4-(2-hydroxy-2-methyl-propionyl)benzyl]phenyl}-2-methyl-1-propane-1-on, and b3 is oligo{2-hydroxy-2-methyl-1-[4-(1-methylvinyl)phenyl]propanone}.

公开(公告)号：US09546288B2

公开(公告)日：2017-01-17

申请号：US15207292

申请日：2016-07-11

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: C09D183/06 ,  C09D11/101 ,  C09D11/107 ,  C09D11/30 ,  B05D3/06

CPC classification number: C09D11/101 ,  B05D3/067 ,  C08G77/16 ,  C08G77/20 ,  C09D4/06 ,  C09D11/107 ,  C09D11/30 ,  C09D11/38 ,  C09D133/06 ,  C09D133/14 ,  C09D183/04 ,  C09D183/06 ,  C08L83/04 ,  C08F290/068

Abstract: A radical polymerizable composition includes a siloxane compound represented by a formula (HO)2(R)Si.O[—Si(R)(OH).O-]n-Si(R)(OH)2 in which R represents a methacryloyl group; and n represents 0 or 1; and a monomer having a viscosity lower than that of the siloxane compound. The composition is preferably cured with UV light from an LED.

Abstract translation: 可自由基聚合的组合物包括由式（HO）2（R）Si.O [-Si（R）（OH）·O - ] n-Si（R）（OH）2表示的硅氧烷化合物，其中R表示 甲基丙烯酰基 n表示0或1; 和具有比硅氧烷化合物低的粘度的单体。 组合物优选用来自LED的UV光固化。

公开(公告)号：US09434847B2

公开(公告)日：2016-09-06

申请号：US14225696

申请日：2014-03-26

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: C09D11/10 ,  C09D11/30 ,  G03F7/033 ,  C09D11/101

CPC classification number: C08F220/68 ,  C09D11/101 ,  C09D11/30 ,  C09D133/14 ,  G03F7/033

Abstract: A photopolymerizable composition includes diethyleneglycoldimethacrylate and alkoxy-modified (meth)acrylic acid ester having an n not less than 9. The n is an average polymerization degree of an alkoxy part of the (meth)acrylic acid ester.

Abstract translation: 光聚合性组合物包括二甘醇二甲基丙烯酸酯和n不小于9的烷氧基改性（甲基）丙烯酸酯.n是（甲基）丙烯酸酯的烷氧基部分的平均聚合度。

公开(公告)号：US09109136B2

公开(公告)日：2015-08-18

申请号：US14117236

申请日：2012-05-10

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: B41J2/15 ,  C09D133/10 ,  B41J2/155 ,  C09D11/101 ,  C09D11/30 ,  B41J2/14 ,  B41J2/175 ,  C09D129/10

Abstract: A photopolymerizable inkjet ink including: at least one selected from the group consisting of (meth)acrylic acid esters negative for skin sensitization and (meth)acrylamides negative for skin sensitization; and at least one selected from the group consisting of vinyl ethers negative for skin sensitization, t-butyl methacrylate negative for skin sensitization, n-pentyl methacrylate negative for skin sensitization, and n-hexyl methacrylate negative for skin sensitization.

公开(公告)号：US09068094B2

公开(公告)日：2015-06-30

申请号：US14118405

申请日：2012-05-10

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: B41J2/175 ,  C09D11/38 ,  B41J11/00 ,  B41J2/21 ,  C09D11/101

CPC classification number: C09D11/30 ,  B41J2/17503 ,  B41J2/2107 ,  B41J11/0015 ,  C09D11/101 ,  C09D11/38

Abstract: A photopolymerizable inkjet ink including: a photopolymerizable monomer having a Stimulation Index (SI value) of less than 3, where the Stimulation Index indicates the extent of sensitization as measured by a skin sensitization test based on Local Lymph Node Assay; and a phenol aromatic compound having two hydroxyl groups in the molecule thereof.

Abstract translation: 一种可光聚合喷墨油墨，其包含：具有小于3的刺激指数（SI值）的光聚合性单体，其中刺激指数表示通过基于局部淋巴结测定法的皮肤致敏试验测定的敏化程度; 和在其分子中具有两个羟基的苯酚芳香族化合物。

公开(公告)号：US20150126636A1

公开(公告)日：2015-05-07

申请号：US14397998

申请日：2013-05-17

Applicant: Takao HIRAOKA

Inventor： Takao Hiraoka

IPC: C09D11/30 ,  C09D133/14

CPC classification number: C08F222/1006 ,  C08F2222/1013 ,  C09D11/101 ,  C09D11/30 ,  C09D11/322 ,  C09D133/14

Abstract: To provide a photopolymerizable composition, which includes photopolymerizable monomers containing glycerol dimethacrylate, caprolactone-modified dipentaerythritol hexaacrylate, and diethylene glycol dimethacrylate, wherein an amount of the glycerol dimethacrylate in the photopolymerizable monomers is 25% by mass or greater.

Abstract translation: 为了提供可光聚合组合物，其包括含有二甲基丙烯酸甘油酯，己内酯改性二季戊四醇六丙烯酸酯和二甘醇二甲基丙烯酸酯的光聚合单体，其中可光聚合单体中二甲基丙烯酸甘油酯的量为25质量％以上。

公开(公告)号：US20150042731A1

公开(公告)日：2015-02-12

申请号：US14376091

申请日：2013-02-27

Applicant: Takao Hiraoka

Inventor： Takao Hiraoka

IPC: C09D11/30 ,  C09D11/101 ,  B41J2/175

CPC classification number: C09D11/30 ,  B41J2/17503 ,  B41J2/2107 ,  C09D11/101

Abstract: A non-aqueous photopolymerizable inkjet ink, including as a photopolymerizable monomer: (a) ethylene glycol dimethacrylate; and (b) caprolactone-modified dipentaerythritol hexaacrylate or ethylene oxide-modified trimethylolpropane tri-methacrylate, or both thereof, wherein the ink includes the (a) component by 10% by mass to 95% by mass with respect to the entire photopolymerizable monomer, and the ink includes the (b) component by 5% by mass to 90% by mass with respect to the entire photopolymerizable monomer, and wherein the ink does not include a diluting solvent.

Abstract translation: 一种非水可光聚合喷墨油墨，包括作为光聚合单体：（a）乙二醇二甲基丙烯酸酯; 和（b）己内酯改性的二季戊四醇六丙烯酸酯或环氧乙烷改性的三羟甲基丙烷三甲基丙烯酸酯，或其二者，其中，油墨包含（a）成分相对于整个光聚合性单体为10质量％至95质量％ 并且所述油墨包含（b）成分相对于整个光聚合性单体为5质量％至90质量％，并且其中所述油墨不包括稀释溶剂。