公开(公告)号：US06376763B2

公开(公告)日：2002-04-23

申请号：US09733799

申请日：2000-12-08

申请人： Ryoji Funahashi ,  Ichiro Matsubara ,  Satoshi Sodeoka

发明人： Ryoji Funahashi ,  Ichiro Matsubara ,  Satoshi Sodeoka

IPC分类号： H01L3534

CPC分类号： C01G51/68 ,  C01P2002/34 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/88 ,  C01P2006/32 ,  C01P2006/40 ,  H01B1/08 ,  H01L35/20 ,  H01L35/22

摘要： This invention provides a complex oxide comprising the features of: (i) being represented by the formula: Ca3-xRExCo4Oy wherein RE is a rare earth element, 0≦x≦0.5 and 8.5≦y≦10, (ii) having a Seebeck coefficient of 100 &mgr;V/K or more at a temperature of 300° C. or higher, and (iii) having an electric conductivity of 103 S/m or more at a temperature of 300° C. or higher. The complex oxide is composed of low-toxicity elements, excellent in heat resistance and chemical durability and high in thermoelectric conversion efficiency.

摘要翻译： 本发明提供一种复合氧化物，其包括以下特征：（i）由下式表示：Ca 3-x R Ex Co 4 O y其中RE为稀土元素，0≤x≤0.5且8.5≤y≤10，（ii） 在300℃以上的温度下具有100μV/ K以上的塞贝克系数，（iii）在300℃以上的温度下具有103S / m以上的电导率。 复合氧化物由低毒元素组成，耐热性和化学耐久性优异，热电转换效率高。

公开(公告)号：US06727424B2

公开(公告)日：2004-04-27

申请号：US10364807

申请日：2003-02-11

申请人： Ryoji Funahashi ,  Ichiro Matsubara ,  Satoshi Sodeoka

发明人： Ryoji Funahashi ,  Ichiro Matsubara ,  Satoshi Sodeoka

IPC分类号： H01L3500

CPC分类号： H01L35/18 ,  C03C3/122 ,  C03C3/15 ,  C03C4/14 ,  C03C10/00 ,  H01L35/14

摘要： This invention provides a complex oxide comprising the features of : (i) being represented by the formula:(A0.4B0.1M0.1)x/0.6Co2Oy wherein A and B are elements differing from each other, each represents Ca, Sr or Ba, M represents Bi, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb or Lu, 1.7≦x≦2, and 3.8≦y≦5, (ii) having a Seebeck coefficient of 100 &mgr;V/K or more at a temperature of 100 K (absolute temperature) or higher and (iii) having an electrical resistivity of 10 m&OHgr;cm or less at a temperature of 100 K (absolute temperature) or higher. The complex oxide of the invention is a material composed of low-toxicity elements existing in large amounts, the material having superior heat resistance and chemical durability and a high thermoelectric conversion efficiency in a temperature range of 600 K or higher which falls in the temperature range of waste heat.

摘要翻译： 本发明提供一种复合氧化物，其包含以下特征：（i）由下式表示：（A0.4B0.1M0.1）x / 0.6Co2Oy其中A和B是彼此不同的元素，各自表示Ca，Sr或 Ba，M表示Bi，Sc，Y，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Yb或Lu，1.7 <= x <= 2和3.8 < = 5，（ii）在100K（绝对温度）以上的温度下具有100kV / K以上的塞贝克系数和（iii）在100K的温度下具有10mOmegacm以下的电阻率（绝对值） 温度）以上。 本发明的复合氧化物是由大量存在的低毒元素组成的材料，该材料具有优异的耐热性和化学耐久性，并且在600K以上的温度范围内具有较高的热电转换效率，其温度范围 的余热。

公开(公告)号：US5380686A

公开(公告)日：1995-01-10

申请号：US109058

申请日：1993-08-19

申请人： Isao Kondou ,  Nobuyuki Tamari ,  Takahiro Tanaka ,  Satoshi Sodeoka

发明人： Isao Kondou ,  Nobuyuki Tamari ,  Takahiro Tanaka ,  Satoshi Sodeoka

IPC分类号： C04B35/628 ,  C04B35/563 ,  C04B35/575 ,  C04B35/626 ,  C04B35/56 ,  C04B35/10

CPC分类号： C04B35/563 ,  C04B35/575 ,  C04B35/626 ,  C04B35/645

摘要： There are disclosed a process for producing a uniformly mixed composite raw material for ceramics by recovering the uniformly mixed composite raw material for ceramics from the dispersion of at least two types of raw materials for ceramics and optionally a component other than said materials in a liquid medium, which comprises coagulating and precipitating the composite raw material together with aluminum hydroxide formed by reacting an aluminum salt with an alkali in the liquid medium; and a uniformly mixed composite raw material for ceramics which is produced by the above process.

摘要翻译： 公开了一种用于陶瓷的均匀混合复合原料的制造方法，其特征在于，从陶瓷的至少两种类型的原料和任选的除液态介质以外的成分的分散体中回收均匀混合的陶瓷用复合原料 其包括将复合原料与通过铝盐与碱在液体介质中反应形成的氢氧化铝凝结和沉淀; 以及通过上述方法制造的均匀混合的陶瓷复合材料。

公开(公告)号：US06544444B2

公开(公告)日：2003-04-08

申请号：US09741607

申请日：2000-12-19

申请人： Ryoji Funahashi ,  Ichiro Matsubara ,  Satoshi Sodeoka

发明人： Ryoji Funahashi ,  Ichiro Matsubara ,  Satoshi Sodeoka

IPC分类号： H01B108

CPC分类号： H01L35/18 ,  C03C3/122 ,  C03C3/15 ,  C03C4/14 ,  C03C10/00 ,  H01L35/14

摘要： This invention provides a complex oxide comprising the features of: (i) being represented by the formula: (A0.4B0.1M0.1)x/0.6Co2Oy wherein A and B are elements differing from each other, each represents Ca, Sr or Ba, M represents Bi, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb or Lu, 1.7≦x≦2, and 3.8≦y≦5, (ii) having a Seebeck coefficient of 100 &mgr;V/K or more at a temperature of 100 K (absolute temperature) or higher and (iii) having an electrical resistivity of 10 m&OHgr;cm or less at a temperature of 100 K (absolute temperature) or higher. The complex oxide of the invention is a material composed of low-toxicity elements existing in large amounts, the material having superior heat resistance and chemical durability and a high thermoelectric conversion efficiency in a temperature range of 600 K or higher which falls in the temperature range of waste heat.

摘要翻译： 本发明提供一种复合氧化物，其包含以下特征：（i）由下式表示：（A0.4B0.1M0.1）x / 0.6Co2Oy其中A和B是彼此不同的元素，各自表示Ca，Sr或 Ba，M表示Bi，Sc，Y，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Yb或Lu，1.7 <= x <= 2，3.8 < = 5，（ii）在100K（绝对温度）以上的温度下具有100kV / K以上的塞贝克系数和（iii）在100K的温度下具有10mOMEGAcm以下的电阻率（绝对值） 温度）以上。 本发明的复合氧化物是由大量存在的低毒元素组成的材料，该材料具有优异的耐热性和化学耐久性，并且在600K以上的温度范围内具有较高的热电转换效率，其温度范围 的余热。