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1.发明授权Graft copolymer, method for preparing the same and thermoplastic resin composition containing the same 有权接枝共聚物，其制备方法和含有该共聚物的热塑性树脂组合物公开(公告)号：US08129469B2
公开(公告)日：2012-03-06
申请号：US11255472
申请日：2005-10-21
Applicant: Hyun-taek O , Tae-bin Ahn , Jung-tae Park , Min-jung Kim , Keun-hoon Yoo
Inventor： Hyun-taek O , Tae-bin Ahn , Jung-tae Park , Min-jung Kim , Keun-hoon Yoo
IPC: C08G63/48 , C08G63/91 , C08F267/06 , C08F255/04 , C08L9/00 , C08L47/00 , C08L51/04 , C08L53/00
CPC classification number: C08L51/04 , C08F257/02 , C08F265/04 , C08F279/02 , C08F279/04 , C08L9/00 , C08L25/06 , C08L25/12 , C08L33/08 , C08L51/003 , C08L53/00 , C08L55/02 , C08L2207/53 , C08L2666/24 , C08L2666/02 , C08L2666/04
Abstract: The present invention relates to a graft copolymer, a method for preparing the same and a thermoplastic resin composition comprising the same. The graft copolymer of the present invention comprises a composite rubber polymer (A-1) having an average particle diameter of 250-600 nm prepared by particle enlargement after mixing a diene rubber polymer (a-1) latex having an average particle diameter of 50-150 nm and a core-shell structured, cross-linked alkyl acrylate rubber polymer (b-1) latex having an average particle diameter of 50-250 nm. A thermoplastic resin composition prepared by mixing the graft copolymer of the present invention with a hard matrix (B) has very superior weathering resistance and superior pigmentation property, gloss, impact resistance and low-temperature impact strength.
Abstract translation: 本发明涉及接枝共聚物，其制备方法和含有它的热塑性树脂组合物。 本发明的接枝共聚物包含平均粒径为250-600nm的复合橡胶聚合物（A-1），其通过在混合平均粒径为50的二烯橡胶聚合物（a-1）胶乳之后通过粒子增大制备 -150nm的核 - 壳结构的交联的丙烯酸烷基酯橡胶聚合物（b-1）胶乳，其平均粒径为50-250nm。 通过将本发明的接枝共聚物与硬质基体（B）混合而制备的热塑性树脂组合物具有非常优异的耐候性和优异的着色性，光泽度，耐冲击性和低温冲击强度。
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2.发明申请LOW SURFACE GLOSS STYRENE RESIN COMPOSITION, AND LOW SURFACE GLOSS SHEET AND COMPOSITE ARTICLE THEREFROM 有权低表面GLOSS苯乙烯树脂组合物和低表面胶层和复合材料公开(公告)号：US20100075165A1
公开(公告)日：2010-03-25
申请号：US12525575
申请日：2008-01-30
Applicant: Yun-kyoung Cho , Seon-mo Son , Bong-keun Lee , Tae-bin Ahn , Han-jong You , Sung-tae Ahn
Inventor： Yun-kyoung Cho , Seon-mo Son , Bong-keun Lee , Tae-bin Ahn , Han-jong You , Sung-tae Ahn
IPC: C08L25/04 , C08L9/00 , C08L47/00 , C08L33/20 , C08L33/04 , C08L35/00 , C08L33/24 , C08K5/12 , C08K5/52 , C08K5/1515 , C08K3/26 , C08K3/22 , B29C47/06 , B32B27/08
CPC classification number: C08L51/04 , B32B25/14 , B32B27/08 , B32B27/30 , C08J2325/06 , C08L25/06 , C08L25/12 , C08L35/06 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2555/40 , Y10T428/31924 , C08L2666/04 , C08L2666/06 , C08L2666/02
Abstract: The present invention relates to a low surface gloss styrene resin composition. The composition of the present invention is composed of (A) 80-99.9 weight % of the basic resin comprising rubber-modified styrene resin and (B) 0.1-20 weight % of syndiotactic polystyrene, the matting agent. The composition also includes (C) hydrogenated styrene block copolymer comprising styrene block and butadiene rubber block as a compatibilizer by 0.1-20 weight % for the total weight of the low surface gloss styrene resin composed of (A) the basic resin and (B) the matting agent and additionally includes (D) a plasticizer by 0.1-30 weight %. The composition of the present invention has excellent weatherability and impact-resistance in addition to the low surface gloss properties, so that it can be applied in various products, particularly exterior products for structures such as sidings and window frames, etc.
Abstract translation: 本发明涉及一种低表面光泽的苯乙烯树脂组合物。 本发明的组合物由（A）80-99.9重量％的包含橡胶改性苯乙烯树脂的基础树脂和（B）0.1-20重量％的间同立构聚苯乙烯，消光剂组成。 该组合物还包含（C）包含苯乙烯嵌段和丁二烯橡胶嵌段作为增容剂的氢化苯乙烯嵌段共聚物，由（A）碱性树脂和（B）组成的低表面光泽苯乙烯树脂的总重量为0.1-20重量％ 该消光剂还包括（D）0.1-30重量％的增塑剂。 本发明的组合物除了具有低的表面光泽特性之外还具有优异的耐候性和抗冲击性，因此可以应用于各种产品，特别是用于诸如边框和窗框等结构的外用产品。
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公开(公告)号：US20050159529A1
公开(公告)日：2005-07-21
申请号：US10517070
申请日：2004-06-09
Applicant: Hyun-taek O , Tae-Bin Ahn , Jung-Tae Park , Keon-Hoon Yoo
Inventor： Hyun-taek O , Tae-Bin Ahn , Jung-Tae Park , Keon-Hoon Yoo
CPC classification number: C08K5/0008 , C08F257/02 , C08F265/04 , C08F285/00 , C08J3/122 , C08J2351/00 , C08L51/003 , Y10S524/904 , C08L51/00 , C08L2666/02
Abstract: The present invention is related to a method of manufacture of a graft copolymer latex and its dried powder including a step of manufacture of a latex using a reactive surfactant for a surfactant in manufacturing of the graft copolymer latex containing acrylic polymers and a step of manufacture of dried powder in which the graft copolymer latex manufactured in the above step of manufacture of a latex is sprayed and dried. The method according to the present invention is effective in that it is possible to provide for dried powder of a graft copolymer latex having a low moisture content and a high powder density and to provide for a thermoplastic resin composition containing the above latex having superior luster, tensile strength, and thermal stability.
Abstract translation: 本发明涉及一种制备接枝共聚物胶乳及其干燥粉末的方法，包括在制备含有丙烯酸类聚合物的接枝共聚物胶乳中使用表面活性剂的反应性表面活性剂制备胶乳的步骤，以及制备 其中在上述制造胶乳步骤中制造的接枝共聚物胶乳被喷雾干燥。 根据本发明的方法是有效的，因为可以提供具有低水分含量和高粉末密度的接枝共聚物胶乳的干燥粉末，并提供含有上述胶乳的热塑性树脂组合物，其具有优异的光泽， 拉伸强度和热稳定性。
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公开(公告)号：US07393891B2
公开(公告)日：2008-07-01
申请号：US10517070
申请日：2004-06-09
Applicant: Hyun-taek O , Tae-bin Ahn , Jung-tae Park , Keon-hoon Yoo
Inventor： Hyun-taek O , Tae-bin Ahn , Jung-tae Park , Keon-hoon Yoo
CPC classification number: C08K5/0008 , C08F257/02 , C08F265/04 , C08F285/00 , C08J3/122 , C08J2351/00 , C08L51/003 , Y10S524/904 , C08L51/00 , C08L2666/02
Abstract: The present invention is related to a method of manufacture of a graft copolymer latex and its dried powder including a step of manufacture of a latex using a reactive surfactant for a surfactant in manufacturing of the graft copolymer latex containing acrylic polymers and a step of manufacture of dried powder in which the graft copolymer latex manufactured in the above step of manufacture of a latex is sprayed and dried. The method according to the present invention is effective in that it is possible to provide for dried powder of a graft copolymer latex having a low moisture content and a high powder density and to provide for a thermoplastic resin composition containing the above latex having superior luster, tensile strength, and thermal stability.
Abstract translation: 本发明涉及一种制备接枝共聚物胶乳及其干燥粉末的方法，包括在制备含有丙烯酸类聚合物的接枝共聚物胶乳中使用表面活性剂的反应性表面活性剂制备胶乳的步骤，以及制备 其中在上述制造胶乳步骤中制造的接枝共聚物胶乳被喷雾干燥。 根据本发明的方法是有效的，因为可以提供具有低水分含量和高粉末密度的接枝共聚物胶乳的干燥粉末，并提供含有上述胶乳的热塑性树脂组合物，其具有优异的光泽， 拉伸强度和热稳定性。
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公开(公告)号：US20070203293A1
公开(公告)日：2007-08-30
申请号：US11511581
申请日：2006-08-29
Applicant: Tae-bin Ahn , Hyun-taek O , Jung-tae Park , Min-jung Kim , Keun-hoon Yoo
Inventor： Tae-bin Ahn , Hyun-taek O , Jung-tae Park , Min-jung Kim , Keun-hoon Yoo
IPC: C08L51/04
CPC classification number: G10L19/10
Abstract: The present invention relates to a thermoplastic resin composition, more precisely, a thermoplastic resin composition with enhanced impact resistance, gloss, weather resistance and scratch resistance, compared with the conventional thermoplastic resin compositions, by containing an acrylate-styrene-acrylonitrile (ASA) graft copolymer, an aromatic vinyl compound and vinyl cyan compound copolymer, an alkyl methacrylate/aromatic vinyl compound/vinyl cyan compound terpolymer and a di-block copolymer (aromatic vinyl compound/vinyl cyan compound-alkyl methacrylate/aromatic vinyl compound/vinyl cyan compound).
Abstract translation: 本发明涉及一种热塑性树脂组合物，更准确地说，与常规热塑性树脂组合物相比，通过含有丙烯酸酯 - 苯乙烯 - 丙烯腈（ASA）接枝物，具有增强的耐冲击性，光泽，耐候性和耐划伤性的热塑性树脂组合物 共聚物，芳族乙烯基化合物和乙烯基青色化合物共聚物，甲基丙烯酸烷基酯/芳族乙烯基化合物/乙烯基氰化合物三元共聚物和二嵌段共聚物（芳族乙烯基化合物/乙烯基氰基化合物 - 甲基丙烯酸烷基酯/芳族乙烯基化合物/ 。
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Patent Agency Ranking
公开(公告)号：US20090086319A1
公开(公告)日：2009-04-02
申请号：US12286559
申请日：2008-10-01
Applicant: Tae-Bin Ahn , Yong-Yeon Hwang , Min-Jung Kim , Jae-Hyun Jeong , Ki-Heon Song
Inventor： Tae-Bin Ahn , Yong-Yeon Hwang , Min-Jung Kim , Jae-Hyun Jeong , Ki-Heon Song
CPC classification number: C08L33/08 , C08L51/06 , Y10T428/1041 , C08L2666/24
Abstract: The present invention provides an optical film that includes i) a (meth)acrylic resin, and 5 to 45 parts by weight of ii) a graft copolymer, prepared by grafting a (meth)acrylic resin onto a copolymer of (meth)acrylic rubber and aromatic vinyl compound, based on 100 parts by weight of the i) (meth)acrylic resin, and an electronic device including the optical film.
Abstract translation: 本发明提供一种光学膜，其包括i）（甲基）丙烯酸树脂和5〜45重量份的ii）通过将（甲基）丙烯酸树脂接枝到（甲基）丙烯酸橡胶的共聚物上而制备的接枝共聚物 和芳族乙烯基化合物，基于100重量份的i）（甲基）丙烯酸树脂，以及包括该光学膜的电子器件。
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公开(公告)号：US06806315B2
公开(公告)日：2004-10-19
申请号：US10363585
申请日：2003-03-04
Applicant: Yang-Hyun Shin , Keun-Hoon Yoo , Tae-Bin Ahn , Chan-Hong Lee
Inventor： Yang-Hyun Shin , Keun-Hoon Yoo , Tae-Bin Ahn , Chan-Hong Lee
IPC: C08L1300
CPC classification number: C08F265/04 , C08F285/00 , C08F212/10
Abstract: A method for preparing a weatherable thermoplastic resin, having superior weatherability and colorability and a weatherable thermoplastic resin prepared by the method are provided. The method includes preparing a seed by adding a water-soluble initiator to either an aromatic vinyl compound or a (meth)acrylic acid alkyl ester to obtain a first compound and performing polymerization with respect to the first compound; preparing an alkyl acrylate rubber polymer by adding an alkyl acrylate monomer, a first emulsifier of pH about 3 to about 9, and an oil-soluble initiator to the seed to obtain a second compound and performing polymerization with respect to the second compound; and preparing graft copolymer by adding the aromatic vinyl compound, a vinyl cyanide compound, a second emulsifier of pH about 9 to about 13, and the oil-soluble initiator to the alkyl acrylate rubber polymer to obtain a third compound and performing graft copolymerization with respect to the third compound.
Abstract translation: 提供了一种制备具有优异的耐候性和着色性的耐候性热塑性树脂的方法和通过该方法制备的耐候性热塑性树脂。 该方法包括通过向芳族乙烯基化合物或（甲基）丙烯酸烷基酯中加入水溶性引发剂以获得第一化合物并相对于第一化合物进行聚合来制备种子; 通过向种子中加入丙烯酸烷基酯单体，pH约3至约9的第一乳化剂和油溶性引发剂以制备丙烯酸烷基酯橡胶聚合物以获得第二化合物并相对于第二化合物进行聚合; 并通过将芳族乙烯基化合物，乙烯基氰化合物，pH约9至约13的第二乳化剂和油溶性引发剂加入到丙烯酸烷基酯橡胶聚合物中制备接枝共聚物，以获得第三种化合物，并进行接枝共聚 到第三化合物。
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8.发明授权Low surface gloss styrene resin composition, and low surface gloss sheet and composite article therefrom 有权低表面光泽的苯乙烯树脂组合物和低表面光泽度的片材及其复合制品公开(公告)号：US08378024B2
公开(公告)日：2013-02-19
申请号：US12525575
申请日：2008-01-30
Applicant: Yun-kyoung Cho , Seon-mo Son , Bong-keun Lee , Tae-bin Ahn , Han-jong You , Sung-tae Ahn
Inventor： Yun-kyoung Cho , Seon-mo Son , Bong-keun Lee , Tae-bin Ahn , Han-jong You , Sung-tae Ahn
CPC classification number: C08L51/04 , B32B25/14 , B32B27/08 , B32B27/30 , C08J2325/06 , C08L25/06 , C08L25/12 , C08L35/06 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2555/40 , Y10T428/31924 , C08L2666/04 , C08L2666/06 , C08L2666/02
Abstract: The present invention relates to a low surface gloss styrene resin composition. The composition of the present invention is composed of (A) 80-99.9 weight % of the basic resin comprising rubber-modified styrene resin and (B) 0.1-20 weight % of syndiotactic polystyrene, the matting agent. The composition also includes (C) hydrogenated styrene block copolymer comprising styrene block and butadiene rubber block as a compatibilizer by 0.1-20 weight % for the total weight of the low surface gloss styrene resin composed of (A) the basic resin and (B) the matting agent and additionally includes (D) a plasticizer by 0.1-30 weight %. The composition of the present invention has excellent weatherability and impact-resistance in addition to the low surface gloss properties, so that it can be applied in various products, particularly exterior products for structures such as sidings and window frames, etc.
Abstract translation: 本发明涉及一种低表面光泽的苯乙烯树脂组合物。 本发明的组合物由（A）80-99.9重量％的包含橡胶改性苯乙烯树脂的基础树脂和（B）0.1-20重量％的间同立构聚苯乙烯，消光剂组成。 该组合物还包含（C）包含苯乙烯嵌段和丁二烯橡胶嵌段作为增容剂的氢化苯乙烯嵌段共聚物，由（A）碱性树脂和（B）组成的低表面光泽苯乙烯树脂的总重量为0.1-20重量％ 该消光剂还包括（D）0.1-30重量％的增塑剂。 本发明的组合物除了具有低的表面光泽特性之外还具有优异的耐候性和抗冲击性，因此可以应用于各种产品，特别是用于诸如边框和窗框等结构的外用产品。
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公开(公告)号：US07936510B2
公开(公告)日：2011-05-03
申请号：US12286559
申请日：2008-10-01
Applicant: Tae-Bin Ahn , Yong-Yeon Hwang , Min-Jung Kim , Jae-Hyun Jeong , Ki-Heon Song
Inventor： Tae-Bin Ahn , Yong-Yeon Hwang , Min-Jung Kim , Jae-Hyun Jeong , Ki-Heon Song
CPC classification number: C08L33/08 , C08L51/06 , Y10T428/1041 , C08L2666/24
Abstract: The present invention provides an optical film that includes i) a (meth)acrylic resin, and 5 to 45 parts by weight of ii) a graft copolymer, prepared by grafting a (meth)acrylic resin onto a copolymer of (meth)acrylic rubber and aromatic vinyl compound, based on 100 parts by weight of the i) (meth)acrylic resin, and an electronic device including the optical film.
Abstract translation: 本发明提供一种光学膜，其包括i）（甲基）丙烯酸树脂和5〜45重量份的ii）通过将（甲基）丙烯酸树脂接枝到（甲基）丙烯酸橡胶的共聚物上而制备的接枝共聚物 和芳族乙烯基化合物，基于100重量份的i）（甲基）丙烯酸树脂，以及包括该光学膜的电子器件。
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公开(公告)号：US07417088B2
公开(公告)日：2008-08-26
申请号：US11511581
申请日：2006-08-29
Applicant: Tae-bin Ahn , Hyun-taek O , Jung-tae Park , Min-jung Kim , Keun-hoon Yoo
Inventor： Tae-bin Ahn , Hyun-taek O , Jung-tae Park , Min-jung Kim , Keun-hoon Yoo
CPC classification number: G10L19/10
Abstract: The present invention relates to a thermoplastic resin composition, more precisely, a thermoplastic resin composition with enhanced impact resistance, gloss, weather resistance and scratch resistance, compared with the conventional thermoplastic resin compositions, by containing an acrylate-styrene-acrylonitrile (ASA) graft copolymer, an aromatic vinyl compound and vinyl cyan compound copolymer, an alkyl methacrylate/aromatic vinyl compound/vinyl cyan compound terpolymer and a di-block copolymer (aromatic vinyl compound/vinyl cyan compound—alkyl methacrylate/aromatic vinyl compound/vinyl cyan compound).
Abstract translation: 本发明涉及一种热塑性树脂组合物，更准确地说，与常规热塑性树脂组合物相比，通过含有丙烯酸酯 - 苯乙烯 - 丙烯腈（ASA）接枝物，具有增强的耐冲击性，光泽，耐候性和耐擦伤性的热塑性树脂组合物 共聚物，芳族乙烯基化合物和乙烯基青色化合物共聚物，甲基丙烯酸烷基酯/芳族乙烯基化合物/乙烯基氰化合物三元共聚物和二嵌段共聚物（芳族乙烯基化合物/乙烯基氰基化合物 - 甲基丙烯酸烷基酯/芳族乙烯基化合物/ 。
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