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公开(公告)号：US08785526B2
公开(公告)日：2014-07-22
申请号：US13325171
申请日：2011-12-14
CPC分类号： D01F6/70 , C04B16/0675 , C04B28/02 , C04B2103/0051 , D01F6/66 , D01F6/78 , Y10T428/298
摘要： Disclosed are polymeric additives for concrete formed of a polyoxymethylene (POM) copolymer. POM copolymers can be utilized to form fibrous additives for concrete, i.e., microfibers and/or macrofibers. The POM copolymers can include one or more chemical groups, e.g., end groups and/or pendant groups that can increase the polarity of the POM and increase the hydrophilicity of the formed fibers, which can improve miscibility of the fibers in wet concrete. Chemical groups of the POM copolymers can bond with components of the concrete or can hydrolyze to form groups that can bond with components of the concrete, e.g., form covalent or noncovalent (e.g., electrostatic or ionic) bonds with one or more components of the concrete binder.
摘要翻译： 公开了由聚甲醛（POM）共聚物形成的混凝土聚合物添加剂。 POM共聚物可用于形成混凝土的纤维添加剂，即微纤维和/或大纤维。 POM共聚物可以包括一个或多个化学基团，例如端基和/或侧基，其可以增加POM的极性并增加所形成的纤维的亲水性，这可改善纤维在湿混凝土中的混溶性。 POM共聚物的化学基团可以与混凝土的组分结合，或者可以水解形成可以与混凝土组分结合的基团，例如与混凝土的一种或多种组分形成共价或非共价键（例如静电或离子）键 粘合剂
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2.再颁专利公开(公告)号：USRE39182E1
公开(公告)日：2006-07-11
申请号：US09998276
申请日：2001-11-30
申请人： Karl-Friedrich Mück , Horst Röschert , Robert M. Gronner , Satyajit Verma , Michael G. Yearwood
发明人： Karl-Friedrich Mück , Horst Röschert , Robert M. Gronner , Satyajit Verma , Michael G. Yearwood
摘要： A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.
摘要翻译： 一种制备聚甲醛共聚物的方法，其中1,3,5-三恶烷在强质子酸引发剂的存在下和在甲醛二烷基缩醛存在下与通常已知的共聚单体聚合，并且其中引发剂溶于 甲醛二烷基缩醛，然后与三恶烷和共聚单体混合。
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公开(公告)号：US08481671B2
公开(公告)日：2013-07-09
申请号：US12787698
申请日：2010-05-26
CPC分类号： C08L67/025 , C08G2/06 , C08G2/10 , C08L59/02 , C08L2666/16
摘要： The present invention relates to a process for the preparation of oxymethylene polymers as well as oxymethylene polymers obtainable therefrom. The process includes polymerization of a monomer, which forms —CH2—O— units in the presence of an acetal of formaldehyde or a polyhydric alcohol and an initiator for cationic polymerization. The initiator may be a heteropoly acid or an acid salt thereof which is dissolved in an alkyl ester of a polybasic carboxylic acid.
摘要翻译： 本发明涉及一种制备甲醛聚合物的方法以及由其获得的甲醛聚合物。 该方法包括在甲醛或多元醇的缩醛和用于阳离子聚合的引发剂的存在下形成-CH 2 -O-单体的单体的聚合。 引发剂可以是杂多酸或其酸盐，其溶解在多元羧酸的烷基酯中。
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4.发明授权Powder containing a polyoxymethylene polymer for coating metallic substrates 有权含有用于涂覆金属基材的聚甲醛聚合物的粉末公开(公告)号：US09051476B2
公开(公告)日：2015-06-09
申请号：US13977401
申请日：2011-12-22
IPC分类号： C09D5/03 , B05D1/24 , C08L59/02 , C09D159/02
CPC分类号： C09D5/037 , B05D1/24 , C08L59/02 , C09D5/031 , C09D5/033 , C09D159/02 , Y10T428/254 , Y10T428/2982
摘要： A powder containing a polyoxymethylene polymer for coating metallic substrates is described. The polymeric particles are made from a polymeric composition containing a polyoxymethylene polymer having functional terminal groups. The polyoxymethylene polymer is blended with at least one functional additive. The functional additive can decrease the stiffness of the polyoxymethylene polymer, can decrease the shrinkage properties of the polyoxymethylene polymer and/or increase adhesion of the polymer to metal surfaces.
摘要翻译： 描述了包含用于涂覆金属基底的聚甲醛聚合物的粉末。 聚合物颗粒由含有具有官能端基的聚甲醛聚合物的聚合物组合物制成。 聚氧化亚甲基聚合物与至少一种功能性添加剂共混。 功能添加剂可以降低聚甲醛聚合物的刚度，可以降低聚甲醛聚合物的收缩性能和/或增加聚合物与金属表面的粘合性。
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公开(公告)号：US20120157576A1
公开(公告)日：2012-06-21
申请号：US13325171
申请日：2011-12-14
CPC分类号： D01F6/70 , C04B16/0675 , C04B28/02 , C04B2103/0051 , D01F6/66 , D01F6/78 , Y10T428/298
摘要： Disclosed are polymeric additives for concrete formed of a polyoxymethylene (POM) copolymer. POM copolymers can be utilized to form fibrous additives for concrete, i.e., microfibers and/or macrofibers. The POM copolymers can include one or more chemical groups, e.g., end groups and/or pendant groups that can increase the polarity of the POM and increase the hydrophilicity of the formed fibers, which can improve miscibility of the fibers in wet concrete. Chemical groups of the POM copolymers can bond with components of the concrete or can hydrolyze to form groups that can bond with components of the concrete, e.g., form covalent or noncovalent (e.g., electrostatic or ionic) bonds with one or more components of the concrete binder.
摘要翻译： 公开了由聚甲醛（POM）共聚物形成的混凝土聚合物添加剂。 POM共聚物可用于形成混凝土的纤维添加剂，即微纤维和/或大纤维。 POM共聚物可以包括一个或多个化学基团，例如端基和/或侧基，其可以增加POM的极性并增加所形成的纤维的亲水性，这可改善纤维在湿混凝土中的混溶性。 POM共聚物的化学基团可以与混凝土的组分结合，或者可以水解形成可以与混凝土组分结合的基团，例如与混凝土的一种或多种组分形成共价或非共价键（例如静电或离子）键 粘合剂
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公开(公告)号：US5994455A
公开(公告)日：1999-11-30
申请号：US149795
申请日：1998-09-08
申请人： Karl-Friedrich Muck , Horst Roschert , Robert M. Gronner , Satyajit Verma , Michael G. Yearwood
发明人： Karl-Friedrich Muck , Horst Roschert , Robert M. Gronner , Satyajit Verma , Michael G. Yearwood
摘要： A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.
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7.发明申请Powder Containing a Polyoxymethylene Polymer For Coating Metallic Substrates 有权含有用于涂覆金属基材的聚甲醛聚合物的粉末公开(公告)号：US20140030508A1
公开(公告)日：2014-01-30
申请号：US13977401
申请日：2011-12-22
CPC分类号： C09D5/037 , B05D1/24 , C08L59/02 , C09D5/031 , C09D5/033 , C09D159/02 , Y10T428/254 , Y10T428/2982
摘要： A powder containing a polyoxymethylene polymer for coating metallic substrates is described. The polymeric particles are made from a polymeric composition containing a polyoxymethylene polymer having functional terminal groups. The polyoxymethylene polymer is blended with at least one functional additive. The functional additive can decrease the stiffness of the polyoxymethylene polymer, can decrease the shrinkage properties of the polyoxymethylene polymer and/or increase adhesion of the polymer to metal surfaces.
摘要翻译： 描述了包含用于涂覆金属基底的聚甲醛聚合物的粉末。 聚合物颗粒由含有具有官能端基的聚甲醛聚合物的聚合物组合物制成。 聚氧化亚甲基聚合物与至少一种功能性添加剂共混。 功能添加剂可以降低聚甲醛聚合物的刚度，可以降低聚甲醛聚合物的收缩性能和/或增加聚合物与金属表面的粘合性。
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公开(公告)号：US20110077378A1
公开(公告)日：2011-03-31
申请号：US12787698
申请日：2010-05-26
CPC分类号： C08L67/025 , C08G2/06 , C08G2/10 , C08L59/02 , C08L2666/16
摘要： The present invention relates to a process for the preparation of oxymethylene polymers as well as oxymethylene polymers obtainable therefrom. The process includes polymerization of a monomer, which forms —CH2—O— units in the presence of an acetal of formaldehyde or a polyhydric alcohol and an initiator for cationic polymerization. The initiator may be a heteropoly acid or an acid salt thereof which is dissolved in an alkyl ester of a polybasic carboxylic acid.
摘要翻译： 本发明涉及一种制备甲醛聚合物的方法以及由其获得的甲醛聚合物。 该方法包括在甲醛或多元醇的缩醛和用于阳离子聚合的引发剂的存在下形成-CH 2 -O-单体的单体的聚合。 引发剂可以是杂多酸或其酸盐，其溶解在多元羧酸的烷基酯中。
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