公开(公告)号：US07628849B1

公开(公告)日：2009-12-08

申请号：US12260344

申请日：2008-10-29

Applicant: Donald R. Diehl ,  Tommie L. Royster, Jr. ,  Andrew J. Hoteling ,  Steven G. Link

Inventor： Donald R. Diehl ,  Tommie L. Royster, Jr. ,  Andrew J. Hoteling ,  Steven G. Link

IPC: C09B47/04 ,  C07D487/22

CPC classification number: C07F7/0836 ,  C09B47/0671 ,  C09B47/085 ,  C09B47/10 ,  C09B69/008

Abstract: Fluorinated bis-(phthalocyanylaluminoxy)silyl bridged cyan or blue-green pigments according to formula (I): wherein R1 and R2 are independently substituted or unsubstituted alkyl, alkenyl, alkynyl, or cycloalkyl groups with eight or less carbon atoms or aryl groups with ten or less carbon atoms; R3 is a divalent linking group comprising oxygen, R1R2Si, substituted or unsubstituted alkyl, alkenyl, alkynyl cycloalkyl or aryl groups; R1, R2, and R3 may comprise the elements of a cyclic ring; n is 1-4; and z is 1-4.

Abstract translation: 根据式（I）的氟化双（（酞菁基铝氧基）甲硅烷基桥接青色或蓝绿色颜料：其中R 1和R 2独立地为具有8个或更少碳原子的烷基，烯基，炔基或环烷基或具有10个 或更少的碳原子; R3是包含氧，R1R2Si，取代或未取代的烷基，烯基，炔基环烷基或芳基的二价连接基团; R1，R2和R3可以包括环的元素; n为1-4; z为1-4。

公开(公告)号：US07608140B2

公开(公告)日：2009-10-27

申请号：US12031766

申请日：2008-02-15

Applicant: Steven G. Link ,  Joan C. Potenza ,  Paul A. Loncle ,  Donald R. Diehl ,  Shari L. Eiff

Inventor： Steven G. Link ,  Joan C. Potenza ,  Paul A. Loncle ,  Donald R. Diehl ,  Shari L. Eiff

IPC: C09D11/02 ,  B41J2/01

CPC classification number: C09D11/32

Abstract: The present invention relates to an aqueous ink comprising at least water, and a colorant of Formula 1 wherein A is any substituted or unsubstituted aromatic or heteroaromatic moiety; R is hydrogen or any non-metallic group; R1 is hydrogen, or any substituted or unsubstituted aryl, alkenyl, alkynyl or alkyl group; R2 and R3 are hydrogen or any non-metallic group, and R2 and R3 can be joined to form a ring that may be aromatic, aliphatic or heterocyclic and may be further substituted; or a colorant of Formula 2: wherein R4 is hydrogen or any non-metallic group; n is an integer of 0-4; and, if n is 2-4, the R4 groups may be the same or different from each other, and a printing method for creating an image on an ink compatible substrate using colorants of Formula 1 or Formula 2.

Abstract translation: 本发明涉及至少包含水的水性油墨和式1的着色剂，其中A是任何取代或未取代的芳族或杂芳族部分; R是氢或任何非金属基团; R 1是氢或任何取代或未取代的芳基，烯基，炔基或烷基; R 2和R 3是氢或任何非金属基团，并且R 2和R 3可以连接形成可以是芳族，脂族或杂环并且可以被进一步取代的环; 或式2的着色剂：其中R 4是氢或任何非金属基团; n是0-4的整数; 如果n为2-4，则R4基彼此可以相同或不同，以及使用式1或式2的着色剂在油墨兼容基板上产生图像的印刷方法。

公开(公告)号：US07582149B2

公开(公告)日：2009-09-01

申请号：US12015110

申请日：2008-01-16

Applicant: Steven G. Link ,  Joan C. Potenza ,  Ann L. Carroll-Lee

Inventor： Steven G. Link ,  Joan C. Potenza ,  Ann L. Carroll-Lee

IPC: C09D11/02 ,  B41J2/01 ,  C09B29/033

CPC classification number: B41M5/0023 ,  C09B29/3691 ,  C09D11/328

Abstract: The invention relates to monoazo colorants derived from pyrazolobenzodiazinedioxides of Formula 1: wherein R1 and R2 are hydrogen or any non-metallic group, n is 0-4, R3 is hydrogen, acyl, aryl, alkenyl, alkynyl or alkyl, A represents an aromatic heterocyclic ring or an aromatic group of Formula 2: wherein R6 and R8 are hydrogen, alkyl, sulfonic acid, or 1-4 carbon alkoxy, R7 is any non-metallic group, m is 0-3, and R6 and R7, R7 and R8, or, when m>1, two R7 groups can be joined to form a fused carbocyclic or heterocyclic aromatic or non-aromatic ring. The invention also relates to an aqueous ink that comprises at least one colorant of Formula 1: wherein A represents an aromatic or heteroaromatic ring, and A can be bonded to other rings that can be aromatic, aliphatic or heterocyclic, and an ink printing method using the colorant-containing ink.

Abstract translation: 本发明涉及衍生自式1的吡唑并二氮杂二环氧化物的单偶氮染料：其中R 1和R 2是氢或任何非金属基团，n是0-4，R 3是氢，酰基，芳基，链烯基，炔基或烷基，A代表芳香族 杂环或式2的芳基：其中R 6和R 8是氢，烷基，磺酸或1-4碳烷氧基，R 7是任何非金属基团，m是0-3，并且R 6和R 7，R 7和 R8，或者当m> 1时，可以连接两个R 7基团以形成稠合的碳环或杂环芳族或非芳族环。 本发明还涉及包含至少一种式1的着色剂的水性油墨：其中A表示芳族或杂芳族环，并且A可以与可以是芳族，脂族或杂环的其它环结合，以及使用 含着色剂的油墨。

公开(公告)号：US06787297B1

公开(公告)日：2004-09-07

申请号：US10436288

申请日：2003-05-12

Applicant: Steven G. Link ,  Richard L. Parton ,  Robert D. Wilson ,  Roger A. Bryant ,  William J. Harrison

Inventor： Steven G. Link ,  Richard L. Parton ,  Robert D. Wilson ,  Roger A. Bryant ,  William J. Harrison

IPC: G03C1005

CPC classification number: G03C1/29

Abstract: This invention provides a silver halide photographic element comprising at least one silver halide emulsion comprising silver halide grains which have associated therewith at least an inner dye layer and an outer dye layer wherein the outer dye layer comprises a dye having at least one substituent that has a positive charge, said photographic element further comprising a cyanine dye of formula (I) or (II) (as described in the specification) that is capable of spectrally sensitizing a silver halide emulsion.

Abstract translation: 本发明提供一种卤化银照相元件，其包含至少一种卤化银乳剂，其包含卤化银颗粒，所述卤化银颗粒至少与内染料层和外染料层相关联，其中外染料层包含具有至少一个取代基的染料， 所述照相元件还包含能够对卤化银乳剂进行光谱增感的式（I）或（II）的花青染料（如说明书中所述）。

公开(公告)号：US06312884B1

公开(公告)日：2001-11-06

申请号：US09533573

申请日：2000-03-23

Applicant: Steven G. Link ,  John D. Mee

Inventor： Steven G. Link ,  John D. Mee

IPC: G03C114

CPC classification number: G03C1/14

Abstract: This invention comprises a photographic element comprising a light sensitive silver halide emulsion layer which contains a sensitizing dye of the formula: wherein: n is 0 or 1; X, Y, and Z are independently O, N, S, Se, or C; X′ is O, NR13, S, or Se; R1 and R2 are acid substituted alkyl; R4 is H or alkyl, with the proviso that if X′ is N, R4 is H; each of R6, R7, R8 and R9 is independently H or a substituent or R7 and R8 or R8 and R9 together with the carbon atoms to which they are attached form a 5-membered or 6-membered ring; when X or Y or Z is O, N, S or Se then a, b or c, respectively, is 0 and when X or Y or Z is C, a, b or c, respectively is 1 and the corresponding R10, R11, or R12 substituent is independently H or a non-aromatic substituent; and R13 is alkyl or substituted alkyl.

Abstract translation: 本发明包括一种含有感光卤化银乳剂层的照相元件，其含有下式的增感染料：其中：n为0或1; X，Y和Z独立地为O，N，S，Se或C; X'是O，NR 13，S或Se; R 1和R 2是酸取代的烷基; R 4是H或烷基，条件是如果X'是N，则R4是H; R6，R7，R8和R9各自是 独立地是H或取代基，或者R 7和R 8或R 8和R 9与它们所连接的碳原子一起形成5元或6元环;当X或Y或Z为O，N，S或Se时， ，b或c分别为0，当X或Y或Z为C时，a，b或c分别为1，相应的R10，R11或R12取代基独立为H或非芳香族取代基; 和R 13是烷基或取代的烷基。

公开(公告)号：US6045983A

公开(公告)日：2000-04-04

申请号：US129269

申请日：1998-08-05

Applicant: Lois A. Buitano ,  Allan F. Sowinski ,  Maria J. Gonzalez ,  Steven G. Link

Inventor： Lois A. Buitano ,  Allan F. Sowinski ,  Maria J. Gonzalez ,  Steven G. Link

IPC: G03C7/00 ,  G03C1/035 ,  G03C1/12 ,  G03C7/30 ,  G03C1/46

CPC classification number: G03C7/30 ,  G03C1/12 ,  G03C7/3022 ,  G03C7/3041

Abstract: A color negative film is disclosed capable of producing dye images suitable for digital scanning. With a green recording layer unit coated over a red recording layer unit a red exposure information containing dye image record is created that better matches human visual color perception when reversed to a positive that is red with unsought densities in the same spectral region as the red exposure information containing dye image attributable to blue and green recording layer units subtracted, by (a) withholding colored masking couplers from the recording layer units, (b) employing tabular grain emulsions with average aspect ratios of less than 15 in the green recording layer unit, and (c) placing spectral sensitizing dye in the red recording layer unit that exhibits an overall half-peak absorption bandwidth of at least 50 nm bridging the green and red regions of the spectrum, with absorption at 560 nm being in the range of from 80 to 95 percent of maximum absorption, which is located in the spectral region of from 575 to 710 nm.

Abstract translation: 公开了能够产生适于数字扫描的染料图像的彩色底片。 通过涂覆在红色记录层单元上的绿色记录层单元，产生包含染料图像记录的红色曝光信息，其在与红色曝光相同的光谱区域中与未测量的浓度相反时，将人类视觉色彩感觉更好地匹配 通过（a）从记录层单元中扣留着色掩蔽成色剂，（b）在绿色记录层单元中使用平均长径比小于15的片状颗粒乳剂，减去归因于蓝色和绿色记录层单元的染色影像的信息， 和（c）在红色记录层单元中放置光谱增感染料，其表现出桥接绿色和红色区域的至少50nm的总体半峰吸收带宽，其中560nm处的吸收在80 至95％的最大吸收，其位于575至710nm的光谱区域。

公开(公告)号：US5597687A

公开(公告)日：1997-01-28

申请号：US545368

申请日：1995-10-19

Applicant: Thomas R. Dobles ,  David A. DuMont ,  Paul B. Gilman ,  Sang H. Kim ,  Steven G. Link ,  Richard L. Parton

Inventor： Thomas R. Dobles ,  David A. DuMont ,  Paul B. Gilman ,  Sang H. Kim ,  Steven G. Link ,  Richard L. Parton

IPC: G03C1/08 ,  G03C1/29

CPC classification number: G03C1/29

Abstract: A supersensitizing dye combination for silver halide photographic materials is disclosed. The combination is of a first dye according to the formula: ##STR1## Z.sub.1 and Z.sub.2 each independently represents the atoms necessary to complete a substituted or unsubstituted heterocyclic nucleus,each L independently represents a substituted or unsubstituted methine group,n is a positive integer of from 1 to 4,p and q each independently represents 0 or 1,X represents a cation as needed to balance the charge of the molecule,A and A' each independently represents a divalent linking group such that at least one of H--A--SO.sub.3 H and H--A'--SO.sub.3 H would each have a log P value that is more negative than -0.3, anda second dye, having an oxidation potential that is at least about 0.08 volts less positive than the oxidation potential of the first dye and a reduction potential that is equal to or more negative than the reduction potential of the first dye, according to the formula: ##STR2## Z.sub.3 and Z.sub.4 each independently represents the atoms necessary to complete a substituted or unsubstituted heterocyclic nucleus,each L independently represents a substituted or unsubstituted methine group,m is a positive integer of from 1 to 4,r and s each independently represents 0 or 1,X' represents a counterion as needed to balance the charge of the molecule,R.sub.3 and R.sub.4 each independently represents substituted or unsubstituted alkyl or substituted or unsubstituted aryl.

Abstract translation: 公开了用于卤化银照相材料的超敏化染料组合。 该组合是根据下式的第一种染料：并且表示完成取代或未取代的杂环核所需的原子，每个L独立地表示取代或未取代的次甲基，n是1至4的正整数，p和 q各自独立地表示0或1，X表示用于平衡分子的电荷所需的阳离子，A和A'各自独立地表示二价连接基团，使得HA-SO 3 H和H-A'-SO 3 H中的至少一个将 每个具有比-0.3更负的对数P值，并且具有比第一染料的氧化电位小至少约0.08伏的氧化电位的第二染料和等于或等于或等于或等于 根据下列公式，阴性比第一种染料的还原电位：完成取代或未取代的杂环核所必需的e原子，每个L独立地表示取代或未取代的 次甲基，m为1至4的正整数，r和s各自独立地表示0或1，X'表示平衡分子电荷所需的抗衡离子，R 3和R 4各自独立地表示取代或未取代的烷基 或取代或未取代的芳基。

公开(公告)号：US20090205533A1

公开(公告)日：2009-08-20

申请号：US12031766

申请日：2008-02-15

Applicant: Steven G. Link ,  Joan C. Potenza ,  Paul A. Loncle ,  Donald R. Diehl ,  Shari L. Eiff

Inventor： Steven G. Link ,  Joan C. Potenza ,  Paul A. Loncle ,  Donald R. Diehl ,  Shari L. Eiff

IPC: C09D11/00 ,  G01D11/00

CPC classification number: C09D11/32

Abstract: The present invention relates to an aqueous ink comprising at least water, and a colorant of Formula 1 wherein A is any substituted or unsubstituted aromatic or heteroaromatic moiety; R is hydrogen or any non-metallic group; R1 is hydrogen, or any substituted or unsubstituted aryl, alkenyl, alkynyl or alkyl group; R2 and R3 are hydrogen or any non-metallic group, and R2 and R3 can be joined to form a ring that may be aromatic, aliphatic or heterocyclic and may be further substituted; or a colorant of Formula 2: wherein R4 is hydrogen or any non-metallic group; n is an integer of 0-4; and, if n is 2-4, the R4 groups may be the same or different from each other, and a printing method for creating an image on an ink compatible substrate using colorants of Formula 1 or Formula 2.

Abstract translation: 本发明涉及至少包含水的水性油墨和式1的着色剂，其中A是任何取代或未取代的芳族或杂芳族部分; R是氢或任何非金属基团; R 1是氢或任何取代或未取代的芳基，烯基，炔基或烷基; R 2和R 3是氢或任何非金属基团，并且R 2和R 3可以连接形成可以是芳族，脂族或杂环并且可以被进一步取代的环; 或式2的着色剂：其中R 4是氢或任何非金属基团; n是0-4的整数; 如果n为2-4，则R4基彼此可以相同或不同，以及使用式1或式2的着色剂在油墨兼容基板上产生图像的印刷方法。

公开(公告)号：US6146818A

公开(公告)日：2000-11-14

申请号：US223221

申请日：1998-12-30

Applicant: Maria J. Gonzalez ,  Allan F. Sowinski ,  Lois A. Buitano ,  Steven G. Link

Inventor： Maria J. Gonzalez ,  Allan F. Sowinski ,  Lois A. Buitano ,  Steven G. Link

IPC: G03C7/20 ,  G03C1/00 ,  G03C1/035 ,  G03C7/00 ,  G03C7/26 ,  G03C7/30 ,  G03C1/08

CPC classification number: G03C7/30 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/3041

Abstract: A color negative film is disclosed capable of producing dye images suitable for digital scanning comprised of a support and, coated on the support, a series of hydrophilic colloid layers including at least two red recording emulsion layer units capable of forming a dye image of a first hue, at least two green recording emulsion layer units capable of forming a dye image of a second hue, and at least one blue recording emulsion layer unit capable of forming a dye image of a third hue, wherein, (1) the series of hydrophilic colloid layers include the following sequence, starting with the layer unit coated nearest the support: (a) a slower speed red recording layer unit, (b) a slower speed green recording layer unit, (c) a faster speed red recording layer unit, and (d) a faster speed green recording layer unit; (2) colored masking couplers are absent from the recording layer units; (3) tabular grain emulsions sensitized to the green and red are employed in the green and red recording layer units, respectively, and (4) spectral sensitizing dye in the red recording layer units exhibits an overall half-peak absorption bandwidth of at least 50 nm bridging the green and red regions of the spectrum, with absorption at 560 nm being in the range of from 80 to 95 percent of maximum absorption, which is located in the spectral region of from 570 to 710 nm. When the images produced by the red recording layer units are printed as red images, the human eye sees the red component image as an improved reproduction of the red component of the original image.

Abstract translation: 公开了一种彩色底片，其能够产生适于数字扫描的染料图像，该染料图像由载体构成，并且涂覆在载体上，一系列亲水胶体层，其包括至少两个红色记录乳剂层单元，能够形成第一 能够形成第二色调的染料影像的至少两个绿色记录乳剂层单元和能够形成第三色调的染料影像的至少一个蓝色记录乳剂层单元，其中，（1）一系列亲水性 胶体层包括以下顺序，从最靠近载体的层单元开始：（a）较慢速度的红色记录层单元，（b）较慢速度的绿色记录层单元，（c）较快速度的红色记录层单元， 和（d）更快速的绿色记录层单元; （2）记录层单元中不存在彩色掩蔽成色剂; （3）在绿色和红色记录层单元中分别使用对绿色和红色敏化的片状颗粒乳剂，（4）红色记录层单元中的光谱增感染料显示总共半峰吸收带宽至少为50 nm桥接光谱的绿色和红色区域，560nm处的吸收在最大吸收的80％至95％的范围内，其位于570至710nm的光谱区域。 当红色记录层单元产生的图像被打印为红色图像时，人眼将红色分量图像视为原始图像的红色分量的改进的再现。

公开(公告)号：US5958666A

公开(公告)日：1999-09-28

申请号：US926857

申请日：1997-09-10

Applicant: Steven G. Link ,  Roger Lok

Inventor： Steven G. Link ,  Roger Lok

IPC: G03C1/16 ,  G03C1/035 ,  G03C1/14 ,  G03C1/18 ,  G03C1/29

CPC classification number: G03C1/14 ,  G03C1/29 ,  G03C1/035 ,  G03C1/16 ,  G03C1/18

Abstract: A photographic element comprises at least one light-sensitive layer comprising a silver halide emulsion, wherein the silver halide content is less than or equal to 30% silver chloride, and a dye of formula (I) or formula (II): ##STR1## wherein the substituents are as defined in the specification. ##STR2## wherein the substituents are as defined in the specification.

Abstract translation: 照相元件包括至少一个包含卤化银乳剂的感光层，其中卤化银含量小于或等于30％氯化银，和式（I）或式（II）的染料：其中取代基 如说明书中所定义。 其中取代基如说明书中所定义。